Impact of total organic carbon (in sediments) and dissolved organic carbon (in overlying water column) on Hg sequestration by coastal sediments from the central east coast of India

2014 ◽  
Vol 79 (1-2) ◽  
pp. 342-347 ◽  
Author(s):  
Parthasarathi Chakraborty ◽  
Brijmohan Sharma ◽  
P.V. Raghunath Babu ◽  
Koffi Marcellin Yao ◽  
Saranya Jaychandran
2008 ◽  
Vol 6 (1) ◽  
Author(s):  
Markus Heryanto Langsa

<p>Penelitian ini bertujuan untuk menentukan senyawa organik khususnya organic karbon terlarut (DOC) dari dua spesies daun tumbuhan (<em>wandoo eucalyptus </em>and <em>pinus radiate, conifer</em>) yang larut dalam air selama periode 5 bulan leaching eksperimen. Kecepatan melarutnya senyawa organic ditentukan secara kuantitatif dan kualitatif menggunakan kombinasi dari beberapa teknik diantaranya Total Organic Carbon (TOC) analyser, Ultraviolet-Visible (UV-VIS) spektrokopi dan pyrolysis-gas chromatography-mass spectrometry (Py-GC-MS).</p><p>Hasil analisis DOC dan UV menunjukkan peningkatan yang tajam dari kelarutan senyawa organic di awal periode pengamatan yang selanjutnya berkurang seiring dengan waktu secara eksponensial. Jumlah relatif senyawa organic yang terlarut tergantung pada luas permukaan, aktifitas mikrobiologi dan jenis sampel tumbuhan (segar atau kering) yang digunakan. Fluktuasi profil DOC dan UV<sub>254</sub> disebabkan oleh aktifitas mikrobiologi. Diperoleh bahwa daun kering lebih mudah terdegradasi menghasilkan senyawa organic dalam air dibandingkan dengan daun segar. Hasil pyrolysis secara umum menunjukkan bahwa senyawa hidrokarbon aromatic dan fenol (dan turunannya) lebih banyak ditemukan pada residue sampel setelah proses leaching kemungkinan karena adanya senyawa lignin atau aktifitas humifikasi mikrobiologi membuktikan bahwa senyawa-senyawa tersebut merupakan komponen penting dalam proses karakterisasi DOC.</p>


2020 ◽  
Vol 95 (1) ◽  
pp. 67-74
Author(s):  
U. K. Pradhan ◽  
R. K. Sahoo ◽  
S. Pradhan ◽  
P. K. Mohany ◽  
P. Mishra

Proceedings ◽  
2020 ◽  
Vol 51 (1) ◽  
pp. 35
Author(s):  
Patrycja Sobczak ◽  
Agata Rosińska

Total organic carbon (TOC) present in surface water consists of different fractions like dissolved organic carbon (DOC) or biodegradable dissolved organic carbon (BDOC). BDOC may have an impact on the bacteriological quality of water as it can be a source of carbon and energy for microorganisms. It is important to consider this parameter in case of the distribution of drinking water. The aim of this research was to compare the qualities of chosen surface water in Poland and Germany in terms of concentration of total organic carbon and its fractions. The samples were taken from the reservoir in Poland and Rhine River in Germany. The first one is a source of drinking water for humans. The research showed that, considering the analyzed compounds, the water from the river has better quality.


1985 ◽  
Vol 42 (4) ◽  
pp. 797-808 ◽  
Author(s):  
S. C. Whalen ◽  
J. C. Cornwell

Budgets for nitrogen, phosphorus, and organic carbon in Toolik Lake, Alaska, were assembled from data collected during 1977–81. The annual total organic carbon (TOC), total nitrogen (TN), and total phosphorus (TP) loads to the Sake were 8557, 290, and 4.64 mmol∙m−2. Inlet streams were the major source of nutrients to the lake, as direct precipitation provided only 1, 2, and 5%, respectively, of the annual TOC, TN, and TP loads to the lake. Up to 30% of the annual N and P inputs to the lake from riverine sources occurred during the first 10 d of stream flow following breakup when cold water temperatures and snow-covered ice limited primary production. Due to the short water renewal time (0.5 yr), efficiency of nutrient retention was poor and 90, 82, and 70% of the annual TOC, TN, and TP inputs to the lake were discharged at the outlet stream. Regeneration within the water column supplied 40–66% and 68–78% of the N and P necessary for measured primary production. Yearly accumulation rates for C, N, and P in the sediment were about 220, 21.0, and 1.75 mmol∙m−2. Phosphorus remineralized within the sediment was completely retained due to adsorption onto Fe oxide minerals in the oxidizing surface layer. Annual rates of release of C and N to the overlying water column were 110 and 11.5–22.2 mmol∙m2. Mass balance considerations showed no serious errors in estimates of any terms of the annual sediment and water column N, P, and organic C budgets.


