The application of the růžička-type iodide-selective electrode for the determination of cyanide in alcoholic drinks

1987 ◽  
Vol 196 ◽  
pp. 293-297 ◽  
Author(s):  
Milan V. Budimir ◽  
Milan Sak-Bosnar ◽  
Momir S. Jovanovič
1981 ◽  
Vol 46 (2) ◽  
pp. 368-376 ◽  
Author(s):  
Josef Veselý

Titration of sulphates with lead perchlorate employing lead ion selective electrode indication was studied using additions of various organic solvents at different pH' and ionic strength values. As the optimum emerged systems with 60-70% 1,4-dioxane, pH' 5.3-5.6. After dehydration with sodium hydroxide, dioxane must be freed from the electrode surface-oxidizing impurities by their reduction with sodium metal and subsequent distillation. The method was applied to determination of sulphates in mountain spring waters. Units of ppm can be determined; the limit of determination, however, depends considerably on the content of dioxane, total salt content in the sample, and speed of the semi-automatic titration. Lead can be determined with EDTA in concentrations down to c(Pb2+) = 5 . 10-6 mol l-1.


Chemosensors ◽  
2021 ◽  
Vol 9 (7) ◽  
pp. 155
Author(s):  
Yan Su ◽  
Ting Liu ◽  
Caiqiao Song ◽  
Aiqiao Fan ◽  
Nan Zhu ◽  
...  

As an essential electrolyte for the human body, the potassium ion (K+) plays many physiological roles in living cells, so the rapid and accurate determination of serum K+ is of great significance. In this work, we developed a solid-contact ion-selective electrode (SC-ISE) using MoS2/Fe3O4 composites as the ion-to-electron transducer to determine serum K+. The potential response measurement of MoS2/Fe3O4/K+-ISE shows a Nernst response by a slope of 55.2 ± 0.1 mV/decade and a low detection limit of 6.3 × 10−6 M. The proposed electrode exhibits outstanding resistance to the interference of O2, CO2, light, and water layer formation. Remarkably, it also presents a high performance in potential reproducibility and long-term stability.


Author(s):  
David C. Cowell

An automated method is described, using standard continuous flow techniques, for the determination of urine fluoride ion concentration using a fluoride ion selective electrode. It is shown that the kinetics of the electrode response to changes in fluoride ion can be used for the accurate measurement of fluoride ion concentration in urine, and that equilibration of the electrode response is not a prerequisite for the measurement of fluoride ion. Recovery experiments are in the range 83 to 90%; in-batch precision is between 0·9 and 1·6% and carryover 2·5% or less.


1983 ◽  
Vol 81 (1-2) ◽  
pp. 135-147 ◽  
Author(s):  
U. Thanei-Wyss ◽  
W. E. Morf ◽  
P. Lienemann ◽  
Z. Stefanac ◽  
I. Mostert ◽  
...  

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