Pre-hydrogenation stage as a strategy to improve the continuous production of a diesel-like biofuel from palm oil

2021 ◽  
Vol 168 ◽  
pp. 505-515
Author(s):  
Juan I. del Río ◽  
William Pérez ◽  
Fernando Cardeño ◽  
James Marín ◽  
Luis A. Rios
Author(s):  
Jaime Garci´a ◽  
Jorge Giraldo ◽  
Antonio Bula ◽  
Adria´n A´vila

Elements of Chemical Process Engineering were used in this research to design and simulate two continuous transesterification processes for the production of biodiesel from palm oil, using the chemical simulator, HYSYS®. This design specified the operating conditions of all the equipment required for the continuous production of biodiesel using ethanol and methanol as alcohols. The palm oil was modeled as a mixture of the triglycerides that compose it in greater proportion, estimating the chemical properties of the substances that take part in the transesterification reaction, with group contributions and group interactions theories. Finally, the quality specifications for biodiesel obtained in both simulations were analyzed to verify the fulfillment of the properties required by ASTM (American Society for Testing and Materials) and EN (European Norms) standards.


2018 ◽  
Vol 7 (3.7) ◽  
pp. 187
Author(s):  
Izatul Husna Zakaria ◽  
Jafni Jafni Azhan Ibrahim ◽  
Abdul Aziz Othman

One of issue regarding of renewable energy supply chain is source sustainability and reliability to ensure continuous production. The aim of this paper is to suggest the oil palm fibre waste to biogas electricity production framework: mill operation perspective that suit to be practices based on evaluation of current practise of oil palm solid waste and Malaysia’s palm oil industry. The framework is based on palm oil mill operation to utilise annually solid waste generate as biomass source for stable biogas electricity production. This conceptual paper is the principal efforts that introduce the usage of storage system for biomass feed input to ensure sustainable stable electricity production from palm oil mill by manipulate their solid waste production. Prospective researchers are put forward to conduct further research to enhance biogas production as alternative for waste treatment strategy.   


2018 ◽  
Vol 6 (3) ◽  
pp. 705
Author(s):  
Tirto Prakoso ◽  
Indra B Kurniawan ◽  
R Heru Nugroho

Methyl esters are one of alkyl esters compound that used as alternative diesel fuel became popular. Methyl esters have similarities on physical and chemical properties with the diesel fuel produced from fossil oil; however it has less combustion and environmental emissions. As fossil oil become rare to be exploited, and the rapid environmental issues, the efforts to develop methyl esters as alternative diesel fuel become a prospective one. One method to produce methyl esters from free fatty acids of crude palm oil (CPO) is the two step esterification-transesterification reaction, each step produce the same final product, however differs in the side product. Esterification produce water and transesterfication produce glycerin. The reaction uses alcohol as main reactant beside the free fatty acids, it can be conducted in batch or continuous production. In this research, the investigation is only emphasized in the first step that is the esterification step to produce methyl esters from free fatty acids contained in crude palm oil. Methanol and sulfuric acid are used as reactant and catalyst respectively. Methyl esters produced by esterification is affected by reaction temperature, amounts of catalyst, and methanol volume. The increase in temperature improved esterification conversion from 19% in 50C to 98% in 60C. While the usage of the highest amount of catalyst, 5 ml/1-CPO, led to produced the highest conversion relative to the conversion from 1 and 3 ml/1-CPO catalyst. Furthermore, 10% amount of methanol per volume CPO produced higher yield than 8%.Keywords : Biodiesel,  CPO Free Fatty Acid Esterification, Methyl Ester ConversionAbstrak Metil ester merupakan suatu senyawa alkil ester yang dapat digunakan sebagai bahan bakar alternatif. Metil ester memiliki sifat fisik dan kimia yang hampir sam a dengan minyak diesel yang dihasilkan dari minyak bumi tetapi emisi pembakaran dari penggunaan ester metal lebih rendah dari pada emisi hasil penggunaan minyak solar. Seiring dengan semakin langkanya sumber minyak bumi dan semakin gencarnya isu lingkungan hidup, pengembangan ester metil sebagai bahan bakar pengganti minyak solar semakin prospektif. Pembuatan ester metil dari asam lemak bebas minyak sawit mentah (crude palm oil) dapat dilakukan dengan beberapa cara antara lain dengan reaksi esterifikasi dan transesterifikasi menggunakan alkohol. Reaksi-reaksi ini dapat dilaksanakan secara batch maupun kontinu. Pada penelitian yang telah dilakukan, pembuatan ester metil dari asam lemak bebas minyak sawit mentah dilakukan dengan reaksi esterifikasi secara batch, dengan reaktan berupa minyak sawit mentah dan metanol. Katalis yang digunakan adalah H2SO4. Konversi ester metil yang dihasilkan dipengaruhi oleh temperatur reaksi, konsentrasi katalis dan konsentrasi metanol. Kenaikan temperatur reaksi akan meningkatkan konversi dari 19% pada 50oC menjadi 98% pada 60oC. Dengan menggunakan konsentrasi katalis tertinggi 5ml/l CPO memicu konversi tertinggi relatif dibandingkan nilai konversi dari 1 dan 3 ml/l CPO. 10% metanol menghasilkan perolehan tinggi dibanding 8%.Kata Kunci: Biodiesel, EsterifikasiAsam Lemak Bebas CPO, Konversi Ester Metil


