Synthesis of spherical metal oxide particles using homogeneous precipitation of aqueous solutions of metal sulfates with urea

2006 ◽  
Vol 169 (1) ◽  
pp. 33-40 ◽  
Author(s):  
Jan Šubrt ◽  
Václav Štengl ◽  
Snejana Bakardjieva ◽  
Lorant Szatmary
Author(s):  
Hammad Younes ◽  
Haiping Hong ◽  
G. P. Peterson

AbstractA better understanding of the bonding and aggregation processes occurring between carbon nanomaterials and metal oxide particles in aqueous solutions is important in the development of novel nanosolids for applications in the areas of sensor development, highly conductive paint, nanotube alignment, polymer composites, Li-ion batteries, and many other areas. The current investigation reviews these processes and presents a detailed description of the aggregation processes occurring between carbon nanomaterials and metal oxide particles (metals) in various aqueous solutions. The results indicate that the charge attraction between the particles results in a strong homogeneous bonding that occurs within the aqueous solution and for the first time demonstrate and describe the aggregation process of these nanoparticles. The relative importance of many parameters that impact the aggregation process is identified and discussed, and guidelines for controlling the aggregation process are presented. This is a simple and cost-effective process to manufacture a novel nano-solid based on carbon nano-material and metal oxide. In addition, the process is easy to scale up and optimize. The methodology could lead to many significant applications as well as commercialization.


ChemInform ◽  
2010 ◽  
Vol 25 (30) ◽  
pp. no-no
Author(s):  
M. S. EL-SHALL ◽  
W. SLACK ◽  
W. VANN ◽  
D. KANE ◽  
D. HANLEY

2019 ◽  
Vol 26 (6) ◽  
pp. 1986-1995 ◽  
Author(s):  
Akinobu Yamaguchi ◽  
Ikuo Okada ◽  
Ikuya Sakurai ◽  
Hirokazu Izumi ◽  
Mari Ishihara ◽  
...  

Synthesis and immobilization of caltrop cupric particles onto a Si substrate using X-ray radiolysis directly from a liquid solution of Cu(COOCH3)2 is demonstrated. Caltrop cupric oxide particles are formed in the X-ray radiolysis of aqueous solutions of Cu(COOCH3)2, which also contain methanol, ethanol, 2-propanol or 1-propanol as ^\bulletOH scavenger. The blade lengths of the caltrop particles are dependent on the alcohol chain length. In particular, it was found that an alkyl alcohol whose chain length is longer than four is unable to synthesize any particles in aqueous solutions of Cu(COOCH3)2 in X-ray radiolysis. These results are attributed to the alkyl alcohol chain length influencing the rate of reaction of radicals and determines the solvable ratio of its alcohol into water. In addition, it was found that the synthesized particle geometric structure and composition can also be controlled by the pH of the aqueous solution in the X-ray radiolysis. This study may open a door to understanding and investigating a novel photochemical reaction route induced under X-ray irradiation. The development of the X-ray radiolysis process enables us to achieve the rapid and easy process of synthesis and immobilization of higher-order nano/microstructure consisting of various materials.


2018 ◽  
Vol 54 (23) ◽  
pp. 2914-2917 ◽  
Author(s):  
Kerda Keevend ◽  
Guido Panzarasa ◽  
Fabian H. L. Starsich ◽  
Martin Zeltner ◽  
Anastasia Spyrogianni ◽  
...  

MeltPEGylation constitutes an elegant one-pot route for the efficient PEGylation of metal oxide nanoparticles with improved hemo- and cytocompatibility.


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