Preparation and properties of continuous glass fiber reinforced anionic polyamide-6 thermoplastic composites

2013 ◽  
Vol 46 ◽  
pp. 688-695 ◽  
Author(s):  
Chun Yan ◽  
Hongzhou Li ◽  
Xiaoqing Zhang ◽  
Yingdan Zhu ◽  
Xinyu Fan ◽  
...  
2020 ◽  
Vol 54 (27) ◽  
pp. 4231-4239
Author(s):  
Vishal Gavande ◽  
Anoop Anand

Continuous glass fiber reinforced thermoplastic composites have been manufactured and their mechanical properties have been evaluated. A catalyzed monomer is infused through a stack of compacted dry reinforcement under vacuum. The monomer undergoes radical polymerization with a peroxide catalyst. Viscosity and reactivity profile have been characterized to determine the catalyst concentration and temperature of infusion. Glass fiber reinforced thermoplastic composites realized through this method have mechanical properties that are comparable with that of epoxy with an added advantage of excellent toughness and repairability. For example, the residual compressive strength of thermoplastic composites after low-velocity impact is found to be over 140% more than that of epoxy-based composites using the same reinforcement and realized under identical manufacturing methods.


2017 ◽  
Vol 25 (1) ◽  
pp. 23-28 ◽  
Author(s):  
Jiuqiang Song ◽  
Yan Qin ◽  
Jia Chen ◽  
Siwen Qin

In this paper, a continuous glass fiber-reinforced polypropylene prepreg was prepared by fiber treatment with a silane coupling agent and MAH-g-PP resin. Continuous glass fiber-reinforced polypropylene sheets were made from prepreg and PP mats by hot-pressing; they displayed exceptional performance. This paper studies the effects of maleic anhydride grafting on the polypropylene crystallinity and MAH-g-PP content in the prepreg, and the mechanical properties of the composites. The results showed that modifying PP with maleic anhydride decreased the tacticity of the polypropylene molecular chain, which reduced the crystallinity and melting point. An excellent interface formed between the polypropylene and fiber after the glass fiber was treated with a silane coupling agent and MAH-g-PP resin. The mechanical properties of the polymer materials displayed more favorable properties as MAH-g-PP content increased; the ideal MAH-g-PP content was 50%.


Materials ◽  
2019 ◽  
Vol 12 (3) ◽  
pp. 463 ◽  
Author(s):  
Ke Chen ◽  
Mingyin Jia ◽  
Hua Sun ◽  
Ping Xue

In this paper, glass fiber-reinforced polyamide-6 (PA-6) composites with up to 70 wt% fiber contents were successfully manufactured using a pultrusion process, utilizing the anionic polymerization of caprolactam (a monomer of PA-6). A novel thermoplastic reaction injection pultrusion test line was developed with a specifically designed injection chamber to achieve complete impregnation of fiber bundles and high speed pultrusion. Process parameters like temperature of injection chamber, temperature of pultrusion die, and pultrusion speed were studied and optimized. The effects of die temperature on the crystallinity, melting point, and mechanical properties of the pultruded composites were also evaluated. The pultruded composites exhibited the highest flexural strength and flexural modulus, reaching 1061 MPa and 38,384 MPa, respectively. Then, effects of fiber contents on the density, heat distortion temperature, and mechanical properties of the composites were analyzed. The scanning electron microscope analysis showed the great interfacial adhesion between fibers and matrix at 180 °C, which greatly improved the mechanical properties of the composites. The thermoplastic reaction injection pultrusion in this paper provided an alternative for the preparation of thermoplastic composites with high fiber content.


2017 ◽  
Vol 30 (4) ◽  
pp. 489-499 ◽  
Author(s):  
Zhiping Xu ◽  
Guibin Wang ◽  
Jiazhuo Hu ◽  
Mei Zhang ◽  
Shuling Zhang ◽  
...  

This study focused on the effect of processing conditions on the tensile properties of continuous glass fiber–reinforced polyether ether ketone composites, fabricated by co-wrapped yarn method, under different conditions. Their tensile properties were investigated in terms of thermal and fracture characterizations. The cooling rate significantly affected only the tensile modulus. However, both holding temperature and holding time had a significant effect on the tensile strengths and modulus. Although the effects of both were the same, the optimal increase of the holding time was found to be more beneficial.


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