Development of an integrated process involving palm industry co-products for monoglyceride/diglyceride emulsifier synthesis: Use of palm cake and fiber for lipase production and palm fatty-acid distillate as raw material

Increasing concern in fossil fuel depletion and CO2 emissions create an urgent need for biofuel substitution. Bio-jet fuel is a possible alternative for conventional jet fuels which currently accounts for 2% of the world’s CO2 emission. Palm Fatty Acid Distillate (PFAD) is the byproduct of palm oil refinery process, which has a potential to become a promising raw material for the synthesis of bioavtur due to its high free fatty acid content. The oil-to-jet pathway is a possible route to produce bioavtur from PFAD, which includes hydrotreating, hydrocracking, and hydroisomerization processes. This research aims to investigate the hydrotreating and hydrocracking processes. The parameters that were investigated are temperature, solvent to PFAD ratio, catalyst loading, and pressure. The parameters variations were as follows: the temperature at 350oC and 400oC, the pressure at 40 bar and 32.5 bar, the solvent to PFAD ratio at 2:1 and 1:1, and the catalyst loading (%wt) at 1%, 2%, and 3%. Presulfided NiMo/γ-Al2O3 PIDO 120 1.3 was used for one-step hydrotreating and hydrocracking processes. Results indicated that the 400oC provided better free fatty acid (FFA) conversion. FFA is also almost completely removed when the catalyst used is 3% weight. Solvent to PFAD ratio affected the FFA conversion marginally, while higher catalyst loading (3%) improved the FFA conversion. Gas chromatography results show that the hydrocarbon chains are successfully hydrocracked into C9-C17. The best selectivity of the product to bioavtur range was calculated at 68.99%. Solvent ratio affects the hydrocracking more significantly than the catalyst loading. One sample with temperature operation 400oC and solvent to PFAD ratio 1:1 was in the range of conventional avtur density. With the method used in this study, it can be concluded that PFAD is a promising raw material for bioavtur. Keywords: Palm Fatty Acid Distillate (PFAD), hydrotreating, hydrocracking, bioavtur

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Preparation of Palm Fatty Acid Distillate (PFAD) As Raw Material for Bio Aviation Fuel Production

ICONIET PROCEEDING ◽

10.33555/iconiet.v2i1.5 ◽

2019 ◽

Vol 2 (1) ◽

pp. 13-18

Author(s):

Barry Wiethoff ◽

Evita H. Legowo ◽

Diah Indriani Widiputri

Keyword(s):

Fatty Acids ◽

Fatty Acid ◽

Free Fatty Acids ◽

Co2 Emission ◽

Hydrocarbon Chain ◽

Oil Refinery ◽

Raw Material ◽

Aviation Fuel ◽

Palm Fatty Acid Distillate ◽

Fatty Acid Distillate

Nowadays, aviation sector became one of the most important transportation in the world. The demand in this sector has increased rapidly over the last 10 years. Unfortunately, the increase of the demand leads to an increase of fuel consumption and CO2 emission in the aviation’s sector. Bio-based aviation fuel is believed to be one of the solution for the reduction of CO2 emission in the aviation’s sector. Palm Fatty Acid Distillate (PFAD) which is a by product of palm oil refinery, contains a high amount of free fatty acids. The free fatty acids contained in the PFAD are able to be converted into straight hydrocarbon chain through decarboxylation process. This thesis conducted 3 different experiments to find out the best decarboxylation reaction’s condition to convert the FFA into straight chain hydrocarbons over an activated carbon catalyst. The experiments compared the results between the experiment with different reaction’s conditions and the presence of solvent in the reaction. The results have shown that the third experiment, which used heptane as solvent and hydrogen in argon gas as reaction’s environment, has the best reaction’s condition among others. Experiment 3 has converted 77.07% of the FFA, while experiment 2 and 1 only converted 58.37% and 16.30% respectively.

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Biodiesel production from Palm Fatty Acid Distillate (PFAD) using reactive distillation

Jurnal Teknik Kimia Indonesia ◽

10.5614/jtki.2012.11.2.7 ◽

2018 ◽

Vol 11 (2) ◽

pp. 108

Author(s):

Arief Budiman ◽

Alita Lelyana ◽

Daniar Rianawati ◽

S Sutijan

Keyword(s):

