Critical residence time in metastable region – a time scale determining the demixing mechanism of nonsolvent induced phase separation

2017 ◽  
Vol 529 ◽  
pp. 35-46 ◽  
Author(s):  
Shun-Lian Su ◽  
Da-Ming Wang ◽  
Juin-Yih Lai
1993 ◽  
Vol 115 (4) ◽  
pp. 751-759 ◽  
Author(s):  
Tsuneaki Ishima ◽  
Koichi Hishida ◽  
Masanobu Maeda

A particle dispersion has been experimentally investigated in a two-dimensional mixing layer with a large relative velocity between particle and gas-phase in order to clarify the effect of particle residence time on particle dispersion. Spherical glass particles 42, 72, and 135 μm in diameter were loaded directly into the origin of the shear layer. Particle number density and the velocities of both particle and gas phase were measured by a laser Doppler velocimeter with modified signal processing for two-phase flow. The results confirmed that the characteristic time scale of the coherent eddy apparently became equivalent to a shorter characteristic time scale due to a less residence time. The particle dispersion coefficients were well correlated to the extended Stokes number defined as the ratio of the particle relaxation time to the substantial eddy characteristic time scale which was evaluated by taking account of the particle residence time.


2014 ◽  
Vol 146 ◽  
pp. 119-127 ◽  
Author(s):  
K. Anand Rao ◽  
T. Sreenivas ◽  
Madhu Vinjamur ◽  
A.K. Suri

1994 ◽  
Vol 50 (3) ◽  
pp. R1752-R1754 ◽  
Author(s):  
H. Sato ◽  
N. Kuwahara ◽  
K. Kubota

2021 ◽  
Author(s):  
Javier Pelegrina ◽  
Carlos Osácar ◽  
Amalio Fernández-Pacheco

Abstract. The concept of residence time of energy in a planetary atmosphere τR, recently introduced and computed for the Earth's atmosphere (Osácar et al., 2020), is here extended to the atmospheres of Venus, Mars and Titan. After a global thermal perturbation, τR is the time scale the atmosphere needs to return to equilibrium. The residence times of energy in the atmospheres of Venus, Earth, Mars and Titan have been computed. In the cases of Venus, Mars and Titan, these are mere lower bounds due to a lack of some energy data.


2017 ◽  
Vol 56 (5) ◽  
pp. 1177-1194 ◽  
Author(s):  
K. W. Lo ◽  
K. Ngan

AbstractThe residence time measures the rate at which a pollutant escapes from a region of interest. Previous studies of urban ventilation have estimated the mean residence time from Eulerian data by assuming a spatially homogeneous pollutant field. Using a large-eddy simulation and a Lagrangian particle model, the residence and exposure times are calculated for an idealized street canyon in the skimming-flow region and a deep street canyon within a realistic urban area. For both domains, the mean residence time is on the order of a canyon circulation time scale, while the mean exposure time, which includes re-entrainment and characterizes the total time spent by a pollutant in a region of interest, is about 20% longer. Intensive quantities such as the Lagrangian visitation factor and return coefficient indicate that re-entrainment is modest. Probability distribution functions of the exposure and residence times are nearly exponential for both domains, in accord with pure diffusion and single-time-scale, vertical-exchange parameterizations. It is argued that, by analogy with Brownian motion, the mean residence and exposure times are set primarily by the mean circulation rather than the turbulence when the flow approximates that within a two-dimensional street canyon.


2021 ◽  
pp. 1-58
Author(s):  
D.S. Dukhovskoy ◽  
I. Yashayaev ◽  
E.P. Chassignet ◽  
P.G. Myers ◽  
G. Platov ◽  
...  

