Chemical Reactor Modelling approach has been applied to evaluate exhaust emissions of the newly designed ARI100 (Patent Pending) recuperated micro gas turbine combustor developed by Ansaldo Ricerche SpA. The development of the chemical reactor network has been performed based on CFD reacting flow analysis, obtained with a global 2-step reaction mechanism, applying boundary conditions concerning the combustion chamber at atmospheric pressure, with 100% of thermal load and fuelled with natural gas. The network consists of 11 ideal reactors: 6 perfectly stirred reactors, and 5 plug flow reactors, including also 13 mixers and 12 splitters. Simulations have been conducted using two detailed reaction mechanisms: GRI Mech 3.0 and Miller & Bowman reaction mechanisms. Exhaust emissions have been evaluated at several operating conditions, obtained at different pressure, and considering different fuel gases, as natural gas and a high H2 content SYNGAS fuel. Furthermore, emissions at different thermal loads have been investigated when natural gas at atmospheric pressure is fuelled. Simulation results have been compared with those obtained from combustion experimental campaign. CO and NOx emissions predicted with CRM approach closely match experimental results at representative operating conditions. Ongoing efforts to improve the proposed reactors network should allow extending the range of applicability to those operating conditions whose simulation results are not completely satisfying. Given the small computational effort required, and the accuracy in predicting combustor experimental exhaust emissions, both CO and NOx, the CRM approach turnout to be an efficient way to reasonably evaluate exhaust emissions of a micro gas turbine combustor.