A pilot plant study using conventional and advanced water treatment processes: Evaluating removal efficiency of indicator compounds representative of pharmaceuticals and personal care products

2016 ◽  
Vol 105 ◽  
pp. 85-96 ◽  
Author(s):  
Shuangyi Zhang ◽  
Stephen Gitungo ◽  
Lisa Axe ◽  
John E. Dyksen ◽  
Robert F. Raczko
2008 ◽  
Vol 57 (1) ◽  
pp. 49-56 ◽  
Author(s):  
C. Miège ◽  
J.M. Choubert ◽  
L. Ribeiro ◽  
M. Eusèbe ◽  
M. Coquery

We created a database in order to quantitatively assess the occurrence and removal efficiency of PPCPs in WWTPs. From 113 scientific publications, we compiled 5887 data on the concentrations and loads of PPCPs in WWTP influents and effluents, and on their removal efficiency. The first outputs of our database include: (1) a list of the most frequently studied molecules, their frequency of detection, their mean concentration and removal in liquid influent and effluent; (2) a comparison of the removal efficiency for different WWTP processes; (3) a study of the influence of the operating conditions (sludge and hydraulic retention times).


2000 ◽  
Vol 41 (7) ◽  
pp. 165-171 ◽  
Author(s):  
W. A. Hijnen ◽  
J. Willemsen-Zwaagstra ◽  
P. Hiemstra ◽  
G. J. Medema ◽  
D. van der Kooij

At eight full-scale water treatment plants in the Netherlands the removal of spores of sulphite-reducing clostridia (SSRC) was determined. By sampling and processing large volumes of water (1 up to 500 litres) SSRC were detected after each stage of the treatment. This enabled the assessment of the removal efficiency of the full-scale unit processes for persistent micro-organisms. A comparison with literature data on the removal of Cryptosporidium and Giardia by the same type of processes revealed that SSRC can be considered as a potential surrogate. The average Decimal Elimination Capacity (DEC) of the overall treatment plants ranged from 1.3–4.3 log. The observed actual log removal of SSRC by the unit processes and the overall treatment at one of the studied locations showed that the level of variation in removal efficiency was approximately 2 log. Moreover, from the actual log removal values it was observed that a low SSRC removal by one unit process is partly compensated by a higher removal by subsequent unit processes at this location. SSRC can be used for identification of the process conditions that cause variation in micro-organism removal which may lead to process optimization. Further research is necessary to determine the optimal use of SSRC in water quality monitoring for the production of microbiologically safe drinking water.


2014 ◽  
Vol 80 (8) ◽  
pp. 2440-2450 ◽  
Author(s):  
Kathryn M. Onesios-Barry ◽  
David Berry ◽  
Jody B. Proescher ◽  
I. K. Ashok Sivakumar ◽  
Edward J. Bouwer

ABSTRACTMany pharmaceuticals and personal care products (PPCPs) have been shown to be biotransformed in water treatment systems. However, little research exists on the effect of initial PPCP concentration on PPCP biotransformation or on the microbial communities treating impacted water. In this study, biological PPCP removal at various concentrations was assessed using laboratory columns inoculated with wastewater treatment plant effluent. Pyrosequencing was used to examine microbial communities in the columns and in soil from a soil aquifer treatment (SAT; a method of water treatment prior to reuse) site. Laboratory columns were supplied with different concentrations (0.25, 10, 100, or 1,000 μg liter−1) of each of 15 PPCPs. Five PPCPs (4-isopropyl-3-methylphenol [biosol],p-chloro-m-xylenol, gemfibrozil, ketoprofen, and phenytoin) were not removed at any tested concentrations. Two PPCPs (naproxen and triclosan) exhibited removals independent of PPCP concentration. PPCP removal efficiencies were dependent on initial concentrations for biphenylol,p-chloro-m-cresol, chlorophene, diclofenac, 5-fluorouracil, ibuprofen, and valproic acid, showing that PPCP concentration can affect biotransformation. Biofilms from sand samples collected from the 0.25- and 10-μg liter−1PPCP columns were pyrosequenced along with SAT soil samples collected on three consecutive days of a wetting and drying cycle to enable comparison of these two communities exposed to PPCPs. SAT communities were similar to column communities in taxonomy and phylotype composition, and both were found to contain close relatives of known PPCP degraders. The efficiency of biological removal of PPCPs was found to be dependent on the concentration at which the contamination occurs for some, but not all, PPCPs.


