Direct C–N bond formation in an in situ ligand transformation reaction and formation of polymeric 1D cadmium(II) complexes with end-to-end bridging thiocyanate or selenocyanate ions: Synthesis, structures and theoretical studies

Polyhedron ◽  
2017 ◽  
Vol 133 ◽  
pp. 8-15 ◽  
Author(s):  
Mehul H. Sadhu ◽  
Ankita Solanki ◽  
T. Kundu ◽  
Vinayak Hingu ◽  
B. Ganguly ◽  
...  
2021 ◽  
Author(s):  
Alexander Ahrens ◽  
Danilo M. Lustosa ◽  
Leonhard F. P. Karger ◽  
Marvin Tim Hoffmann ◽  
Matthias Rudolph ◽  
...  

The reactivity of cationic (C^C)gold(III) carbonyl complexes was investigated. While the in situ-formed IPrAu(bph)CO+ complex (bph = biphenyl-2,2’-diyl) does not undergo a migratory insertion of CO into the neighboring gold-carbon...


ChemInform ◽  
2009 ◽  
Vol 40 (44) ◽  
Author(s):  
Remi Martinez ◽  
Marc-Olivier Simon ◽  
Reynald Chevalier ◽  
Cyrielle Pautigny ◽  
Jean-Pierre Genet ◽  
...  

ACS Catalysis ◽  
2021 ◽  
pp. 560-567
Author(s):  
Philippe Steinsoultz ◽  
Aurélien Bailly ◽  
Patrick Wagner ◽  
Estefania Oliva ◽  
Martine Schmitt ◽  
...  

Holzforschung ◽  
2017 ◽  
Vol 71 (9) ◽  
pp. 713-723 ◽  
Author(s):  
Francisco Arriaga ◽  
Daniel F. Llana ◽  
Miguel Esteban ◽  
Guillermo Íñiguez-González

Abstract The mechanical properties of timber can be estimated from wave propagation velocity by measuring wave time-of-flight (ToF). However, a time-lag complicates the measurements, which produces an apparent velocity dependency on length and this species and instrument dependent property is also influenced by knottiness. This research is dealing with time-lag determination by different sensor positioning in situ ToF measurements. ToF longitudinal measurements were conducted on 120 90 mm×140 mm specimens of the coniferous species radiata pine, Scots pine, laricio pine and maritime pine. The following commercially available acoustic devices were used: Sylvatest Duo, USLab, and Microsecond Timer. The sensors were arranged for the measurement types “end-to-end”, “on the same surface” and “on opposite surfaces”. ToF data were obtained from the full-length (4 m) specimens and then from the same specimens shortened to 3 m, 2 m and 1 m in length. The in situ procedures of ToF are applicable for a reliable length determination independently from the time-lag (tL) and velocity. The differences observed by end-to-end measurements, with respect to velocity, are below 4.4%. A velocity correction factor can be deduced for each instrument, which is independent of species.


2010 ◽  
Vol 6 (1) ◽  
pp. 970868 ◽  
Author(s):  
G. W. Eidson ◽  
S. T. Esswein ◽  
J. B. Gemmill ◽  
J. O. Hallstrom ◽  
T. R. Howard ◽  
...  

Water resources are under unprecedented strain. The combined effects of population growth, climate change, and rural industrialization have led to greater demand for an increasingly scarce resource. Ensuring that communities have adequate access to water—an essential requirement for community health and prosperity—requires finegrained management policies based on real-time in situ data, both environmental and hydrological. To address this requirement at the state level, we have developed the South Carolina Digital Watershed, an end-to-end system for monitoring water resources. In this paper, we describe the design and implementation of the core system components: (i) in situ sensing hardware, (ii) collection and uplink facilities, (iii) data streaming middleware, and (iv) back-end repository and presentation services. We conclude by discussing key organizational and technical challenges encountered during the development process.


2017 ◽  
Vol 53 (71) ◽  
pp. 9930-9933 ◽  
Author(s):  
Yijue Xu ◽  
Lysiane Champion ◽  
Bulat Gabidullin ◽  
David L. Bryce

In situ 31P solid-state NMR studies of mechanochemical halogen bond formation provide insights into the cocrystallisation process and an estimate of the activation energy.


CCS Chemistry ◽  
2020 ◽  
pp. 2764-2771
Author(s):  
Bao-Gui Cai ◽  
Shuai-Shuai Luo ◽  
Lin Li ◽  
Lei Li ◽  
Jun Xuan ◽  
...  

2021 ◽  
Vol 8 ◽  
Author(s):  
Katie Winkle ◽  
Emmanuel Senft ◽  
Séverin Lemaignan

Participatory design (PD) has been used to good success in human-robot interaction (HRI) but typically remains limited to the early phases of development, with subsequent robot behaviours then being hardcoded by engineers or utilised in Wizard-of-Oz (WoZ) systems that rarely achieve autonomy. In this article, we present LEADOR (Led-by-Experts Automation and Design Of Robots), an end-to-end PD methodology for domain expert co-design, automation, and evaluation of social robot behaviour. This method starts with typical PD, working with the domain expert(s) to co-design the interaction specifications and state and action space of the robot. It then replaces the traditional offline programming or WoZ phase by an in situ and online teaching phase where the domain expert can live-program or teach the robot how to behave whilst being embedded in the interaction context. We point out that this live teaching phase can be best achieved by adding a learning component to a WoZ setup, which captures implicit knowledge of experts, as they intuitively respond to the dynamics of the situation. The robot then progressively learns an appropriate, expert-approved policy, ultimately leading to full autonomy, even in sensitive and/or ill-defined environments. However, LEADOR is agnostic to the exact technical approach used to facilitate this learning process. The extensive inclusion of the domain expert(s) in robot design represents established responsible innovation practice, lending credibility to the system both during the teaching phase and when operating autonomously. The combination of this expert inclusion with the focus on in situ development also means that LEADOR supports a mutual shaping approach to social robotics. We draw on two previously published, foundational works from which this (generalisable) methodology has been derived to demonstrate the feasibility and worth of this approach, provide concrete examples in its application, and identify limitations and opportunities when applying this framework in new environments.


2009 ◽  
Vol 304 (1-2) ◽  
pp. 153-158 ◽  
Author(s):  
A. Murugadoss ◽  
Papori Goswami ◽  
Anumita Paul ◽  
Arun Chattopadhyay

Sign in / Sign up

Export Citation Format

Share Document