AbstractThe impact of increasing Greenland freshwater discharge on the subpolar North Atlantic (SPNA) remains unknown as there are uncertainties associated with the time scales of the Greenland freshwater anomaly (GFWA) in the SPNA. Results from numerical simulations tracking GFWA and an analytical approach are employed to estimate the response time suggesting a decadal time scale (13 years) required for the SPNA to adjust for increasing GFWA. Analytical solutions obtained for a long-lasting increase of freshwater discharge show a non-steady state response of the SPNA with increasing content of the GFWA. In contrast, solutions for a short-lived pulse of freshwater demonstrate different responses of the SPNA with a rapid increase of freshwater in the domain followed by an exponential decay after the pulse has passed. Derived theoretical relation between time scales show that residence time scales are time-dependent for a non-steady state case and asymptote the response time scale with time. Residence time of the GFWA deduced from Lagrangian experiments is close to and smaller than the response time, in agreement with the theory. The Lagrangian analysis shows dependence of the residence time on the entrance route of the GFWA and on the depth. The fraction of the GFWA exported through Davis Strait has limited impact on the interior basins, whereas the fraction entering the SPNA from the southwest Greenland shelf spreads into the interior regions. In both cases, the residence time of the GFWA increases with depth demonstrating long persistence of the freshwater anomaly in the subsurface layers.


2000 ◽  
Vol 11 (02) ◽  
pp. 347-358 ◽  
Author(s):  
J. C. LEE

When phase separation is induced by polymerizating monomers in a mixture of monomers and nonreacting molecules, the dynamics is different depending on the time scale of polymerization τpl and the time scale of phase separation τps. Previous studies have explored the dynamic regimes where τpl ≪ τps and that where τpl ≫ τps. In the former, a spanning gel emerges before the phase separation and the phase separation is driven largely by activation. In the latter, phase separation occurs first between polymers and nonbonding molecules and then the polymers turn into a gel, and therefore the driving mechanism is the same as in the usual liquid–liquid demixing processes. Using Molecular Dynamics simulations, we explore in this paper the intermediate dynamic regime where the two time scales are comparable. When the polymerization is done by means of the thermal condensation reaction, we observe the expected crossover, one limit behavior at early times and then the other at late times. When the polymerization is done by means of the radical addition reaction, the results suggest that the driving mechanism changes more than once.


2017 ◽  
Vol 47 (8) ◽  
pp. 2101-2114 ◽  
Author(s):  
Paul R. Holland

AbstractIdealized modeling studies have shown that the melting of ice shelves varies as a quadratic function of ocean temperature. However, this result is the equilibrium response, derived from steady ice–ocean simulations subjected to a fixed ocean forcing. This study considers instead the transient response of melting, using unsteady simulations subjected to forcing conditions that are oscillated with a range of periods. The results show that the residence time of water in the subice cavity offers a critical time scale. When the forcing varies slowly (period of oscillation ≫ residence time), the cavity is fully flushed with forcing anomalies at all stages of the cycle and melting follows the equilibrium response. When the forcing varies rapidly (period ≤ residence time), multiple cold and warm anomalies coexist in the cavity, cancelling each other in the spatial mean and thus inducing a relatively steady melt rate. This implies that all ice shelves have a maximum frequency of ocean variability that can be manifested in melting. Between these two extremes, an intermediate regime occurs in which melting follows the equilibrium response during the cooling phase of the forcing cycle, but deviates during warming. The results show that ice shelves forced by warm water have high melt rates, high equilibrium sensitivity, and short residence times and hence a short time scale over which the equilibrium sensitivity is manifest. The most rapid melting adjustment is induced by warm anomalies that are also saline. Thus, ice shelves in the Amundsen and Bellingshausen Seas, Antarctica, are highly sensitive to ocean change.


2019 ◽  
Author(s):  
Carlos Osácar ◽  
Manuel Membrado ◽  
Amalio Fernández-Pacheco

Abstract. In atmospheric chemistry, a parameter called residence time is defined for each gas as T = M/F, where M represents the mass of the gas in the atmosphere and F is the total average influx or outflux, which in time averages are equal. In this letter we extend this concept from matter to energy which is also a conservative quantity and estimate the average residence time of energy in the atmosphere which amounts to about 56 days. A similar estimation for the residence time of energy in the Sun is of the order of 107 yr, which agrees with the Kelvin-Helmholtz time scale.


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