Polylactic acid coating on a biodegradable magnesium alloy: An in vitro degradation study by electrochemical impedance spectroscopy

2012 ◽  
Vol 520 (23) ◽  
pp. 6841-6844 ◽  
Author(s):  
Alyaa Alabbasi ◽  
S. Liyanaarachchi ◽  
M. Bobby Kannan
2015 ◽  
Vol 814 ◽  
pp. 132-136 ◽  
Author(s):  
Xian Yang Hua ◽  
Mei Feng He ◽  
Xiao Qin Zhou

Magnesium is one of the elements necessary for the body, is the man behind the body’s content of potassium ions within the cell are involved in a series of metabolic processes in vivo, including the formation of bone cells , acceleration of bone healing ability. Resulting from the good mechanical properties and biocompatibility, magnesium alloy is used in medical intervention material, but the high corrosion rate of magnesium alloys is the main drawback to their widespread use, especially in biomedical applications. There is a need for developing new coatings that provide simultaneously corrosion resistance and enhanced biocompatibility. In this work the medical magnesium alloy surface are dipped and coated with polylactic acid, so that obtain a dense uniform polylactic acid coating. And the corrosion resistance of the coating is studied in order to obtain controlled degradable and corrosion resisted magnesium alloy biological material. This paper mainly studies the influence of different concentrations of polylactic acid coating on AZ91D magnesium alloy corrosion resistance. The coated samples were immersed in Hank’s solution and the coating performance was studied by electrochemical impedance spectroscopy and scanning electron microscopy. This research is about the influence of the coating on the corrosion resistance of magnesium alloy through the open circuit potential, polarization curves, electrochemical impedance spectroscopy and Mott-Schottky. The results confirmed that the polylactic acid slow down the corrosion rate of AZ91D magnesium alloys in Hank’s solution. And along with the increase of poly lactic acid concentration, the corrosion resistance of magnesium alloys is improved. There is a wide variation of the corrosion morphology magnesium alloy AZ91D specimens after the surface modification using polylactic acid coating, compared with the unmodified.


2013 ◽  
Vol 765 ◽  
pp. 803-807
Author(s):  
Gaur Swati ◽  
Anand Sawroop Khanna ◽  
Raghuvir Kumar Singh Raman

In the present study, combinations of a phosphonato silane with a precursor, Methyltriethoxy silane (MTEOS) in various ratios were applied onto the alloy Mg-6Zn-Ca. The corrosion resistance of the coated and uncoated specimens in a modified simulated body fluid (m-SBF) was characterized by potentiodynamic polarization and electrochemical impedance spectroscopy (EIS). Results suggest that the silane coating significantly decreases the degradation rate of the magnesium alloy, indicating its potential to be used as a corrosion barrier for magnesium alloy temporary implants.


2013 ◽  
Vol 756-759 ◽  
pp. 85-88
Author(s):  
Xiao Ming Wang ◽  
Sheng Zhu ◽  
Qing Chang ◽  
Guo Feng Han

Al-based coating on ZM5 magnesium alloy was prepared by Supersonic Particles Deposition (SPD). Electrochemical working station was utilized to test polarization curve, corrosion potential and electrochemical impedance spectroscopy etc. The results indicted that corrosion potential of Al-Si coating was about-767.6mV, much higher than that of ZM5 Mg-substrate; And corrosion current density of the coating sample decreased three order of magnitude than that of the uncoated. Compared to Mg-substrate, the radius of capacitive impedance arc of the coating enlarged and impedance modulus improved two order of magnitude.


RSC Advances ◽  
2015 ◽  
Vol 5 (37) ◽  
pp. 29589-29593 ◽  
Author(s):  
A. Srinivasan ◽  
Kwang Seon Shin ◽  
N. Rajendran

Increase in magnitude (IZI) and phase angle maximum values with applied potential reveal the protective nature of the coating.


2012 ◽  
Vol 24 (5) ◽  
pp. 1033-1038 ◽  
Author(s):  
Marcos Pita ◽  
Jan Halámek ◽  
Soujanya Chinnapareddy ◽  
Donald J. White ◽  
Vladimir Gartstein ◽  
...  

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