2020 ◽  
Author(s):  
Eleni E. Karamerou ◽  
Sophie Parsons ◽  
Marcelle C. McManus ◽  
Christopher Chuck

Abstract Background Palm oil is the most commonly used crop oil worldwide, and is used predominantly for food, in the chemical industry and for biofuels. It is mainly cultivated in areas with biodiverse and carbon-rich rainforest which has given rise to large increases in greenhouse gas (GHG) emissions and significant impacts to biodiversity. There is therefore substantial interest in finding an alternative to palm oil. Heterotrophic single cell oils (SCOs) are one potential replacement as these are able to mimic the lipid profile of palm oil in a way that other terrestrial and exotic crop oils cannot. But, despite a large experimental research effort in this area, there are only a handful of techno-economic modelling publications. As such, there is little understanding of whether SCOs are, or could ever be, a potential competitive replacement to palm oil. To help address this question we designed a detailed model that coupled a hypothetical heterotroph (using the very best possible biological lipid production) with the largest and most efficient chemical plant design possible. Results Our base case gave a lipid selling price of $2.01 / kg for ~8,000 tonnes / year production, that could be reduced to $1.54 /kg on increasing production to ~48,000 tonnes of lipid a year. A range of scenarios to further reduce this cost were then assessed, including using a thermotolerant strain (reducing the cost from $1.54 /kg to $1.47 /kg), zero cost electricity ($ 1.48/kg), using non-sterile conditions ($1.05 / kg), wet extraction of lipids ($1.48 / kg), continuous production of extracellular lipid ($0.76 /kg) and selling the whole yeast cell, including recovering value for the protein and carbohydrate ($1.14 /kg). If co-products were produced alongside the lipid then the price could be effectively reduced to $0, depending on the amount of carbon funnelled away from lipid production, as long as the co-product could be sold in excess of $1/kg. Conclusions The model presented here represents an ideal case that which while not achievable in reality, importantly would not be able to be improved on, irrespective of the scientific advances in this area. From the scenarios explored, however, it should still be possible to produce lower cost SCOs, but research must start to be applied in three key areas, firstly designing products where the whole cell is used, displacing products that contain palm oil rather than attempting to produce an exact refined palm oil substitute. Secondly, further work on the product systems that produce lipids extracellularly in a continuous processing methodology or finally that create an effective biorefinery designed to produce a low molecular weight, bulk chemical, alongside the lipid. All other research areas will only ever give incremental gains rather than leading towards an economically competitive, sustainable, microbial oil.


2021 ◽  
Vol 14 (1) ◽  
Author(s):  
Eleni E. Karamerou ◽  
Sophie Parsons ◽  
Marcelle C. McManus ◽  
Christopher J. Chuck

Abstract Background Heterotrophic single-cell oils (SCOs) are one potential replacement to lipid-derived biofuels sourced from first-generation crops such as palm oil. However, despite a large experimental research effort in this area, there are only a handful of techno-economic modelling publications. As such, there is little understanding of whether SCOs are, or could ever be, a potential competitive replacement. To help address this question, we designed a detailed model that coupled a hypothetical heterotroph (using the very best possible biological lipid production) with the largest and most efficient chemical plant design possible. Results Our base case gave a lipid selling price of $1.81/kg for ~ 8,000 tonnes/year production, that could be reduced to $1.20/kg on increasing production to ~ 48,000 tonnes of lipid a year. A range of scenarios to further reduce this cost were then assessed, including using a thermotolerant strain (reducing the cost from $1.20 to $1.15/kg), zero-cost electricity ($ 1.12/kg), using non-sterile conditions ($1.19/kg), wet extraction of lipids ($1.16/kg), continuous production of extracellular lipid ($0.99/kg) and selling the whole yeast cell, including recovering value for the protein and carbohydrate ($0.81/kg). If co-products were produced alongside the lipid then the price could be effectively reduced to $0, depending on the amount of carbon funnelled away from lipid production, as long as the co-product could be sold in excess of $1/kg. Conclusions The model presented here represents an ideal case that which while not achievable in reality, importantly would not be able to be improved on, irrespective of the scientific advances in this area. From the scenarios explored, it is possible to produce lower cost SCOs, but research must start to be applied in three key areas, firstly designing products where the whole cell is used. Secondly, further work on the product systems that produce lipids extracellularly in a continuous processing methodology or finally that create an effective biorefinery designed to produce a low molecular weight, bulk chemical, alongside the lipid. All other research areas will only ever give incremental gains rather than leading towards an economically competitive, sustainable, microbial oil.


