Kinetic parameters of oxidation of coals by heat-release measurement and their relevance to self-heating tests

Fuel ◽  
1998 ◽  
Vol 77 (1-2) ◽  
pp. 19-22 ◽  
Author(s):  
J.C. Jones ◽  
K.P. Henderson ◽  
J. Littlefair ◽  
S. Rennie
1997 ◽  
Vol 15 (6) ◽  
pp. 481-487 ◽  
Author(s):  
J.C. Jones

A sample of Sitka Spruce litter has been examined in a microcalo rimeter at temperatures up to 58°C, and kinetic parameters deduced from the re sults in a way which is explained step by step. The kinetic parameters were then used to predict the ignition temperature of the material in a field situation. Input to this calculation includes measured heat-release rate at incipient ignition of a different litter, reported independently.


Author(s):  
Harvinder S Sidhu ◽  
Mark I Nelson ◽  
Thiansiri Luangwilai ◽  
Xiao Dong Chen

We model the increase in temperature in compost piles or landfill sites due to micro-organisms undergoing exothermic reactions. The model incorporates the heat release due to biological activity within the pile and the heat release due to the oxidation of cellulosic materials. The heat release rate due to biological activity is modelled by a function which is a monotonic increasing function of temperature over a particular range and followed by a monotone decreasing function of temperature. This functionality represents the fact that micro-organisms die or become dormant at high temperatures. The heat release due to the oxidation reaction is modelled by the usual manner using Arrhenius kinetics. The bifurcation behaviour is investigated for two-dimensional slab geometries to determine the critical sizes of the compost piles.


2014 ◽  
Vol 63 ◽  
pp. 1-9 ◽  
Author(s):  
Wendi Guo ◽  
Ken Trischuk ◽  
Xiaotao Bi ◽  
C. Jim Lim ◽  
Shahab Sokhansanj

Author(s):  
K.M. Akhmetov ◽  
◽  
G.S. Shaikhova ◽  
V.V. Zhurov ◽  
E.N. Khmyrova ◽  
...  

The article presents a mathematical model of coal self-heating in the stack in which the heat exchange and gas exchange processes are described by a system of two non-linear differential equations of the second order with respect to the temperature t of coal self-heating and the volume fraction C of oxygen in the voids of the stack with boundary and initial conditions. The differential equations took into account that self-heating of coal in the stack and appearance of spontaneous combustion are observed in a relatively small layer adjacent to the surface of its contact with the air and called the zone of oxygen influence. In the mathematical model, the influence on the process of coal self-heating of parameter F- specific heat release power was taken into account, which in addition characterises the stability of coal during storage. When compiling the differential equations, such physical parameters as thermal conductivity, diffusion coefficient, specific heat capacity of coal in the stack, bulk density, thermal effect of oxidation, stack voidness, temperature coefficient of exponential growth of heat release power were also used. For numerical implementation of the mathematical model, dimensionless variables and criteria were introduced, which allowed us to apply the net method. Analysis of the obtained results allowed to get: change in the stack temperature profiles with time; change in the stack oxygen concentration profiles with time; influence on the stack temperature profile of the specific heat release power; influence on the stack temperature profile of the parameter characterizing exponential growth of heat release intensity with temperature increase. It has been determined that the dynamics of coal self-heating in the stack is mostly influenced by the Lykov criterion, proportional to the diffusion coefficient, and the Nusselt criterion related to the effective thermal conductivity and to the effective thermal diffusivity of coal. The obtained results suggest that self-heating in the stack is due on the one hand to intensive penetration of air oxygen and on the other hand to a weakened heat transfer. Self-heating and the transition of self-heating into ignition are associated with the occurrence of turbulent diffusion in the stack, arising from increased thermal blowing, whose impact can be enhanced by directing it perpendicular to the surface of the stack.


2003 ◽  
Vol 67 (4) ◽  
pp. 665-670 ◽  
Author(s):  
B. B. Beamish ◽  
J. D. St. George ◽  
M. A. Barakat

AbstractAdiabatic self-heating tests were carried out on five New Zealand coal samples ranging in rank from lignite to high-volatile bituminous. Kinetic parameters of oxidation were obtained from the self-heating curves assuming Arrhenius behaviour. The activation energy E (kJ mol–1) and the pre-exponential factor A (s–1) were determined in the temperature range of 70–140°C. The activation energy exhibited a definite rank relationship with a minimum E of 55 kJ mol–1 occurring at a Suggate rank of ∼6.2 corresponding to subbituminous C. Either side of this rank there was a noticeable increase in the activation energy indicating lower reactivity of the coal. A similar rank trend was also observed in the R70 self-heating rate index values that were taken from the initial portion of the self-heating curve from 40 to 70°C. From these results it is clear that the adiabatic method is capable of providing reliable kinetic parameters of coal oxidation.


Fuel ◽  
1996 ◽  
Vol 75 (15) ◽  
pp. 1755-1757 ◽  
Author(s):  
J.C. Jones ◽  
P.S. Chiz ◽  
R. Koh ◽  
J. Matthew

2014 ◽  
Vol 496-500 ◽  
pp. 246-250
Author(s):  
Song Qi Hu ◽  
Guan Jie Wu

The paraffin, pre-treated paraffin and hydroxyl-terminated polybutadiene (HTPB) were measured by Differential Scanning Calorimetry (DSC) and Thermogravimetry (TG) in different conditions. Thermal degradation characteristics of the paraffin, pre-treated paraffin and HTPB were studied; Influences of different pressure and different temperatures on thermal degradation characteristics of pre-treated paraffin were analyzed. Experiments show that the decomposition temperature of pre-treated paraffin is higher than that of the untreated paraffin, but lower than that of HTPB; the initial reaction temperature, the reaction exothermic peak temperature and the reaction heat release of pre-treated paraffin were all affected by pressure and heating rate; Kinetic parameters of pre-treated paraffin in oxygen atmosphere were calculated.


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