The effect of zirconium incorporation on the thermal stability and carbonized product of phenol–formaldehyde resin

2014 ◽  
Vol 102 ◽  
pp. 180-185 ◽  
Author(s):  
Changqing Liu ◽  
Kezhi Li ◽  
Hejun Li ◽  
Shouyang Zhang ◽  
Yulei Zhang
2010 ◽  
Vol 150-151 ◽  
pp. 429-432
Author(s):  
Chuan Bai Yu ◽  
Chun Wei ◽  
Dong Ming Pan

The objective of this research was to investigate thermal stability and dynamic mechanical behavior of nano-SiO2/phenol formaldehyde resin (PF) nanocomposites with various nano-SiO2 at 2 wt% loading content. The nano-SiO2/PF nanocomposites were fabricated by two-roll compounding and compression molding technology. The storage modulus (E′) at the starting point of 50 was increased by adding various nano-SiO2 into PF matrix. The E′ of the nanocomposite with only 2 wt% of SiO2 synthesized under ultrasonic irradiation (U-SiO2) was 2 times higher than that of the control PF. Thermal expansion and the coefficient of thermal expansion of nano-SiO2 loaded nanocomposites were lower than that of the control PF in the range of 100–200 and 200–250 . Thermogravimetric analysis demonstrated that the thermal stability of nanocomposites was evidently enhanced. In comparison, U-SiO2 reinforced nanocomposites showed higher thermal properties than those reinforced by mesoporous silica (SBA-15) and SiO2 synthesized by stirring (S-SiO2).


2020 ◽  
pp. 34-43
Author(s):  
N. R. Memetov ◽  
◽  
A. V. Gerasimova ◽  
A. E. Kucherova ◽  
◽  
...  

The paper evaluates the effectiveness of the use of graphene nanostructures in the purification of lead (II) ions to improve the ecological situation of water bodies. The mechanisms and characteristic parameters of the adsorption process were analyzed using empirical models of isotherms at temperatures of 298, 303, 313 and 323 K, which correspond to the following order (based on the correlation coefficient): Langmuir (0.99) > Temkin (0.97) > Dubinin – Radushkevich (0.90). The maximum adsorption capacity of the material corresponds to the range from 230 to 260 mg/g. We research the equilibrium at the level of thermodynamic parameter estimates, which indicates the spontaneity of the process, the endothermic nature and structure change of graphene modified with phenol-formaldehyde resin during the adsorption of lead (II) ions, leading to an increase in the disorder of the system.


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