scholarly journals R-branch line intensities and temperature-dependent line broadening and shift coefficients of the nitric oxide fundamental rovibrational band

Author(s):  
Christopher A. Almodovar ◽  
Wey-Wey Su ◽  
Christopher L. Strand ◽  
Ronald K. Hanson
Author(s):  
Ritobrata Sur ◽  
R. Mitchell Spearrin ◽  
Wen Y. Peng ◽  
Christopher L. Strand ◽  
Jay B. Jeffries ◽  
...  

Author(s):  
Simon Engelbert ◽  
Rolf-Dieter Hoffmann ◽  
Jutta Kösters ◽  
Steffen Klenner ◽  
Rainer Pöttgen

Abstract The structures of the equiatomic stannides RERhSn with the smaller rare earth elements Y, Gd-Tm and Lu were reinvestigated on the basis of temperature-dependent single crystal X-ray diffraction data. GdRhSn crystallizes with the aristotype ZrNiAl at 293 and 90 K. For RE = Y, Tb, Ho and Er the HP-CeRuSn type (approximant with space group R3m) is already formed at room temperature, while DyRhSn adopts the HP-CeRuSn type below 280 K. TmRhSn and LuRhSn show incommensurate modulated variants with superspace groups P31m(1/3; 1/3; γ) 000 (No. 157.1.23.1) (γ = 3/8 for TmRhSn and γ = 2/5 for LuRhSn). The driving force for superstructure formation (modulation) is a strengthening of Rh–Sn bonding. The modulation is expressed in a 119Sn Mössbauer spectrum of DyRhSn at 78 K through line broadening.


1957 ◽  
Vol 1 ◽  
pp. 193-206 ◽  
Author(s):  
William J. Campbell ◽  
Melvin Leon ◽  
John Thatcher

AbstractAn investigation was undertaken by the Bureau of Mines at College Park, Md., to determine the effect of various combinations of collimators, analyzing crystals and detectors on line intensities, line-to-backgrouhd ratios, and spectral resolution. The research showed that line broadening due to mosaic crystal surfaces was greatly reduced and line splitting from faults was eliminatedby the use of two fine collimators (0.005 inch, spacing, 4 inch length). Line intensities were reduced, but lineto- background ratios arid line profiles were substantially improved with double collimators. Pulse height discrimination resulted in marked improvement in the line-to-background ratio in the long-wave length region, 2 to 10 A, but was much less effective for shorter wave lengths.


1998 ◽  
Vol 187 (2) ◽  
pp. 200-205 ◽  
Author(s):  
J.-Y. Mandin ◽  
V. Dana ◽  
L. Régalia ◽  
A. Barbe ◽  
P.Von der Heyden

2006 ◽  
Vol 3 (4) ◽  
pp. 976-979 ◽  
Author(s):  
R. Hauschild ◽  
H. Priller ◽  
M. Decker ◽  
J. Brückner ◽  
H. Kalt ◽  
...  

2009 ◽  
Vol 247 (2) ◽  
pp. 347-352 ◽  
Author(s):  
M. B. Smirnov ◽  
V. G. Talalaev ◽  
B. V. Novikov ◽  
S. V. Sarangov ◽  
N. D. Zakharov ◽  
...  

Author(s):  
Wey-Wey Su ◽  
Christian Boulet ◽  
Christopher A. Almodovar ◽  
Yiming Ding ◽  
Christopher L. Strand ◽  
...  

1978 ◽  
Vol 33 (12) ◽  
pp. 1461-1468 ◽  
Author(s):  
H. C. Petzold ◽  
W. Behmenburg

Abstract The temperature dependence of the absorption spectrum k(v̄) of Hg-Ar-mixtures in the range 30-1000 cm-1 about the center of the Hg-line at v̄0 = 39425 cm-1 (λ0 = 2536.5 Å) has been investigated in the temperature interval 473 -1273 K. The measurements were carried out at number densities 1.0 x 1017-9.1 X 1018 cm-3 for Hg and 9.4 x 1018-9.7 x 1018 cm-3 for Ar. Potentials for the Hg-Ar-system in the thermal energy range originating from the Hg-states 61S0 and 63P1 have been deduced from the data. It turned out that they differ considerably from Lennard-Jones-functions. By comparison of the observed spectra with calculations on the basis of quantummechanical theory of collisional line broadening it is concluded that transitions from free translational states of Hg-Ar-pairs as well as bound and quasi-bound vibrational states of the Hg-Ar-molecule contribute to the formation of the satellite structure on the short wavelength side of the Hg-line.


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