A comparison of small doses (up to 0.7 mass part) of impact strength modifiers of foreign and domestic production in polyvinylchloride-based compositions is given. Domestic acrylicnitrile- butadiene styrene modifiers (ABS) were used. The developed shock-resistant polyvinylchloride compositions in the presence of ABS elastifier have high melt fluidity, which has a beneficial effect on the recyclability. Changes in supramolecular structure were estimated from thermomechanical testing and electron microscopy data for both unfilled and filled PVC samples. Thermomechanical analysis showed that the presence of ABS modifier had a favorable effect on the technological properties of PVC-based samples. Electron-microscopic images indicate that in unfilled PVC samples, the heterogeneous PVC structure is expressed in the presence of ABS copolymer in comparison with foreign acrylic modifiers. When the compositions are filled with micro-heterogeneous structure in dispersion medium, the filler-polymer is formed by chalk particles, while ABS elasticifier is at the phase interface. Due to the peculiarities of the structure ABS has a higher degree of “fixation” on the surface of the chalk particles in comparison with the basic compositions containing acrylic modifiers, which with increasing chalk concentration leads to lower wear and tear on the top of the forming equipment.
Effect of backbone and end-group regioisomerism on thermomechanical properties of vanillin-based polyurethane networks
