A green approach for the synthesis of long chain aliphatic acid esters at room temperature

2008 ◽  
Vol 279 (2) ◽  
pp. 159-164 ◽  
Author(s):  
Xinzhong Li ◽  
Wumanjiang Eli
Molecules ◽  
2019 ◽  
Vol 24 (5) ◽  
pp. 836 ◽  
Author(s):  
Meng-Qi Ling ◽  
Han Xie ◽  
Yu-Bo Hua ◽  
Jian Cai ◽  
Si-Yu Li ◽  
...  

Bottle aging is the final stage before wines are drunk, and is considered as a maturation time when many chemical changes occur. To get a better understanding of the evolution of wines’ flavor profile, the flavor compounds (phenolic and volatile compounds), dissolved oxygen (DO), and flavor characters (OAVs and chromatic parameters) of rosé and dry white wines bottled with different closures were determined after 18 months’ bottle aging. The results showed the main phenolic change trends of rosé wines were decreasing while the trends of white wines were increasing, which could be the reason for their unique DO changing behaviors. Volatile compounds could be clustered into fluctuating, increasing, and decreasing groups using k-means algorithm. Most volatile compounds, especially some long-chain aliphatic acid esters (octanoates and decanoates), exhibited a lower decrease rate in rosé wines sealed with natural corks and white wines with screw caps. After 18 months of bottle aging, wines treated with natural corks and their alternatives could be distinguished into two groups based on flavor compounds via PLS-DA. As for flavor characters, the total intensity of aroma declined obviously compared with their initial counterparts. Rosé wines exhibit visual difference in color, whereas such a phenomenon was not observed in white wines.


2012 ◽  
Vol 19 (3) ◽  
pp. 387-389 ◽  
Author(s):  
Cristiane B. Hobuss ◽  
Dalila Venzke ◽  
Bruna S. Pacheco ◽  
Alexander O. Souza ◽  
Marco A.Z. Santos ◽  
...  

2013 ◽  
Author(s):  
Cristiane B. Hobuss ◽  
Bruna S. Pacheco ◽  
Alexander O. Souza ◽  
Marina Ritter ◽  
Marco A. Z. Santos ◽  
...  

1998 ◽  
Vol 38 (2) ◽  
pp. 185-192 ◽  
Author(s):  
M. J. Bauer ◽  
R. Herrmann ◽  
A. Martin ◽  
H. Zellmann

Large amounts of phthalic acid esters (PAEs) are leached from plastics dumped at municipal landfills. This leachate transports PAEs either adsorbed on particulate matter or in dissolved phase. Dissolved organic macromolecules, mainly humic-like substances, enhance the solubility of PAEs. In the biochemical environments of municipal landfills short chain PAEs can be degraded by base-catalyzed hydrolysis or by microorganisms which enzymatically split the side chains. However, there is no cleavage of the aromatic ring. Long chain PAEs like di-(2-ethylhexyl) phthalate are neither degraded abiotically nor by microorganisms. Hence, these PAEs can be leached and washed out of leaky landfills into the groundwater and thus continue to be a threat to the aquatic environment. Only a combined UV radiation/ozonation treatment is capable of fully destroying PAEs.


1992 ◽  
Vol 70 (6) ◽  
pp. 448-454 ◽  
Author(s):  
Ewa Świeżewska ◽  
T. Chojnacki ◽  
W. J. Jankowski ◽  
K. Singh ◽  
J. Olsson

The long chain polyprenols composed of 30 and more isoprene units from leaves of plants belonging to the genera Potentilla and Rosa have been described. They occur in the form of fatty acid esters. The composition of polyprenol mixture was species dependent and its content reached ca. 0.5% wet weight. Large scale preparation of individual polyprenols from a natural polyprenol mixture was performed using time-extended liquid chromatography on the hydrophobic gel Lipidex-5000.Key words: long chain polyprenols, Rosaceae.


2021 ◽  
Author(s):  
Iurii Galadzhun ◽  
Rafal Kulmaczewski ◽  
Namrah Shahid ◽  
Oscar Cespedes ◽  
Mark J Howard ◽  
...  

[Fe(bpp)2][BF4]2 (bpp = 2,6-di{pyrazol-1-yl}pyridine) derivatives bearing a bent geometry of hexadec-1-ynyl or hexadecyl substituents pyrazole are isomorphous, and high-spin at room temperature. However, only the latter compound undergoes an abrupt,...


1951 ◽  
Vol 43 (3) ◽  
pp. 684-688 ◽  
Author(s):  
C. J. Maim ◽  
J. W. Mench ◽  
D. L. Kendall ◽  
G. D. Hiatt

RSC Advances ◽  
2017 ◽  
Vol 7 (67) ◽  
pp. 42000-42012 ◽  
Author(s):  
Pramod K. Sahu

A green synthesis of hydrotalcite (a double layered catalyst) by a grinding method using Al/Mg molar ratios of 1.0–3.0 at room temperature is described.


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