Surface-imprinted polymer microspheres for rapid and selective adsorption of As(V) ions from the aqueous phase

: Core-shell polymers represent a class of composite particles comprising of minimum two dissimilar constituents, one at the center known as a core which is occupied by the other called shell. Core-shell molecularly imprinting polymers (CSMIPs) are composites prepared via printing a template molecule (analyte) in the coreshell assembly followed by their elimination to provide the everlasting cavities specific to the template molecules. Various other types of CSMIPs with a partial shell, hollow-core and empty-shell are also prepared. Numerous methods have been reported for synthesizing the CSMIPs. CSMIPs composites could develop the ability to identify template molecules, increase the relative adsorption selectivity and offer higher adsorption capacity. Keen features are measured that permits these polymers to be utilized in numerous applications. It has been developed as a modern technique with the probability for an extensive range of uses in selective adsorption, biomedical fields, food processing, environmental applications, in utilizing the plant's extracts for further applications, and sensors. This review covers the approaches of developing the CSMIPs synthetic schemes, and their application with special emphasis on uses in the biomedical field, food care subjects, plant extracts analysis and in environmental studies.

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Eco-friendly ionic liquid imprinted polymer based on a green synthesis strategy for highly selective adsorption tylosin in animal muscle samples

Environmental Science and Pollution Research ◽

10.1007/s11356-020-11842-5 ◽

2021 ◽

Author(s):

Lifang Wang ◽

Jingfan Chen ◽

Xian Li ◽

Letian Chen ◽

Kaige Zhang ◽

...

Keyword(s):

Ionic Liquid ◽

Green Synthesis ◽

Selective Adsorption ◽

Imprinted Polymer ◽

Synthesis Strategy ◽

Animal Muscle

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Gold (Au) selective adsorption using polyeugenol based ionic imprinted polymer with ethylene glycol dimethacrylate crosslink

10.1063/5.0005546 ◽

2020 ◽

Author(s):

M. Cholid Djunaidi ◽

Nor Basid Adiwibawa Prasetya ◽

Didik Setiyo Widodo ◽

Retno Ariadi Lusiana ◽

Pardoyo

Keyword(s):

Ethylene Glycol ◽

Selective Adsorption ◽

Ethylene Glycol Dimethacrylate ◽

Glycol Dimethacrylate ◽

Imprinted Polymer

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Efficient synthesis of narrowly dispersed molecularly imprinted polymer microspheres with multiple stimuli-responsive template binding properties in aqueous media

Chemical Communications ◽

10.1039/c2cc31932b ◽

2012 ◽

Vol 48 (50) ◽

pp. 6217 ◽

Cited By ~ 93

Author(s):

Yue Ma ◽

Ying Zhang ◽

Man Zhao ◽

Xianzhi Guo ◽

Huiqi Zhang

Keyword(s):

Molecularly Imprinted Polymer ◽

Aqueous Media ◽

Polymer Microspheres ◽

Stimuli Responsive ◽

Efficient Synthesis ◽

Imprinted Polymer ◽

Binding Properties ◽

Molecularly Imprinted

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Luteolin Imprinted Polymer with Selective Recognition and Adsorption Performance

Materials Science Forum ◽

10.4028/www.scientific.net/msf.809-810.297 ◽

2014 ◽

Vol 809-810 ◽

pp. 297-301

Author(s):

Ping Rui Meng ◽

Liang Bo Li

Keyword(s):

Adsorption Process ◽

Selective Adsorption ◽

Methanol Solution ◽

Selective Recognition ◽

Imprinted Polymer ◽

Molecular Imprinted Polymers ◽

Adsorption Dynamics ◽

Adsorption Performance ◽

Recognition Specificity ◽

Adsorption Amount

In order to selectively separate luteolin from its crude solution, we synthesized luteolin molecular imprinted polymers (LMIP) with high recognition specificity for luteolin, using an imprinting technique. Luteolin was used as template, methanol as solvent, and N,N’-methylenebisacrylamide (MBAA) as the cross-linking. Then prepared LMIP were characterized and evaluated by scanning electron microscope (SEM) and equilibrium absorption experiments. The results showed that the cavities matching with the template molecules in size and structure were present in the LMIP. Adsorption dynamics analysis suggested that, when the adsorption time reached 4 h, the adsorption process had reached balance and the adsorption capacity was at steady state. The selective adsorption amount reached at 35.65 umol/g for the LMIP, while a lower value of 11.68 umol/g for the blank polymer (i.e. nontemplated). Relative to the corresponding blank polymer, LMIP had an excellent recognition to luteolin in methanol solution. Keywords: Molecular imprinting, Molecular recognition, Adsorbent, Luteolin

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