Anticorrosive polypyrrole/zirconium-oxide composite film prepared in oxalic acid and dodecylbenzene sulfonic acid mix electrolyte

2020 ◽  
Vol 147 ◽  
pp. 105815
Author(s):  
Merve Menkuer ◽  
Hatice Ozkazanc
The Analyst ◽  
2019 ◽  
Vol 144 (6) ◽  
pp. 1960-1967 ◽  
Author(s):  
Chao Chen ◽  
Pengcheng Zhao ◽  
Meijun Ni ◽  
Chunyan Li ◽  
Yixi Xie ◽  
...  

A temperature-induced sensing film consisting of poly(N-vinylcaprolactam) (PVCL), graphene oxide (GO) and glucose oxidase (GOD) was fabricated and used to modify a glassy carbon electrode (GCE).


Author(s):  
Uta Ulrich ◽  
Matthias Pfannerstill ◽  
Guido Ostendorp ◽  
Nicola Fohrer

AbstractThe research of the environmental fate of pesticides has demonstrated that applied compounds are altered in their molecular structure over time and are distributed within the environment. To assess the risk for contamination by transformation products (TP) of the herbicides flufenacet and metazachlor, the following four water body types were sampled in a small-scale catchment of 50 km2 in 2015/2016: tile drainage water, stream water, shallow groundwater, and drinking water of private wells. The TP were omnipresent in every type of water body, more frequently and in concentrations up to 10 times higher than their parent compounds. Especially metazachlor sulfonic acid, metazachlor oxalic acid, and flufenacet oxalic acid were detected in almost every drainage and stream sample. The transformation process leads to more mobile and more persistent molecules resulting in higher detection frequencies and concentrations, which can even occur a year or more after the application of the parent compound. The vulnerability of shallow groundwater and private drinking water wells to leaching compounds is proved by numerous positives of metazachlor-TP with maximum concentrations of 0.7 μg L−1 (drinking water) and 20 μg L−1 (shallow groundwater) of metazachlor sulfonic acid. Rainfall events during the application period cause high discharge of the parent compound and lower release of TP. Later rainfall events lead to high displacement of TP. For an integrated risk assessment of water bodies, the environmental behavior of pesticide-TP has to be included into regular state-of-the-art water quality monitoring.


2003 ◽  
Vol 66 (1) ◽  
pp. 115-119 ◽  
Author(s):  
J. JEAN ◽  
J.-F. VACHON ◽  
O. MORONI ◽  
A. DARVEAU ◽  
I. KUKAVICA-IBRULJ ◽  
...  

Six commercial disinfectants were tested for their efficacy in inactivating hepatitis A virus in solution or attached to agri-food surfaces. Disinfectant I contains 10% quaternary ammonium plus 5% glutaraldehyde;disinfectant II contains 12% sodium hypochlorite; disinfectant III contains 2.9% dodecylbenzene sulfonic acid plus 16% phosphoric acid; disinfectant IV contains 10% quaternary ammonium; disinfectant V contains 2% iodide; and disinfectant VI contains 2% stabilized chlorine dioxide. Among these, disinfectants I and II were shown to be the most effective in inactivating hepatitis A virus in solution. The efficacy of these disinfectants was further tested against hepatitis A virus attached to common agri-food surfaces, including polyvinyl chlorine, high-density polyethylene, aluminum, stainless steel, and copper. Disinfectant II was shown to be the most effective, with a maximum inactivation level of about 3 log10. The inactivation efficacy was shown to be affected by the concentration of the active ingredient, the contact time between the disinfectant and the contaminated surfaces, and the incubation temperature. In general, hepatitis A virus was shown to be highly resistant to most disinfectants tested, and high concentrations of active ingredient were needed to achieve acceptable inactivation levels.


e-Polymers ◽  
2008 ◽  
Vol 8 (1) ◽  
Author(s):  
Chia-Fu Chen ◽  
Chi-an Dai ◽  
Wen-Yen Chiu

AbstractIn this work, poly(3-ethylenedioxythiophene) (PEDOT) was synthesized on glass by spin coating for 10 seconds at 500 rpm and polymerization was carried out in an oven at 110°C for 10 min. Methanol and water mixture were used as the solvent and dodecylbenzene sulfonic acid (DBSA) as the surfactant. The conductivities of films were measured and their relationship with different solvent or various surfactant contents were discussed. The morphology of films was observed by SEM, and PEDOT synthesized in methanol-rich solvents or with less DBSA content had more smooth surfaces, showed lower degradation temperature (by TGA). Also, PEDOT synthesized in methanol-rich solvents or with less DBSA were doped better, as observed by UV-Vis spectra.


Biosensors ◽  
2016 ◽  
Vol 6 (3) ◽  
pp. 31 ◽  
Author(s):  
Nor Ahmad ◽  
Jaafar Abdullah ◽  
Nor Yusof ◽  
Ahmad Ab Rashid ◽  
Samsulida Abd Rahman ◽  
...  

2014 ◽  
Vol 144 (3) ◽  
pp. 369-376 ◽  
Author(s):  
Di Zhang ◽  
Yeqiong Zhang ◽  
Huiyuan Ma ◽  
Hong Yan ◽  
Yongbin Song

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