2003 ◽  
Vol 36 (6) ◽  
pp. 707-710 ◽  
Author(s):  
Phang Lai Yee ◽  
Mohd Ali Hassan ◽  
Yoshihito Shirai ◽  
Minato Wakisaka ◽  
Mohamed Ismail Adbul Karim

2021 ◽  
Author(s):  
Eleni E. Karamerou ◽  
Sophie Parsons ◽  
Marcelle C. McManus ◽  
Christopher Chuck

Abstract Background Heterotrophic single cell oils (SCOs) are one potential replacement to lipid derived biofuels sourced from first generation crops such as palm oil. However, despite a large experimental research effort in this area, there are only a handful of techno-economic modelling publications. As such, there is little understanding of whether SCOs are, or could ever be, a potential competitive replacement. To help address this question we designed a detailed model that coupled a hypothetical heterotroph (using the very best possible biological lipid production) with the largest and most efficient chemical plant design possible.Results Our base case gave a lipid selling price of $1.81 / kg for ~8,000 tonnes / year production, that could be reduced to $1.20 /kg on increasing production to ~48,000 tonnes of lipid a year. A range of scenarios to further reduce this cost were then assessed, including using a thermotolerant strain (reducing the cost from $1.20 /kg to $1.15 /kg), zero cost electricity ($ 1.12/kg), using non-sterile conditions ($1.19 / kg), wet extraction of lipids ($1.16 / kg), continuous production of extracellular lipid ($0.99 /kg) and selling the whole yeast cell, including recovering value for the protein and carbohydrate ($0.81 /kg). If co-products were produced alongside the lipid then the price could be effectively reduced to $0, depending on the amount of carbon funnelled away from lipid production, as long as the co-product could be sold in excess of $1/kg. Conclusions The model presented here represents an ideal case that which while not achievable in reality, importantly would not be able to be improved on, irrespective of the scientific advances in this area. From the scenarios explored, it is possible to produce lower cost SCOs, but research must start to be applied in three key areas, firstly designing products where the whole cell is used. Secondly, further work on the product systems that produce lipids extracellularly in a continuous processing methodology or finally that create an effective biorefinery designed to produce a low molecular weight, bulk chemical, alongside the lipid. All other research areas will only ever give incremental gains rather than leading towards an economically competitive, sustainable, microbial oil.


2020 ◽  
Vol 10 (1) ◽  
Author(s):  
Safa Senan Mahmod ◽  
Azratul Madihah Azahar ◽  
Abdullah Amru Indera Luthfi ◽  
Peer Mohamed Abdul ◽  
Mohd Shahbudin Mastar ◽  
...  

Abstract Two-stage anaerobic digestion of palm oil mill effluent (POME) is a promising method for converting the waste from the largest agricultural industry in Southeast Asia into a clean and sustainable energy. This study investigates the degradation of acid-rich effluent from the dark fermentation stage for the production of biomethane (BioCH4) in a 30-L continuous stirred-tank reactor (CSTR). The continuous methanogenic process was operated with varied HRTs (10 - 1 day) and OLRs (4.6–40.6 gCOD/L.d−1) under thermophilic conditions. Methanothermobacter sp. was the dominant thermophilic archaea that was responsible for the production rate of 4.3 LCH4/LPOME.d−1 and methane yield of 256.77 LCH4kgCOD at HRT of 2 d, which is the lowest HRT reported in the literature. The process was able to digest 85% and 64% of the initial POME’s COD and TSS, respectively. The formation of methane producing granules (MPG) played a pivotal role in sustaining the efficient and productive anaerobic system. We report herein that the anaerobic digestion was not only beneficial in reducing the contaminants in the liquid effluent, but generating BioCH4 gas with a positive net energy gain of 7.6 kJ/gCOD.


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