Fatty Acid ◽

Reactive Distillation ◽

Aspen Plus ◽

High Energy ◽

Raw Material ◽

Biodiesel Production ◽

Esterification Reaction ◽

Scale Production ◽

Palm Fatty Acid Distillate ◽

Fatty Acid Distillate

Palm fatty acid distillate (PFAD) is a lower-value by-product obtained during the refining of palm oil and contained high amount of free fatty acid (FFA). However, it’s a potentially valuable and low-cost raw material for the production of biodiesel through esterification process. Esterification of FFA using the conventional batch faces a challenge since it is low in productivity and requires high excess of reactant so that it is not efficient for large-scale production. To overcome this problem, reactive distillation (RD) is the best candidate. RD is one of the most attractive equipment which provides potential benefits for the esterification reaction. To obtain an optimal design of the RD, an accurate model and simulation of the process is needed. In this work, a simulation study of biodiesel production from PFAD as feedstock using RD is presented by using ASPEN Plus v7.1. Two case studies of total reflux (case A) and recycled distillate (case B) were demonstrated. Close relation was found among high separation and high energy consumption in RD. Two models of RD show the more economical heat duty of both condenser and reboiler. Effect of L/F ratio, number of stages in reaction zone, and model of RD to conversion of esterification reaction were discussed. Keywords: biodiesel, esterification, PFAD, reactive distillationAbstrakSuatu produk hasil samping yang memiliki nilai ekonomi rendah, biasa dikenal sebagai Palm Fatty Acid Distilate (PFAD), diperoleh dari proses pemurnian minyak kelapa sawit. PFAD mengandung asam lemak bebas (FFA) tinggi, cukup potensial, dapat digunakan sebagai bahan baku produksi biodiesel melalui proses esterifikasi. Esterifikasi FFA dengan proses batch konvensional menghadapi tantangan karena produktivitasnya cukup rendah dan membutuhkan excess reaktan yang tinggi sehingga tidak efisien jika diterapkan untuk produksi skala besar. Reactive distillation (RD) dapat menjadi solusi untuk mengatasi masalah ini. RD merupakan alat yang berpotensi memberikan keuntungan dalam reaksi esterifikasi. Untuk mendapatkan desain yang optimal dari suatu RD, pemodelan yang akurat dan simulasi dari proses ini diperlukan. Di sini, dilakukan simulasi produksi biodiesel dari PFAD menggunakan RD dilakukan dengan ASPEN Plus v7.1. Dua kasus dipelajari, yaitu refluks total (kasus A) dan recycle distillate (kasus B) yang bertujuan untuk mempelajari pengaruh rasio antara cairan yang dikembalikan ke kolom dengan feed (L/ F), dan variable variable desain. Semakin tinggi kemurnian dari hasil pemisahan, konsumsi energi yang dibutuhkan juga menjadi semakin besar. Perbandingan antara dua model dari kolom distilasi reaktif menunjukkan beban panas kondensor dan reboiler menjadi lebih ekonomis. Pengaruh perbandingan L/F, jumlah stage dalam zona reaksi, dan model kolom distilasi reaktif terhadap konversi reaksi esterifikasi akan di bahas di sini.Kata kunci: biodiesel, esterifikasi, PFAD, menara distilasi

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Hydrogenated Palm Fatty Acid Distillate as Raw Materials for Magnesium Stearate Alternatives

Journal of Engineering and Technological Sciences ◽

10.5614/j.eng.technol.sci.2021.53.3.3 ◽

2021 ◽

Vol 53 (3) ◽

pp. 210303

Author(s):

Abdu Ravi Zakaria ◽

Dwi Rokhmat Setiawan ◽

Shelly Shelly ◽

Melia Laniwati ◽

Dianika Lestari

Keyword(s):

Fatty Acid ◽

Iodine Value ◽

Raw Materials ◽

Pharmaceutical Products ◽

Ammonium Formate ◽

Transfer Hydrogenation ◽

Raw Material ◽

Degree Of Saturation ◽

Palm Fatty Acid Distillate ◽

Fatty Acid Distillate

Palm fatty acid distillate (PFAD) was used as raw material to produce solid lubricant, or anti-adherent, for confectionery or pharmaceutical products. To improve the degree of saturation, the PFAD was hydrogenated by using two methods: gaseous hydrogenation (GH) and catalytic transfer hydrogenation (CTH) using ammonium formate to produce hydrogenated PFAD (HPFAD). The HPFAD was saponified with MgO to produce magnesium salts of hydrogenated PFAD (Mg-HPFAD). The objective of this research was to investigate the effect of hydrogen concentration and reaction temperature on the iodine value of HPFAD and to investigate the characteristics of paracetamol tablets when using Mg-HPFAD as lubricant compared to commercial Mg-stearate. The HPFAD produced by CTH had a lower iodine value than the HPFAD produced by GH. The lowest iodine value was obtained after CTH using 3.6 M ammonium formate at 90°C. Paracetamol tablets with Mg-PFAD or Mg-HPFAD lubricant showed higher dissolution of active compounds with similar friability, frictiability, and hardness compared to paracetamol tablets with Mg-stearate.

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