A comparative study between Keggin-type tungstophosphates and tungstosilicates in the oxidation of cyclooctane with hydrogen peroxide

2004 ◽  
Vol 222 (1-2) ◽  
pp. 159-165 ◽  
Author(s):  
M. Salete S. Balula ◽  
Isabel C.M.S. Santos ◽  
Mário M.Q. Simões ◽  
M. Graça P.M.S. Neves ◽  
José A.S. Cavaleiro ◽  
...  
Keyword(s):  
Hydrogen Peroxide ◽  
Comparative Study ◽  
Keggin Type

A comparative study of oxidation of alkanes and alkenes by hydrogen peroxide catalyzed by Cu(salen) complex covalently bound to a Keggin type polyoxometalate and its neat counterpart

2008 ◽  
Vol 9 (14) ◽  
pp. 2411-2416 ◽  
Author(s):  
Valiollah Mirkhani ◽  
Majid Moghadam ◽  
Shahram Tangestaninejad ◽  
Iraj Mohammadpoor-Baltork ◽  
Nahid Rasouli
Keyword(s):  
Hydrogen Peroxide ◽  
Comparative Study ◽  
Keggin Type ◽  
Salen Complex ◽  
Covalently Bound

scholarly journals A Mn(iii) polyoxotungstate in the oxidation of organosulfur compounds by H2O2 at room temperature: an environmentally safe catalytic approach

2016 ◽  
Vol 6 (9) ◽  
pp. 3271-3278 ◽  
Author(s):  
Tiago A. G. Duarte ◽  
Sónia M. G. Pires ◽  
Isabel C. M. S. Santos ◽  
Mário M. Q. Simões ◽  
M. Graça P. M. S. Neves ◽  
...  
Keyword(s):  
Hydrogen Peroxide ◽  
Room Temperature ◽  
Organosulfur Compounds ◽  
Keggin Type ◽  
Environmentally Safe

A manganese monosubstituted Keggin-type polyoxometalate was used as a catalyst in the oxidation of recalcitrant organosulfur compounds by hydrogen peroxide at room temperature.

A comparative study of the electrogeneration of hydrogen peroxide using Vulcan and Printex carbon supports

Carbon ◽  
2011 ◽  
Vol 49 (8) ◽  
pp. 2842-2851 ◽  
Author(s):  
M.H.M.T. Assumpção ◽  
R.F.B. De Souza ◽  
D.C. Rascio ◽  
J.C.M. Silva ◽  
M.L. Calegaro ◽  
...  
Keyword(s):  
Hydrogen Peroxide ◽  
Comparative Study ◽  
Carbon Supports

scholarly journals Decomposition of Cyanide from Gold Leaching Tailingsby Using Sodium Metabisulphite and Hydrogen Peroxide

2020 ◽  
Vol 2020 ◽  
pp. 1-7
Author(s):  
Dongzhuang Hou ◽  
Lang Liu ◽  
Qixing Yang ◽  
Bo Zhang ◽  
Huafu Qiu ◽  
...  
Keyword(s):  
Hydrogen Peroxide ◽  
Comparative Study ◽  
Contact Time ◽  
Synergetic Effect ◽  
Economic Conditions ◽  
Gold Mine ◽  
Optimal Conditions ◽  
Gold Leaching ◽  
Sodium Metabisulphite ◽  
To Come

Cyanidation is widely used by most gold mine worldwide and will remain prevail in years (or decades) to come, while cyanide is hazardous, toxic pollutants whose presence in wastewater and tailings can seriously affect human and its environment; hence, it is necessary to control these contaminants. The purpose of this study was to examine the effects through the investigation of changes in pH, concentration, and contact time, and the optimal conditions were obtained. It has been proven that the decomposition of cyanide in solution and tailings increased as the alkalinity in the presence of 0.5 g/L Na2S2O5. An increase in H2O2 (30%) concentration (from 1 to 4 mL/L) increased the decomposition in solution, while the effect on removing cyanide was better when pH was 9 than 8 and 10 in tailings. The cyanide in tailings decreased in the first 4 h and increased after 4 h. The effective and economic conditions for maximum decomposition of cyanide from leach tailings are first treated in 0.5 g/L Na2S2O5 at pH 10 for 3 hours and then 2 mL/L H2O2 (30%) is added to the tailings at pH 9 for 4 hours through comparative study. The findings provide the basis to optimize the decomposition of cyanide from gold leaching tailings in mining or backfilling by using the synergetic effect of Na2S2O5 and H2O2.

Oxidation of Benzaldehyde to Benzoic Acid with Aqueous Hydrogen Peroxide over Dodecatungstophosphoric Acid

2013 ◽  
Vol 781-784 ◽  
pp. 219-222
Author(s):  
Qiu Ying Huang ◽  
Bei Bei Dong ◽  
Xiu Cheng Zheng
Keyword(s):  
Hydrogen Peroxide ◽  
Benzoic Acid ◽  
Catalytic Reaction ◽  
Type Structure ◽  
Optimal Parameters ◽  
Reaction Parameters ◽  
Aqueous Hydrogen Peroxide ◽  
Reaction Conditions ◽  
Prepared Sample ◽  
Keggin Type

Dodecatungstophosphoric acid was synthesized and used as catalyst for oxidation of benzaldehyde to benzoic acid with aqueous hydrogen peroxide. The effect of various catalytic reaction parameters including time, temperatures, and the amount of catalyst on the yield of benzoic acid was investigated in details. The results indicated that the as-prepared sample was in the keggin-type structure and the optimal parameters under the reaction conditions were as follows: 0.5 g of catalyst, reacted at 80 C for 5 h.

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