Electrochromic properties of three-colour prussian green ECDs and the evolution of Fe ions during the discoloration process

2021 ◽  
pp. 131627
Author(s):  
Y.G. Wang ◽  
M. Wang ◽  
Y.Q. Wang ◽  
Q. Zhang ◽  
H.N. Zhou ◽  
...  
Author(s):  
Hiroki Kurata ◽  
Kazuhiro Nagai ◽  
Seiji Isoda ◽  
Takashi Kobayashi

Electron energy loss spectra of transition metal oxides, which show various fine structures in inner shell edges, have been extensively studied. These structures and their positions are related to the oxidation state of metal ions. In this sence an influence of anions coordinated with the metal ions is very interesting. In the present work, we have investigated the energy loss near-edge structures (ELNES) of some iron compounds, i.e. oxides, chlorides, fluorides and potassium cyanides. In these compounds, Fe ions (Fe2+ or Fe3+) are octahedrally surrounded by six ligand anions and this means that the local symmetry around each iron is almost isotropic.EELS spectra were obtained using a JEM-2000FX with a Gatan Model-666 PEELS. The energy resolution was about leV which was mainly due to the energy spread of LaB6 -filament. The threshole energies of each edges were measured using a voltage scan module which was calibrated by setting the Ni L3 peak in NiO to an energy value of 853 eV.


2018 ◽  
pp. 25-34
Author(s):  
S. V. Rogozhkin ◽  
◽  
A. A. Nikitin ◽  
A. A. Khomich ◽  
N. A. Iskandarov ◽  
...  

2021 ◽  
Vol 594 ◽  
pp. 73-79
Author(s):  
Xianfeng Wu ◽  
Kai Wang ◽  
Junyu Lin ◽  
Dan Yan ◽  
Zhiyong Guo ◽  
...  

Materials ◽  
2021 ◽  
Vol 14 (15) ◽  
pp. 4061
Author(s):  
Yongtao Li ◽  
Liqing Liu ◽  
Dehao Wang ◽  
Hongguang Zhang ◽  
Xuemin He ◽  
...  

BiFeO3 is considered as a single phase multiferroic. However, its magnetism is very weak. We study the magnetic properties of BiFeO3 by Cu and (Cu, Zn). Polycrystalline samples Bi(Fe0.95Cu0.05)O3 and BiFe0.95(Zn0.025Cu0.025)O3 are prepared by the sol-gel method. The magnetic properties of BiFe0.95(Zn0.025Cu0.025)O3 are greater than that of BiFeO3 and Bi(Fe0.95Cu0.05)O3. The analyses of X-ray absorption fine structure data show that the doped Cu atoms well occupy the sites of the Fe atoms. X-ray absorption near edge spectra data confirm that the valence state of Fe ions does not change. Cu and Zn metal ion co-doping has no impact on the local structure of the Fe and Bi atoms. The modification of magnetism by doping Zn can be understood by the view of the occupation site of non-magnetically active Zn2+.


2016 ◽  
Vol 8 (40) ◽  
pp. 27107-27114 ◽  
Author(s):  
Lili Xiao ◽  
Ying Lv ◽  
Wenjie Dong ◽  
Nan Zhang ◽  
Xingyuan Liu

1993 ◽  
Vol 24 (4) ◽  
pp. 299-304 ◽  
Author(s):  
J Kapoor ◽  
A Metz ◽  
D Riegel ◽  
R Zeller ◽  
K. D Gross ◽  
...  
Keyword(s):  

1995 ◽  
Author(s):  
Takeshi Miki ◽  
Kazuki Yoshimura ◽  
Yutaka Tai ◽  
Masato Tazawa ◽  
Ping Jin ◽  
...  

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