High-performance UV-curable epoxy acrylate nanocomposite coatings reinforced with aramid nanofibers

2022 ◽  
Vol 163 ◽  
pp. 106631
Author(s):  
Ying Wang ◽  
Rongjun Qu ◽  
Yuankai Pan ◽  
Yuexin Luo ◽  
Ying Zhang ◽  
...  
Keyword(s):  
High Performance ◽  
Nanocomposite Coatings ◽  
Epoxy Acrylate ◽  
Uv Curable

Preparation and properties of novel high performance UV-curable epoxy acrylate/hyperbranched polysiloxane coatings

2012 ◽  
Vol 74 (1) ◽  
pp. 142-150 ◽  
Author(s):  
Ping Liu ◽  
Aijuan Gu ◽  
Guozheng Liang ◽  
Qingbao Guan ◽  
Li Yuan
Keyword(s):  
High Performance ◽  
Epoxy Acrylate ◽  
Uv Curable ◽  
Hyperbranched Polysiloxane

scholarly journals Preparation and Properties of Plant-Oil-Based Epoxy Acrylate-Like Resins for UV-Curable Coatings

Polymers ◽  
2020 ◽  
Vol 12 (9) ◽  
pp. 2165
Author(s):  
Jijun Tang ◽  
Jinshuai Zhang ◽  
Jianyu Lu ◽  
Jia Huang ◽  
Fei Zhang ◽  
...  
Keyword(s):  
High Performance ◽  
Seed Oil ◽  
Plant Oils ◽  
Epoxy Acrylate ◽  
Plant Oil ◽  
Rubber Seed Oil ◽  
Uv Curable ◽  
Ring Opening Reaction ◽  
Epoxy Value ◽  
Acid Precursor

Novel oil-based epoxy acrylate (EA)-like prepolymers were synthesized via the ring-opening reaction of epoxidized plant oils with a new unsaturated carboxyl acid precursor (MAAMA) synthesized by reacting maleic anhydride (MA) with methallyl alcohol (MAA). Since the employed epoxidized oils including epoxidized soybean oil (ESO), epoxidized rubber seed oil (ERSO), and epoxidized wilsoniana seed oil (EWSO) possessed epoxy values of 7.34–4.38%, the obtained epoxy acrylate (EA)-like prepolymers (MMESO, MMERSO, and MMEWSO) indicated a C=C functionality of 7.81–4.40 per triglyceride. Furthermore, effects of the C=C functionality and the addition of hydroxyethyl methacrylate (HEMA) diluent on the ultimate properties of the resulting UV-cured EA-like materials were investigated and compared with those of commercially available acrylated ESO (AESO) resins. As the C=C functionality increased, the storage modulus at 25 °C (E’25), glass transition temperature (Tg), 5% weight–loss temperature (T5), tensile strength and modulus (σ and E), and hardness of the coating for both the pure EA and EA/HEMA resins increased significantly as well. These properties indicated similar trends when comparing the EA materials with 30% of HEMA with those pure EA materials. Specially, although ERSO had a clearly lower epoxy value that ESO, both the UV-cured pure MMERSO and MMERSO/HEMA materials showed much better E’25, Tg, σ, and E than their AESO counterparts, indicating that the MAAMA modification of epoxidized plant oils was much more effective than the modification of acrylic acid to achieve high-performance oil-based epoxy acrylate resins.

High-Performance Soybean-Oil-Based Epoxy Acrylate Resins: “Green” Synthesis and Application in UV-Curable Coatings

2018 ◽  
Vol 6 (7) ◽  
pp. 8340-8349 ◽  
Author(s):  
Qiong Wu ◽  
Yun Hu ◽  
Jijun Tang ◽  
Jing Zhang ◽  
Cuina Wang ◽  
...  
Keyword(s):  
Soybean Oil ◽  
Green Synthesis ◽  
High Performance ◽  
Epoxy Acrylate ◽  
Uv Curable

POSS-functionalized polyphosphazene nanotube: preparation and effective reinforcement on UV-curable epoxy acrylate nanocomposite coatings

RSC Advances ◽  
2016 ◽  
Vol 6 (4) ◽  
pp. 3025-3031 ◽  
Author(s):  
Siyu Li ◽  
Shuilai Qiu ◽  
Bin Yu ◽  
Gang Tang ◽  
Weiyi Xing ◽  
...  
Keyword(s):  
Efficient Method ◽  
Nanocomposite Coatings ◽  
Epoxy Acrylate ◽  
Uv Curable ◽  
Effective Reinforcement

This study presents an efficient method of preparing functionalized poly(cyclotriphosphazene-co-4,4′-sulfonyldiphenol) (PZS) nanotube reinforced UV-curable materials.

