Efficient removal of pyrene by biochar supported iron oxide in heterogeneous Fenton-like reaction via radicals and high-valent iron-oxo species

2021 ◽  
Vol 265 ◽  
pp. 118518
Author(s):  
Hongxian Jian ◽  
Fang Yang ◽  
Yue Gao ◽  
Kai Zhen ◽  
Xuejiao Tang ◽  
...  
2017 ◽  
Vol 5 (2) ◽  
pp. 748-755 ◽  
Author(s):  
Seung Hwa Yoo ◽  
Dawon Jang ◽  
Han-Ik Joh ◽  
Sungho Lee

A high performance Fe3O4/Fe/Fe3C@PCNF heterogeneous Fenton catalyst was synthesized for aqueous H2O2 decomposition and was utilized to remove methylene blue in water.


Processes ◽  
2021 ◽  
Vol 9 (6) ◽  
pp. 942
Author(s):  
Christoph Horn ◽  
Stephanie Ihmann ◽  
Felix Müller ◽  
Doris Pospiech ◽  
Konstantin B. L. Borchert ◽  
...  

Advanced oxidation processes are the main way to remove persistent organic trace compounds from water. For these processes, heterogeneous Fenton catalysts with low iron leaching and high catalytic activity are required. Here, the preparation of such catalysts consisting of silica-supported iron oxide (Fe2O3/SiOx) embedded in thermoplastic polymers is presented. The iron oxide catalysts are prepared by a facile sol–gel procedure followed by thermal annealing (calcination). These materials are mixed in a melt compounding process with modified polypropylenes to stabilize the Fe2O3 catalytic centers and to further reduce the iron leaching. The catalytic activity of the composites is analyzed by means of the Reactive Black 5 (RB5) assay, as well as by the conversion of phenol which is used as an example of an organic trace compound. It is demonstrated that embedding of silica-supported iron oxide in modified polypropylene turns the reaction order from pseudo-first order (found for Fe2O3/SiOx catalysts), which represents a mainly homogeneous Fenton reaction, to pseudo-zeroth order in the polymer composites, indicating a mainly heterogeneous, surface-diffusion-controlled process.


2010 ◽  
Vol 12 (7) ◽  
pp. 1281 ◽  
Author(s):  
Camino Gonzalez-Arellano ◽  
Kenta Yoshida ◽  
Rafael Luque ◽  
Pratibha L. Gai

ChemCatChem ◽  
2019 ◽  
Vol 11 (6) ◽  
pp. 1625-1632 ◽  
Author(s):  
Yunyun Zhou ◽  
Sittichai Natesakhawat ◽  
Thuy‐Duong Nguyen‐Phan ◽  
Douglas R. Kauffman ◽  
Chris M. Marin ◽  
...  

2000 ◽  
Vol 198 (1-2) ◽  
pp. 115-126 ◽  
Author(s):  
She-Tin Wong ◽  
Jyh-Fu Lee ◽  
Soofin Cheng ◽  
Chung-Yuan Mou

2017 ◽  
Vol 27 (5) ◽  
pp. 512-514 ◽  
Author(s):  
Anastasiya A. Shesterkina ◽  
Elena V. Shuvalova ◽  
Elena A. Redina ◽  
Olga A. Kirichenko ◽  
Olga P. Tkachenko ◽  
...  

2012 ◽  
Vol 32 (2) ◽  
pp. 187-192 ◽  
Author(s):  
Yao-Hui Huang ◽  
Chia-Chi Su ◽  
Yun-Pei Yang ◽  
Ming-Chun Lu

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