2013 ◽  
Vol 726-731 ◽  
pp. 2502-2505
Author(s):  
Zhong Hua Huang ◽  
Zheng Li Liu ◽  
Li Jun Zhu ◽  
Guli Mira Akbar

Pharmaceuticals and personal care products (PPCPs) have been widely detected in aquatic environment in recent years; as emerging micro-pollutants, their influence on human health and ecological environment safety are of increasing concern. Membrane filtration is considered as the suitable separation method for PPCPs removal due to different removal mechanisms. This paper reviews the removal efficiency and removal mechanisms for PPCPs by NF/RO membranes.


2010 ◽  
Vol 62 (10) ◽  
pp. 2450-2458 ◽  
Author(s):  
Angela Yu-Chen Lin ◽  
Cheng-Fan Lin ◽  
Yu-Ting Tsai ◽  
Hank Hui-Hsiang Lin ◽  
Jie Chen ◽  
...  

Pharmaceuticals and personal care products (PPCPs) constitute a class of chemicals of emerging concern due to the potential risks they pose to organisms and the environment, even at low concentrations (ng/L). Recent studies have found that PPCPs are not efficiently removed in secondary wastewater treatment plants (WWTPs). This study has: (1) simultaneously investigated the occurrence of sixty-one PPCPs using solid phase extraction and high-performance liquid chromatography-tandem mass spectrometry, (2) evaluated removal efficiencies of target PPCPs in six WWTPs that discharge effluents into major Taiwanese rivers, and lastly (3) examined matrix interference during analysis of target PPCPs in water samples. The twenty target PPCPs were chosen for their high detection frequencies, high influent concentrations, and stability during wastewater treatment processes. Caffeine and acetaminophen were detected at the highest concentrations (as high as 24,467 and 33,400 ng/L) and were effectively removed (both >96%); other PPCPs were detected in the high ng/L range but were not effectively removed. Matrix interference (by ion suppression or enhancement) during the analysis resulted in underestimation of the removal efficiencies of erythromycin-H2O, cefazolin, clarithromycin, ibuprofen, diclofenac, clofibric acid and gemfibrozil.


Author(s):  
Minja Bogunović ◽  
Tijana Marjanović ◽  
Ivana Ivančev-Tumbas

Emerging microcontaminants benzophenone (BP), benzophenone-3 (BP-3) and caffeine (CF) are widely used anthropogenic markers from a group of pharmaceuticals and personal care products. They have different logD values and charges at neutral pH (2.96 neutral for BP; 3.65 negative and neutral for BP-3; 0.28 and neutral for CF). The goal of this study was to assess the efficacy of coagulation/flocculation/sedimentation (C/F/S), adsorption onto two types of powdered activated carbon (PAC)/sedimentation (PAC/S) and the combination of these two processes in different dosing sequences (PAC/C/F/S) and with/without ultrafiltration (powdered activated carbon/ultrafiltration—PAC/UF, coagulation/UF—CoA/UF) for the removal of selected micropollutants from river water. It was shown that the removal efficiency of benzophenones by coagulation depends on the season, while CF was moderately removed (40–70%). The removal of neutral BP by two PACs unexpectedly differed (near 40% and ˃93%), while the removal of BP-3 was excellent (>95%). PACs were not efficient for the removal of hydrophilic CF. Combined PAC/C/F/S yielded excellent removal for BP and BP-3 regardless of PAC type only when the PAC addition was followed by C/F/S, while C/F/S efficiency for CF diminished. The combination of UF with PAC or coagulant showed also high efficacy for benzophenones, but was negligible for CF removal.


2007 ◽  
Vol 79 (13) ◽  
pp. 2564-2577 ◽  
Author(s):  
Joan Oppenheimer ◽  
Roger Stephenson ◽  
Arturo Burbano ◽  
Li Liu

Author(s):  
Alex Neumann

The increased use of Pharmaceuticals and Personal Care Products (PPCP’s) has led to an increase in many population health problems. In 1997, 15–50 % of women had developed breasts by the age of 8. Ten years prior to this, breast development by the age of 8 was uncommon. There are certain researchers who believe that this may be linked to the pharmaceuticals humans are consuming.Wastewater treatment plants are a significant gateway by which pharmaceuticals enter the water supply. Many pharmaceuticals find themselves in wastewater treatment plants, however the plants do not target these specific chemicals for treatment. As a result, they are released into the surrounding bodies of water, and accumulate in aquatic animals. When water treatment plants take water from the bodies of water and distribute it for human consumption, humans consume these chemicals.Many techniques for removing the pharmaceuticals have been tested, but there is still much uncertainty as to which are effective methods. The potential hazards associated with these chemicals are still uncertain, but the current evidence is indicating that it is very likely that these chemicals can be very hazardous.


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