A predictive method for constructing the distillation curve of petroleum fluids using their physical bulk properties

2021 ◽  
Vol 200 ◽  
pp. 108403
Author(s):  
Pouya Hosseinifar ◽  
Hamidreza Shahverdi
2003 ◽  
Vol 775 ◽  
Author(s):  
Byeongchan Lee ◽  
Kyeongjae Cho

AbstractWe investigate the surface kinetics of Pt using the extended embedded-atom method, an extension of the embedded-atom method with additional degrees of freedom to include the nonbulk data from lower-coordinated systems as well as the bulk properties. The surface energies of the clean Pt (111) and Pt (100) surfaces are found to be 0.13 eV and 0.147 eV respectively, in excellent agreement with experiment. The Pt on Pt (111) adatom diffusion barrier is found to be 0.38 eV and predicted to be strongly strain-dependent, indicating that, in the compressive domain, adatoms are unstable and the diffusion barrier is lower; the nucleation occurs in the tensile domain. In addition, the dissociation barrier from the dimer configuration is found to be 0.82 eV. Therefore, we expect that atoms, once coalesced, are unlikely to dissociate into single adatoms. This essentially tells that by changing the applied strain, we can control the patterning of nanostructures on the metal surface.


2021 ◽  
Vol 5 (3) ◽  
Author(s):  
Stefan A. Seidl ◽  
Bernhard Kretz ◽  
Christian Gehrmann ◽  
David A. Egger
Keyword(s):  

1981 ◽  
Vol 17 (11) ◽  
pp. 619-621 ◽  
Author(s):  
V. E. Emel'yanov ◽  
V. P. Grebenshchikov ◽  
V. F. Golosova ◽  
G. N. Baranova

Author(s):  
J. S. Chin

A practical engineering calculation method has been formulated for commercial multicomponent fuel stagnant droplet evaporation with variable finite mass and thermal diffusivity. Instead of solving the transient liquid phase mass and heat transfer partial differential equation set, a totally different approach is used. With zero or infinite mass diffusion resistance in liquid phase, it is possible to obtain vapor pressure and vapor molecular mass based on the distillation curve of these turbine fuels. It is determined that Peclet number (Pef) is a suitable parameter to represent the mass diffusion resistance in liquid phase. The vapor pressure and vapor molecular mass at constant finite Pef is expressed as a function of finite Pef, vapor pressure, and molecular mass at zero Pef and infinite Pef. At any time step, with variable finite Pef, the above equation is still valid, and PFsPef=∞, PFsPef=0, MfvPef=∞, MfvPef=0 are calculated from PFsPef≡∞, PFsPef≡0, MfvPef≡∞, MfvPef≡0, thus PFs and Mfv can be determined in a global way which eventually is based on the distillation curve of fuel. The explicit solution of transient heat transfer equation is used to have droplet surface temperature and droplet average temperature as a function of surface Nusselt number and non-dimensional time. The effect of varying com position of multi-component fuel evaporation is taken into account by expressing the properties as a function of molecular mass, acentric factor, critical temperature, and critical pressure. A specific calculation method is developed for liquid fuel diffusion coefficient, also special care is taken to calculate the binary diffusion coefficient of fuel vapor-air in gaseous phase. The effect of Stefan flow and natural convection has been included. The predictions from the present evaporation model for different turbine fuels under very wide temperature ranges have been compared with experimental data with good agreement.


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