2017 ◽  
Vol 13 (3) ◽  
pp. 167
Author(s):  
Husnah Husnah ◽  
Eko Prianto ◽  
Siti Nurul Aida

Sungai Musi merupakan sungai besar mengaliri wilayah Sumatera Selatan, Lampung, dan Bengkulu , dan bervariasi dalam pemanfaatannya, khususnya di bagian hilir, didominasi oleh kegiatan industri yang membuang limbahnya ke Sungai Musi. Kajian pengaruh industri terhadap Sungai Musi telah dilakukan, namun sebatas analisis fisik dan kimia lingkungan dan belum mengarah kepada pengaruhnya terhadap organisme air. Organisme air adalah indikator penting perubahan lingkungan karena organisme khususnya organisme dasar (benthos) menyimpan sejarah proses-proses terjadi di perairan. Riset yang bertujuan untuk mengetahui kualitas perairan Sungai Musi bagian hilir ditinjau dari karakteristik fisik dan kimia dan struktur makrozoobenthos telah dilakukan di Sungai Musi, Sumatera Selatan pada bulan Mei dan September 2006. Riset dilakukan bersifat survei lapangan. Delapan stasiun ditentukan di Sungai Musi bagian hilir berdasarkan pada perbedaan mikrohabitat. Stasiun riset masing masing antara lain Sejagung, Pulokerto, Jembatan Ampera, Sebokor, Pulau Burung, Upang, Pulau Payung, dan Sungsang. Pada masing masing stasiun, dilakukan pengambilan contoh air untuk parameter fisika, kimia, dan makrobenthos. Contoh air diambil dari atas perahu motor pada kedalaman 1,0 m dari permukaan air dengan menggunakan kemmerer water sampler. Sebagian contoh dianalisis di lapangan (suhu, pH, dan oksigen terlarut) dan sebagian lagi yaitu jumlah padatan tersesuspensi (total suspended solids), jumlah padatan terlarut (total dissolved solids), jumlah karbon organik (total organic carbon), organik karbon terlarut (dissolved organic carbon), konsumsi oksigen biologi (biochemical oxygen demand), nitrat, dan fosfat dianalisis di laboratorium kimia. Contoh makrozoobenthos diambil pada 10 titik di masing-masing stasiun, dengan menggunakan ekman dredge dengan bukaan mulut 400 cm2. Contoh makrobenthos pada masingmasing titik tersebut disortir dengan menggunakan saringan dan kemudian digabungkan (dikomposit) dan diawetkan dengan formalin 10%. Data kualitas air dianalisis dengan principle component analysis dan kelimpahan makrozoobenthos dianalisis dengan analisis cluster. Kualitas perairan di Sungai Musi bagian hilir dikelompokkan atas 2 yang mengalami tekanan berat yaitu dari Sejagung sampai dengan Pulau Burung dan tekanan ringan yaitu dari Upang sampai dengan Muara Sungai Musi. Kelompok pertama dicirikan oleh nilai konsentrasi total dissolved solids, total organic carbon, dan dissolved organic carbon yang tinggi diiringi dengan kelimpahan makrozoobenhthos yang rendah serta didominasi oleh Tubifex sp. Kelompok ke-2 dari Upang sampai dengan Muara Sungai Musi dicirikan oleh nilai konsentrasi total suspended solids yang tinggi, dengan kelimpahan makrozoobenthos yang tinggi dan didominasi oleh Gammarus. Musi River is a large river , crossing three provinces, South Sumatra, Lampung and Bengkulu, and differeing in types and levels of its resources ultization, particularly at the down stream of Musi River, mostly dominated by industries activities producing a waste which flows to the river. Several studies on the effect of industries on the Musi River have been conducted , however , limmieted on physical dan chemical aspects of the water, not yet to evaluate its effect on aquatic organism. Aquatic organism such macrozoobenthos is important indicator of environmental changes since this organism records the history of processes occurred in the water. Study to assess water quality of the down stream Musi River based on physical, chemical water characteristics and macrozoobenthos community structure was conducted at may and september 2006 in Musi River located in South Sumatera Province of Indonesia. The study used inventory field survey. Eight sampling sites; Sejagung, Pulokerto, Jembatan Ampera, Sebokor, Pulau Burung, Upang, Pulau Payung, and Sungsang were selected based on the microhabitat difference. water sampling for physical and chemical parameters and sediment, and  macrozoobenthos were carried in each sampling site. Water sample was collected at a depth of 1.0 m from the water surface by using kemmerer water sampler. Some water quality parameters such as temperature, pH, and dissolved oxygen) were directly analyzed in the field, while the others such as total suspended solids, total dissolved solids, total organic carbon, dissolved organic carbon, biochemical oxygen demand, nitrate, and phosphate were analyzed in laboratory. Macrozoobenthos was collected at ten sampling points in each sampling sites using Ekman Dredge of 400 cm2 mouth opening. Macrozoobenthos from ten sampling points was composited, sorted and preserved with formalin 10%. Water quality parameters were analyzed with principle component analysis while macrozoobenthos abundance was analyzed with cluster. Results revealed that water quality at the down stream Musi River was classified into two groups. The first group was the heavy degraded sites from Sejagung to Pulau Burung, characterized by having high concentration of total dissolved solids, total organic carbon, and dissolved organic carbon, low abundance of macrozoobenthos with Tubifex sp. as the dominant species. The second group was light degraded sites from Upang to the mouth of Musi River, characterized by high concentration of total suspended solids and high macrozoobenthos abundance with Gammarus sp. as the dominant species.


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