Coordination driven self-assembly of donor-acceptor linkers in 3D supramolecular frameworks: Ground state charge transfer and tunable porosity

This paper illustrates structure–property relationship of organic conjugated molecules in forming NIR-absorbing organic donor/acceptor charge-transfer complex at ground state.

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Impact of Ground-State Charge Transfer and Polarization Energy Change on Energy Band Offsets at Donor/Acceptor Interface in Organic Photovoltaics

Advanced Functional Materials ◽

10.1002/adfm.200901585 ◽

2010 ◽

Vol 20 (5) ◽

pp. 715-721 ◽

Cited By ~ 51

Author(s):

Kouki Akaike ◽

Kaname Kanai ◽

Yukio Ouchi ◽

Kazuhiko Seki

Keyword(s):

Charge Transfer ◽

Organic Photovoltaics ◽

Ground State ◽

Energy Band ◽

Energy Change ◽

Band Offsets ◽

Polarization Energy ◽

Donor Acceptor ◽

State Charge

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Light harvesting vesicular donor–acceptor scaffold limits the rate of charge recombination in the presence of an electron donor

Energy & Environmental Science ◽

10.1039/c3ee43293a ◽

2014 ◽

Vol 7 (5) ◽

pp. 1661-1669 ◽

Cited By ~ 32

Author(s):

Rijo T. Cheriya ◽

Ajith R. Mallia ◽

Mahesh Hariharan

Keyword(s):

Charge Transfer ◽

Survival Time ◽

Electron Donor ◽

Self Assembly ◽

Light Harvesting ◽

Charge Recombination ◽

Donor Acceptor

This work highlights the utility of π–π stacked self-assembly for enhanced survival time of charge transfer intermediates upon photoexcitation of donor–acceptor systems.

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Nanopore-induced host–guest charge transfer phenomena in a metal–organic framework

Chemical Science ◽

10.1039/c7sc05390h ◽

2018 ◽

Vol 9 (13) ◽

pp. 3282-3289 ◽

Cited By ~ 12

Author(s):

S. Yamamoto ◽

J. Pirillo ◽

Y. Hijikata ◽

Z. Zhang ◽

K. Awaga

Keyword(s):

Charge Transfer ◽

Self Assembly ◽

Metal Organic Framework ◽

Donor And Acceptor ◽

Organic Electron ◽

Donor Acceptor ◽

Metal Organic ◽

Bulk Scale ◽

A Charge ◽

Organic Framework

Using the “crystal sponge” approach, weak organic electron donor molecules were impregnated and evenly distributed in a crystal of a metal–organic framework (MOF), with the self-assembly of the donor–acceptor pairs with electron acceptor ligands. The nanopores of the MOF confined them and induced a charge transfer phenomenon, which would not occur between donor and acceptor molecules in a bulk scale.

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Bending-Type Electron Donor–Donor–Acceptor Triad: Dual Excited-State Charge-Transfer Coupled Structural Relaxation

Chemistry of Materials ◽

10.1021/acs.chemmater.9b02712 ◽

2019 ◽

Vol 31 (15) ◽

pp. 5981-5992 ◽

Cited By ~ 10

Author(s):

Jia-An Lin ◽

Shu-Wei Li ◽

Zong-Ying Liu ◽

Deng-Gao Chen ◽

Chun-Ying Huang ◽

...

Keyword(s):

Excited State ◽

Charge Transfer ◽

Electron Donor ◽

Structural Relaxation ◽

Donor Acceptor ◽

State Charge

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SEPARATION OF INITIAL AND FINAL STATE CONTRIBUTIONS TO CHEMICAL SHIFTS IN TERMS OF A POTENTIAL MODEL

Surface Review and Letters ◽

10.1142/s0218625x9400045x ◽

1994 ◽

Vol 01 (04) ◽

pp. 469-472 ◽

Cited By ~ 3

Author(s):

R.J. COLE ◽

P. WEIGHTMAN

Keyword(s):

Charge Transfer ◽

Ground State ◽

Potential Model ◽

Chemical Shifts ◽

Free Atom ◽

Core Hole ◽

Final State ◽

State Charge ◽

Elemental Solid

A recently developed potential model facilitates the separation of initial and final state contributions to chemical shifts in terms of ground state charge transfer and differences in core hole screening charge. The model is applied to the free atom to elemental solid shifts of the elements Na, Mg, Si, and Zn.

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