Non-equilibrium thermodynamic potential and flux fluctuation theorem

2009 ◽  
Vol 373 (37) ◽  
pp. 3301-3303 ◽  
Author(s):  
M. Criado-Sancho ◽  
J. Casas-Vázquez ◽  
D. Jou
Entropy ◽  
2020 ◽  
Vol 22 (3) ◽  
pp. 293
Author(s):  
Gleb A. Zhernokleev ◽  
Leonid M. Martyushev

Nonlinear non-equilibrium thermodynamic relations have been constructed based on the generalized Ehrenfest–Klein model. Using these relations, the behavior of the entropy and its production in time at arbitrary deviations from equilibrium has been studied. It has been shown that the transient fluctuation theorem is valid for this model if a dissipation functional is treated as the thermodynamic entropy production.


Energy ◽  
2020 ◽  
Vol 208 ◽  
pp. 118348
Author(s):  
Zhihao Guo ◽  
Shuai Deng ◽  
Yu Zhu ◽  
Li Zhao ◽  
Xiangzhou Yuan ◽  
...  

Symmetry ◽  
2019 ◽  
Vol 11 (3) ◽  
pp. 433 ◽  
Author(s):  
Lee Jinwoo

Sagawa and Ueda established a fluctuation theorem of information exchange by revealing the role of correlations in stochastic thermodynamics and unified the non-equilibrium thermodynamics of measurement and feedback control. They considered a process where a non-equilibrium system exchanges information with other degrees of freedom such as an observer or a feedback controller. They proved the fluctuation theorem of information exchange under the assumption that the state of the other degrees of freedom that exchange information with the system does not change over time while the states of the system evolve in time. Here we relax this constraint and prove that the same form of the fluctuation theorem holds even if both subsystems co-evolve during information exchange processes. This result may extend the applicability of the fluctuation theorem of information exchange to a broader class of non-equilibrium processes, such as a dynamic coupling in biological systems, where subsystems that exchange information interact with each other.


2016 ◽  
Vol 18 (36) ◽  
pp. 24966-24983 ◽  
Author(s):  
Wolfgang Dreyer ◽  
Clemens Guhlke ◽  
Rüdiger Müller

Butler–Volmer equations can be recovered from a complete non-equilibrium thermodynamic model by application of asymptotic analysis. Thereby we gain insight into the coupling of different physical phenomena and can derive Butler–Volmer equations for very different materials and electrochemical systems.


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