Asymmetric solution-phase mixture aldol reaction using oligomeric ethylene glycol tagged chiral oxazolidinones

A Poly (ethylene glycol) (PEG) self-assembled monolayer was solution phase coupled to common MEMS (microelectromechanical systems) substrates through a one step procedure in order to investigate the potential anti-fouling properties of the polymer for implantable biomedical MEMS applications.

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Solution-Phase Mixture Synthesis with Double-Separation Tagging: Double Demixing of a Single Mixture Provides a Stereoisomer Library of 16 Individual Murisolins

Angewandte Chemie ◽

10.1002/ange.200501989 ◽

2005 ◽

Vol 117 (42) ◽

pp. 7098-7100 ◽

Cited By ~ 5

Author(s):

Craig S. Wilcox ◽

Venugopal Gudipati ◽

Hejun Lu ◽

Serhan Turkyilmaz ◽

Dennis P. Curran

Keyword(s):

Solution Phase ◽

Phase Mixture ◽

Mixture Synthesis

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Solution-Phase Mixture Synthesis with Fluorous Tagging En Route: Total Synthesis of an Eight-Member Stereoisomer Library of Passifloricins

Angewandte Chemie International Edition ◽

10.1002/anie.200600041 ◽

2006 ◽

Vol 45 (15) ◽

pp. 2423-2426 ◽

Cited By ~ 30

Author(s):

Dennis P. Curran ◽

Gustavo Moura-Letts ◽

Matthias Pohlman

Keyword(s):

Total Synthesis ◽

Solution Phase ◽

Phase Mixture ◽

Mixture Synthesis

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A concise asymmetric synthesis of (−)-trans-aerangis lactone

Canadian Journal of Chemistry ◽

10.1139/cjc-2018-0203 ◽

2018 ◽

Vol 96 (12) ◽

pp. 1061-1063 ◽

Cited By ~ 1

Author(s):

Rachana Pandey ◽

Ranjana Prakash

Keyword(s):

Ethylene Glycol ◽

Total Synthesis ◽

Asymmetric Synthesis ◽

Aldol Reaction ◽

Starting Material ◽

Asymmetric Total Synthesis

A concise stereoselective approach to functionalized δ-lactone skeleton from monosilylated ethylene glycol as a starting material and its application to the asymmetric total synthesis of (−)-trans-aerangis lactone have been demonstrated. The synthesis utilizes the organocatalyzed MacMillan’s cross aldol reaction as a key step.

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Solution-Phase Mixture Synthesis with Fluorous Tagging En Route: Total Synthesis of an Eight-Member Stereoisomer Library of Passifloricins

Angewandte Chemie ◽

10.1002/ange.200600041 ◽

2006 ◽

Vol 118 (15) ◽

pp. 2483-2486 ◽

Cited By ~ 9

Author(s):

Dennis P. Curran ◽

Gustavo Moura-Letts ◽

Matthias Pohlman

Keyword(s):

Total Synthesis ◽

Solution Phase ◽

Phase Mixture ◽

Mixture Synthesis

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Aminated poly(ethylene glycol) methacrylate resins as stable heterogeneous catalysts for the aldol reaction in water

Journal of Catalysis ◽

10.1016/j.jcat.2019.11.027 ◽

2020 ◽

Vol 381 ◽

pp. 540-546 ◽

Cited By ~ 2

Author(s):

Anton De Vylder ◽

Jeroen Lauwaert ◽

Jeriffa De Clercq ◽

Pascal Van Der Voort ◽

Christopher W. Jones ◽

...

Keyword(s):

Ethylene Glycol ◽

Heterogeneous Catalysts ◽

Aldol Reaction ◽

Poly Ethylene Glycol ◽

Glycol Methacrylate ◽

Poly Ethylene ◽

Reaction In Water

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Bulk properties of a liquid phase mixture {ethylene glycol+tert-butanol} in the temperature range 278.15–348.15 K and pressures of 0.1-100 MPa. I. Experimental results, excess and partial molar volumes

Journal of Structural Chemistry ◽

10.1134/s0022476613080118 ◽

2013 ◽

Vol 54 (S2) ◽

pp. 304-319 ◽

Cited By ~ 1

Author(s):

G. I. Egorov ◽

D. M. Makarov

Keyword(s):

Liquid Phase ◽

Ethylene Glycol ◽

Partial Molar Volumes ◽

Experimental Results ◽

Bulk Properties ◽

Molar Volumes ◽

Temperature Range ◽

Tert Butanol ◽

Phase Mixture

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Solution-Phase Mixture Synthesis with Double-Separation Tagging: Double Demixing of a Single Mixture Provides a Stereoisomer Library of 16 Individual Murisolins

Angewandte Chemie International Edition ◽

10.1002/anie.200501989 ◽

2005 ◽

Vol 44 (42) ◽

pp. 6938-6940 ◽

Cited By ~ 18

Author(s):

Craig S. Wilcox ◽

Venugopal Gudipati ◽

Hejun Lu ◽

Serhan Turkyilmaz ◽

Dennis P. Curran

Keyword(s):

Solution Phase ◽

Phase Mixture ◽

Mixture Synthesis

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Synthesis and Growth Mechanisms of Ag Metallo-Organic Nanoparticles in Different Morphologies by Using Polymer-Mediated Polyol Process

Key Engineering Materials ◽

10.4028/www.scientific.net/kem.334-335.817 ◽

2007 ◽

Vol 334-335 ◽

pp. 817-820

Author(s):

Yun Ze Shi ◽

Hui Qing Fan ◽

Mei Tian Bi ◽

Jie Zhang ◽

Xian Hua Zeng

Keyword(s):

Ethylene Glycol ◽

Elevated Temperatures ◽

Critical Role ◽

Nucleation And Growth ◽

Polyol Process ◽

Solution Phase ◽

Molar Ratio ◽

Silver Nanostructures ◽

Growth Mechanisms ◽

Silver Nanocubes

Mono-dispersed silver nanoparticles with various morphologies were synthesized in large quantities by reducing silver nitrate with ethylene glycol in the presence of poly(vinylpyrrolidone) (PVP). The effects of the concentration of AgNO3, temperature, adding rates of PVP and AgNO3 injected into ethylene glycol as well as molar ratio between the repeating unit of PVP and AgNO3 were discussed. By varying the temperature and reaction time, silver nanocubes, nnoprisms and nanospheres were obtained. It is indicated that at elevated temperatures, the ethylene glycol can reduce Ag+ ion into Ag atoms, and thereby inducing the nucleation and growth of silver nanostructures in the solution phase. In the polymer-mediated polyol process, PVP plays a critical role in producing silver nanostructures with good stability and size/shape uniformity. As a result, both the crystallinity of a seed and extent of PVP coverage on the seed were instrumental in controlling the morphology of Ag nanoparticles.

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