Gas phase versus solution chemistry: on the reversal of regiochemistry of methylation of sp2- and sp3-nitrogens

2001 ◽  
Vol 42 (39) ◽  
pp. 6949-6952 ◽  
Author(s):  
Jennifer S Brodbelt ◽  
John Isbell ◽  
Jonathan M Goodman ◽  
Henry V Secor ◽  
Jeffrey I Seeman
Keyword(s):  
Gas Phase ◽  
Solution Chemistry ◽  
Phase Versus ◽  
Versus Solution

scholarly journals On the Regioselectivity of the Gould–Jacobs Reaction: Gas‐Phase Versus Solution‐Phase Thermolysis

2020 ◽  
Vol 2020 (45) ◽  
pp. 7051-7061
Author(s):  
Michaela Wernik ◽  
Peter E. Hartmann ◽  
Gellért Sipos ◽  
Ferenc Darvas ◽  
A. Daniel Boese ◽  
...  
Keyword(s):  
Gas Phase ◽  
Solution Phase ◽  
Phase Versus ◽  
Versus Solution

Solvation of anion radicals: gas-phase versus solution

1989 ◽  
Vol 111 (7) ◽  
pp. 2667-2674 ◽  
Author(s):  
Haim Shalev ◽  
Dennis H. Evans
Keyword(s):  
Gas Phase ◽  
Phase Versus ◽  
Versus Solution ◽  
Anion Radicals

scholarly journals Influence of Water on the Dynamic Adsorption of Chlorinated VOCs on Active Carbon: Relative Humidity of the Gas Phase versus Pre-Adsorbed Water

2006 ◽  
Vol 24 (3) ◽  
pp. 215-228 ◽  
Author(s):  
F. Cosnier ◽  
A. Celzard ◽  
G. Furdin ◽  
D. Bégin ◽  
J.F. Marêché
Keyword(s):  
Gas Phase ◽  
Activated Carbons ◽  
Adsorbed Water ◽  
Phase Versus ◽  
Chlorinated Volatile Organic Compounds ◽  
Adsorption Capacities ◽  
Volatile Organic ◽  
Influence Of Water ◽  
Hindered Diffusion ◽  
Induced Adsorption

The present work deals with the influence of water on the adsorption of two chlorinated volatile organic compounds (VOCs) on activated carbons (ACs) having very different pore textures and surface chemistry. Two kinds of moisture were considered, viz. pre-adsorbed on the AC or present as steam in the gaseous phase, at various relative humidities ranging from 30% to 75%. It is shown that the adsorption of the VOCs depends on the kind of moisture. If the latter is pre-adsorbed, water is just displaced by the VOCs (overshoot). The adsorption capacities of the AC remain unchanged and only some minor changes in the shape of the breakthrough front, corresponding to hindered diffusion, may sometimes occur. In contrast, the simultaneous adsorption of steam and VOC leads to competition between water and the chlorinated compound, with direct consequences on the adsorption kinetics and capacities of the AC. However, the decrease of the water-induced adsorption performances depends strongly on the AC and the VOC (through different VOC/AC and water/VOC interactions), and on the concentration of the VOC.

Photoionization of Gas-Phase versus Ion-Beam-Desorbed Dopamine with Femtosecond Laser Pulses

1999 ◽  
Vol 71 (3) ◽  
pp. 574-581 ◽  
Author(s):  
Vasil Vorsa ◽  
Kenneth F. Willey ◽  
Nicholas Winograd
Keyword(s):  
Femtosecond Laser ◽  
Gas Phase ◽  
Ion Beam ◽  
Laser Pulses ◽  
Femtosecond Laser Pulses ◽  
Phase Versus

scholarly journals A comparative study of AumRhn (4 ≤ m + n ≤ 6) clusters in the gas phase versus those deposited on (100) MgO

2016 ◽  
Vol 18 (32) ◽  
pp. 22122-22128 ◽  
Author(s):  
Fernando Buendía ◽  
Jorge A. Vargas ◽  
Marcela R. Beltrán ◽  
Jack B. A. Davis ◽  
Roy L. Johnston
Keyword(s):  
Genetic Algorithm ◽  
Density Functional Theory ◽  
Gas Phase ◽  
Density Functional ◽  
Energy Surface ◽  
Three Dimensional ◽  
Two Dimensional ◽  
Functional Theory ◽  
Phase Versus ◽  
Combined Use

The combined use of a genetic algorithm and Density Functional Theory (DFT) calculations allows us to explore the potential energy surface. Our results show interesting effects on the geometries of the clusters on deposition. Two-dimensional clusters in the gas phase become three-dimensional and vice versa.

Sign in / Sign up

Export Citation Format

Share Document