scholarly journals 3D Printing of High Viscosity Reinforced Silicone Elastomers

Polymers ◽  
2021 ◽  
Vol 13 (14) ◽  
pp. 2239
Author(s):  
Nicholas Rodriguez ◽  
Samantha Ruelas ◽  
Jean-Baptiste Forien ◽  
Nikola Dudukovic ◽  
Josh DeOtte ◽  
...  
Keyword(s):  
Mechanical Properties ◽  
High Performance ◽  
New Technologies ◽  
Three Dimensional ◽  
High Viscosity ◽  
Layer By Layer ◽  
Silicone Elastomers ◽  
Uv Curable ◽  
Octet Truss ◽  
Tunable Mechanical Properties

Recent advances in additive manufacturing, specifically direct ink writing (DIW) and ink-jetting, have enabled the production of elastomeric silicone parts with deterministic control over the structure, shape, and mechanical properties. These new technologies offer rapid prototyping advantages and find applications in various fields, including biomedical devices, prosthetics, metamaterials, and soft robotics. Stereolithography (SLA) is a complementary approach with the ability to print with finer features and potentially higher throughput. However, all high-performance silicone elastomers are composites of polysiloxane networks reinforced with particulate filler, and consequently, silicone resins tend to have high viscosities (gel- or paste-like), which complicates or completely inhibits the layer-by-layer recoating process central to most SLA technologies. Herein, the design and build of a digital light projection SLA printer suitable for handling high-viscosity resins is demonstrated. Further, a series of UV-curable silicone resins with thiol-ene crosslinking and reinforced by a combination of fumed silica and MQ resins are also described. The resulting silicone elastomers are shown to have tunable mechanical properties, with 100–350% elongation and ultimate tensile strength from 1 to 2.5 MPa. Three-dimensional printed features of 0.4 mm were achieved, and complexity is demonstrated by octet-truss lattices that display negative stiffness.

UV-curable hyperbranched nanocomposite coatings

2006 ◽  
Vol 55 (3) ◽  
pp. 284-290 ◽  
Author(s):  
Linda Fogelström ◽  
Per Antoni ◽  
Eva Malmström ◽  
Anders Hult
Keyword(s):  
Nanocomposite Coatings ◽  
Uv Curable

Designing efficient UV-curable flame-retardant and antimicrobial wood coating: Phosphorodiamidate reactive diluent with epoxy acrylate

2021 ◽  
Vol 28 (10) ◽  
Author(s):  
Pundalik Mali ◽  
Narendra Sonawane ◽  
Vikas Patil ◽  
Ravi Mawale ◽  
Nilesh Pawar
Keyword(s):  
Flame Retardant ◽  
Epoxy Acrylate ◽  
Reactive Diluent ◽  
Wood Coating ◽  
Uv Curable

scholarly journals Studying the Influence of Mica Particle Size on the Properties of Epoxy Acrylate/Mica Composite Coatings through Reducing Mica Particle Size by the Ball-Milled Method

Coatings ◽  
2022 ◽  
Vol 12 (1) ◽  
pp. 98
Author(s):  
Yaling Da ◽  
Jianxing Liu ◽  
Zixian Gao ◽  
Xiangxin Xue
Keyword(s):  
Particle Size ◽  
Ball Milling ◽  
Composite Coatings ◽  
High Energy ◽  
Particle Sizes ◽  
Epoxy Acrylate ◽  
Pencil Hardness ◽  
Uv Curable ◽  
Chemical Structures ◽  
Mica Composite

In this work, a series of epoxy acrylate (EA)/mica composite coatings were synthesized through introducing mica powders of different particle size into epoxy acrylate coatings and using an ultraviolet (UV) curing technique to investigate the influence of mica particle size on the coatings. Mica powders of different particle sizes were obtained by ball-milling for 4, 8, 12, 16, and 20 h with a planetary high-energy ball mill. The particle size and morphologies of ball-milled mica powders were characterized by laser particle size analyzer and scanning electron microscopy (SEM). The results indicated that planetary ball-milling reduced the particle size of mica powders effectively. Mica powders that were un-ball-milled and ball-milled were added into the epoxy acrylate matrix by a blending method to synthesize the organic-inorganic UV curable coatings. The optical photographs of the coatings showed greater stability of liquid mixtures with smaller particle size fillers. The chemical structures of EA/mica composite coatings were investigated by Fourier transform infrared spectroscopy (FTIR), and the conversion rate of C=C bonds was calculated. The results indicated that the C=C conversion of coatings with mica powders of smaller particle sizes was higher. Tests of mechanical properties and tests using electrochemical impedance spectroscopy (EIS) showed that pencil hardness, impact resistance, and coating resistance were improved due to the reduction of mica powders particle size.

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