Computationally designed ionic liquid based molecularly imprinted@ graphene oxide composite: Characterization and validation

2021 ◽  
pp. 116925
Author(s):  
Ranjita S. Das ◽  
Atul V. Wankhade ◽  
Anupama Kumar
2011 ◽  
Vol 21 (21) ◽  
pp. 7795 ◽  
Author(s):  
Jianfeng Shen ◽  
Min Shi ◽  
Bo Yan ◽  
Hongwei Ma ◽  
Na Li ◽  
...  

RSC Advances ◽  
2015 ◽  
Vol 5 (113) ◽  
pp. 92932-92939 ◽  
Author(s):  
Xiaojiao Wang ◽  
Chuannan Luo ◽  
Leilei Li ◽  
Huimin Duan

Schematic diagram of GO/CCNTs/IL/AuNPs/MIPs composites applied to the electrode.


2015 ◽  
Vol 51 ◽  
pp. 274-278 ◽  
Author(s):  
Chengli Yao ◽  
Anjian Xie ◽  
Yuhua Shen ◽  
Jinmiao Zhu ◽  
Hongying Li

RSC Advances ◽  
2021 ◽  
Vol 11 (22) ◽  
pp. 13085-13090
Author(s):  
Shuang Han ◽  
Aixin Yao ◽  
Yuan Wang

In this research, we used GO as the support material, IL as the stabilizer, CA153 as the template and DA as the functional monomer for the preparation of GMIPs. The GMIP was successfully used as an enrichment agent for the selective enrichment of CA153.


2021 ◽  
Vol 55 (9-10) ◽  
pp. 1163-1175
Author(s):  
YAN HAO ◽  
◽  
JING QU ◽  
ZUNYI LIU ◽  
SONGBO LI ◽  
...  

A novel adsorbent made of porous cellulose/graphene oxide composite microspheres (PCGCM) was synthesized in [Bmim]Cl ionic liquid. The as-prepared PCGCM was evaluated for the removal of Ce (III) via static adsorption experiments. The results showed that the adsorption equilibrium of Ce (III) onto PCGCM was achieved within 50 min and the adsorption was highly pH dependent. An excellent adsorption capacity as high as 415.1 mg•g-1 was obtained at a pH of 4.9, which was much higher than most adsorbents reported in the literature. The pseudo-second order kinetic model and Langmuir isotherm model were found to fit the adsorption behavior of PCGCM well. The XPS analysis confirmed that the adsorption was based on the ion exchange mechanism. Meanwhile, PCGCM could be regenerated with 1 mol•L-1 HCl for repetitious adsorption of Ce (III). This work provides an attractive approach for the removal of rare earth ions as pollutants.


Polymers ◽  
2018 ◽  
Vol 10 (12) ◽  
pp. 1329 ◽  
Author(s):  
Lingyu Liu ◽  
Xudong Zhu ◽  
Yanbo Zeng ◽  
Hailong Wang ◽  
Yixia Lu ◽  
...  

In this paper, we report a new composite of reduced graphene oxide/Fe3O4-ionic liquid based molecularly imprinted polymer (RGO/Fe3O4-IL-MIP) fabricated for diphenylamine (DPA) detection. RGO/Fe3O4-IL-MIP was prepared with RGO/Fe3O4 as supporter, ionic liquid 1-vinyl-3-butylimidazolium hexafluorophosphate ([VC4mim][PF6]) as functional monomer, ionic liquid 1,4-butanediyl-3,3’-bis-l-vinylimidazolium dihexafluorophosphate ([V2C4(mim)2][(PF6)2]) as cross-linker, and diphenylamine (DPA) as template molecule. Fourier transform infrared spectroscopy, thermal gravimetric analysis, scanning electron microscopy, and vibrating sample magnetometer were employed to characterize the RGO/Fe3O4-IL-MIP composite. RGO/Fe3O4-IL-MIP was then drop-cast onto a glassy carbon electrode to construct an electrochemical sensor for DPA. The differential pulse voltammetry (DPV) peak current response for 20 μM DPA of RGO/Fe3O4-IL-MIP modified glassy carbon electrode (GCE) was 3.24 and 1.68 times that of RGO/Fe3O4-IL-NIP and RGO/Fe3O4-EGDMA-MIP modified GCEs, respectively, indicating the advantage of RGO/Fe3O4-IL-MIP based on ionic liquid (IL) as a cross-linker. The RGO/Fe3O4-IL-MIP sensor demonstrated good recognition for DPA. Under the optimized conditions, the RGO/Fe3O4-IL-MIP sensor exhibited a DPA detection limit of 0.05 μM (S/N = 3) with a linear range of 0.1–30 μM. Moreover, the new RGO/Fe3O4-IL-MIP based sensor detected DPA in real samples with satisfactory results.


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