Non-isothermal crystallization kinetics of Poly(Butylene succinate) (PBS) nanocomposites with different modified carbon nanotubes

Polymer ◽  
2018 ◽  
Vol 146 ◽  
pp. 361-377 ◽  
Author(s):  
Tugay Yarici ◽  
Mehmet Kodal ◽  
Guralp Ozkoc
Keyword(s):  
Carbon Nanotubes ◽  
Crystallization Kinetics ◽  
Isothermal Crystallization ◽  
Butylene Succinate ◽  
Isothermal Crystallization Kinetics ◽  
Modified Carbon Nanotubes ◽  
Kinetics Of

Non-Isothermal Crystallization Kinetics of Graphene Oxide-Carbon Nanotubes Hybrids / Polyamide 6 Composites

2019 ◽  
Vol 41 (3) ◽  
pp. 394-394
Author(s):  
Zhi Qiang Wang Zhi Qiang Wang ◽  
Yong Ke Zhao and Xiang Feng Wu Yong Ke Zhao and Xiang Feng Wu
Keyword(s):  
Carbon Nanotubes ◽  
Graphene Oxide ◽  
Cooling Rate ◽  
Crystallization Kinetics ◽  
Isothermal Crystallization ◽  
Crystallization Rate ◽  
Polyamide 6 ◽  
Degree Of Crystallinity ◽  
Isothermal Crystallization Kinetics ◽  
Kinetics Of

The hybrids combined by nano-materials with different dimensions usually possess much better enhancement effects than single one. Graphene oxide-carbon nanotubes hybrids / polyamide 6 composites has been fabricated. The non-isothermal crystallization kinetics of the as-prepared samples was discussed. Research results showed that increasing the cooling rate was in favor of increasing the crystallization rate and the degree of crystallinity for the as-prepared samples. Moreover, the crystallization rate was first decreased and then increased with increasing the hybrids loading. Furthermore, the crystallization mechanism was changed with increasing the crystallization temperature and the cooling rate. The nucleation and growth modes of the non-isothermal crystallization could be classified into three different types, according to the Ozawa’s theory. These complicated results could be attributed to the important role of crystallization rate as well as the simultaneous hindering and promoting effects of the as-prepared hybrids. This work has reference values for understanding the crystallization kinetics of the polyamide 6-based composites.

scholarly journals Morphology, Nucleation, and Isothermal Crystallization Kinetics of Poly(Butylene Succinate) Mixed with a Polycarbonate/MWCNT Masterbatch

Polymers ◽  
2018 ◽  
Vol 10 (4) ◽  
pp. 424 ◽  
Author(s):  
Thandi Gumede ◽  
Adriaan Luyt ◽  
Ricardo Pérez-Camargo ◽  
Agnieszka Tercjak ◽  
Alejandro Müller
Keyword(s):  
Crystallization Kinetics ◽  
Isothermal Crystallization ◽  
Butylene Succinate ◽  
Isothermal Crystallization Kinetics ◽  
Kinetics Of

Effects of Attapulgite on the Isothermal Crystallization Behavior of Poly(Butylene Succinate-co-Butylene Adipate)

2013 ◽  
Vol 791-793 ◽  
pp. 56-59
Author(s):  
Zhi Guo Qi ◽  
Jin Nan Chen ◽  
Bao Hua Guo ◽  
Yu Zhang
Keyword(s):  
Crystallization Kinetics ◽  
Crystallization Temperature ◽  
Isothermal Crystallization ◽  
Crystallization Behavior ◽  
Growth Form ◽  
Crystallization Rate ◽  
Melt Mixing ◽  
Butylene Succinate ◽  
Isothermal Crystallization Kinetics ◽  
Kinetics Of

Poly (butylene succinate-co-butylene adipate)/attapulgite nanocomposites were prepared by melt mixing in a HAAKE mixer. The crystallization kinetics of PBSA and its nanocomposites was studied under isothermal conditions by differential scanning calorimetr. The isothermal crystallization kinetics results indicated that attapulgite can induce heterogeneous nucleation, resulting in an improvement on the crystallization temperature and crystallization rate. Both the PBSA and its nanocomposites were correlated to the spherulitic growth form.

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