04/00947 Comparison of burning natural gas and low-calorific-value synthesis gas in gas turbine combustor

2004 ◽  
Vol 45 (2) ◽  
pp. 123
Author(s):  
Thormod Andersen ◽  
Hanne M. Kvamsdal ◽  
Olav Bolland

A concept for capturing and sequestering CO2 from a natural gas fired combined cycle power plant is presented. The present approach is to decarbonise the fuel prior to combustion by reforming natural gas, producing a hydrogen-rich fuel. The reforming process consists of an air-blown pressurised auto-thermal reformer that produces a gas containing H2, CO and a small fraction of CH4 as combustible components. The gas is then led through a water gas shift reactor, where the equilibrium of CO and H2O is shifted towards CO2 and H2. The CO2 is then captured from the resulting gas by chemical absorption. The gas turbine of this system is then fed with a fuel gas containing approximately 50% H2. In order to achieve acceptable level of fuel-to-electricity conversion efficiency, this kind of process is attractive because of the possibility of process integration between the combined cycle and the reforming process. A comparison is made between a “standard” combined cycle and the current process with CO2-removal. This study also comprise an investigation of using a lower pressure level in the reforming section than in the gas turbine combustor and the impact of reduced steam/carbon ratio in the main reformer. The impact on gas turbine operation because of massive air bleed and the use of a hydrogen rich fuel is discussed.


Author(s):  
K. O. Smith ◽  
A. Fahme

Three subscale, cylindrical combustors were rig tested on natural gas at typical industrial gas turbine operating conditions. The intent of the testing was to determine the effect of combustor liner cooling on NOx and CO emissions. In order of decreasing liner cooling, a metal louvre-cooled combustor, a metal effusion-cooled combustor, and a backside-cooled ceramic (CFCC) combustor were evaluated. The three combustors were tested using the same lean-premixed fuel injector. Testing showed that reduced liner cooling produced lower CO emissions as reaction quenching near the liner wall was reduced. A reduction in CO emissions allows a reoptimization of the combustor air flow distribution to yield lower NOx emissions.


Author(s):  
Candy Hernandez ◽  
Vincent McDonell

Abstract Lean-premixed (LPM) gas turbines have been developed for stationary power generation in efforts to reduce emissions due to strict air quality standards. Lean-premixed operation is beneficial as it reduces combustor temperatures, thus decreasing NOx formation and unburned hydrocarbons. However, tradeoffs occur between system performance and turbine emissions. Efforts to minimize tradeoffs between stability and emissions include the addition of hydrogen to natural gas, a common fuel used in stationary gas turbines. The addition of hydrogen is promising for both increasing combustor stability and further reducing emissions because of its wide flammability limits allowing for lower temperature operation, and lack of carbon molecules. Other efforts to increase gas turbine stability include the usage of a non-lean pilot flame to assist in stabilizing the main flame. By varying fuel composition for both the main and piloted flows of a gas turbine combustor, the effect of hydrogen addition on performance and emissions can be systematically evaluated. In the present work, computational fluid dynamics (CFD) and chemical reactor networks (CRN) are created to evaluate stability (LBO) and emissions of a gas turbine combustor by utilizing fuel and flow rate conditions from former hydrogen and natural gas experimental results. With CFD and CRN analysis, the optimization of parameters between fuel composition and main/pilot flow splits can provide feedback for minimizing pollutants while increasing stability limits. The results from both the gas turbine model and former experimental results can guide future gas turbine operation and design.


Author(s):  
Jeffrey N. Phillips ◽  
Richard J. Roby

A screening level study has been carried out to examine the potential of using H2-enriched natural gas to improve the combustion performance of gas turbines. H2 has wider flammability limits and a higher flame speed than methane. Many previous studies have shown that when H2 is added to fuel, more efficient combustion and lower emissions will result. However, to date no commercial attempt has been made to improve the combustion performance of a natural gas-fired gas turbine by supplementing the fuel with H2. Four potential options for supplementing natural gas with H2 have been analyzed. Three of these options use the exhaust heat of the gas turbine either directly or indirectly to partially reform methane. The fourth option uses liquid H2 supplied from an industrial gas producer.


Author(s):  
Carmine Russo ◽  
Giulio Mori ◽  
Vyacheslav V. Anisimov ◽  
Joa˜o Parente

Chemical Reactor Modelling approach has been applied to evaluate exhaust emissions of the newly designed ARI100 (Patent Pending) recuperated micro gas turbine combustor developed by Ansaldo Ricerche SpA. The development of the chemical reactor network has been performed based on CFD reacting flow analysis, obtained with a global 2-step reaction mechanism, applying boundary conditions concerning the combustion chamber at atmospheric pressure, with 100% of thermal load and fuelled with natural gas. The network consists of 11 ideal reactors: 6 perfectly stirred reactors, and 5 plug flow reactors, including also 13 mixers and 12 splitters. Simulations have been conducted using two detailed reaction mechanisms: GRI Mech 3.0 and Miller & Bowman reaction mechanisms. Exhaust emissions have been evaluated at several operating conditions, obtained at different pressure, and considering different fuel gases, as natural gas and a high H2 content SYNGAS fuel. Furthermore, emissions at different thermal loads have been investigated when natural gas at atmospheric pressure is fuelled. Simulation results have been compared with those obtained from combustion experimental campaign. CO and NOx emissions predicted with CRM approach closely match experimental results at representative operating conditions. Ongoing efforts to improve the proposed reactors network should allow extending the range of applicability to those operating conditions whose simulation results are not completely satisfying. Given the small computational effort required, and the accuracy in predicting combustor experimental exhaust emissions, both CO and NOx, the CRM approach turnout to be an efficient way to reasonably evaluate exhaust emissions of a micro gas turbine combustor.


Author(s):  
Y. Ozawa ◽  
J. Hirano ◽  
M. Sato ◽  
M. Saiga ◽  
S. Watanabe

Catalytic combustion is an ultra low NOx combustion method, so it is expected that this method will be applied to gas turbine combustor. However, it is difficult to develop catalytic combustor because catalytic reliability at high temperature is still insufficient. To overcome this difficulty, we designed a catalytic combustor in which premixed combustion was combined. By this device, it is possible to obtain combustion gas at a combustion temperature of 1300°C while keeping the catalytic temperature below 1000°C. After performing preliminary tests using LPG, we designed two types of combustors for natural gas with a capacity equivalent to 1 combustor used in a 20MW–class multi–can type gas turbine. Combustion tests were conducted at atmospheric pressure using natural gas. As a result, it was confirmed that a combustor in which catalytic combustor segments were arranged alternately with premixing nozzles could achieve low NOx and high combustion efficiency in the range from 1000°C to 1300°C of the combustor exit gas temperature.


Author(s):  
Kenneth O. Smith ◽  
Leonard C. Angello ◽  
F. Richard Kurzynske

The design and initial rig testing of an ultra-low NOx gas turbine combustor primary zone are described. A lean premixed, swirl-stabilized combustor was evaluated over a range of pressures up to 10.7 × 105 Pa (10.6 atm) using natural gas. The program goal of reducing NOx emissions to 10 ppm (at 15% O2) with coincident low CO emissions was achieved at all combustor pressure levels. Appropriate combustor loading for ultra-low NOx operation was determined through emissions sampling within the primary zone. The work described represents a first step in developing an advanced gas turbine combustion system that can yield ultra-low NOx levels without the need for water injection and selective catalytic reduction.


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