Prediction of remaining useful life for a composite electrode lithium ion battery cell using an electrochemical model to estimate the state of health

2021 ◽  
Vol 481 ◽  
pp. 228861
Author(s):  
Kaveh Khodadadi Sadabadi ◽  
Xin Jin ◽  
Giorgio Rizzoni
Author(s):  
Meng Huang ◽  
Mrinal Kumar

Lithium-ion battery cycle- and calendar-life remain to be one of the greatest uncertainties for the advanced energy storage systems. Accurate characterization of battery aging has been crucial for battery state-of-health (SOH) estimation and the remaining useful life (RUL) prediction. The formation-and-growth of the solid-electrolyte interphase (SEI) has been widely recognized as one of the most prominent battery degradation mechanisms. It consumes the cyclable lithium within the cell and ultimately leads to the capacity fade which cannot be measured directly onboard. This study evaluates the multi-scale multi-physics battery models and their respective aging mechanisms as well as the corresponding characterization metrics. Then the reduced order single particle model (SPM) is selected in this study, given its parametric dependence on both electrochemical and physical parameters as well as its compatibility to the available measurements in vehicle for aging characterization. nLi, the total moles of cyclable lithium within the cell, is identified as a valid aging parameter that can effectively characterize the capacity fade through the interpretation of experimental aging data. This study also investigates into the potentially optimal testing profile and the sufficient amount of data required for the accurate aging characterization. Then the method of brute force nearest neighbor search (NNS) is applied to derive the long-term evolution trend of the aging parameter nLi, which can serve as a key benchmark for validating the in-vehicle implementable algorithms for battery state-of-health (SOH) estimation and as an important foundation for predicting the remaining useful life (RUL) of battery.


Energies ◽  
2020 ◽  
Vol 13 (18) ◽  
pp. 4858
Author(s):  
Zhonghua Yun ◽  
Wenhu Qin ◽  
Weipeng Shi ◽  
Peng Ping

Generally, the State-of-Health (SOH) monitoring and Remaining Useful Life (RUL) prediction and assessment of lithium-ion (Li-ion) batteries need to use sensors to obtain the degradation test data of the same type of batteries and establish the degradation model for reference. However, when the battery type is unknown, a usable reference model cannot be obtained, so its prediction and evaluation may be relatively inconvenient. In this paper, the State of-Health prediction for lithium-ion batteries based on a novel hybrid scheme is proposed. Firstly, historical charge/discharge time series and capacity series are extracted to analyze and construct Health Indicators, then using Complete Ensemble Empirical Mode Decomposition with Adaptive Noise (CEEMDAN) to decompose the Health Indicator series into the trend and non-trend terms. Among them, the relatively smooth trend item data series uses the Autoregressive Integrated Moving Average model (ARIMA) for prediction; when dealing with the data series of non-trend items which are obviously non-smooth and seemingly random, the residuals predicted by ARIMA and the non-trend items obtained by CEEMDAN decomposition are combined into new non-trend items; then the least square support vector machine (LSSVM) is introduced to build a nonlinear prediction model and make predictions. Finally, combining the prediction results of the trend item data series and the non-trend item data series as a reference for the assessment of the state of health and remaining useful life. The 13 experimental results of 3 batteries verify the effectiveness of the scheme.


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