04/00948 Development of low NOx combustion technology in medium-Btu fueled 1300°C-class gas turbine combustor in an integrated coal gasification combined cycle

2004 ◽  
Vol 45 (2) ◽  
pp. 123
Author(s):  
M. Sato ◽  
T. Ninomiya ◽  
T. Nakata ◽  
T. Yoshine ◽  
M. Yamada ◽  
...  

From the view point of future coal utilization technology for the thermal power generation systems, the coal gasification combined cycle system has drawn special interest recently. In the coal gasification combined cycle power generation system, it is necessary to develop a high temperature gas turbine combustor using a low–BTU gas (LBG) which has high thermal efficiency and low emissions. In Japan a development program on the coal gasification combined cycle power generation system has started in 1985 by the national government and Japanese electric companies. In this program, is planned to develop the 1300 °C class gas turbines. However, in the case of using a hot type fuel gas cleaning system, the coal gas fuel to be supplied to gas turbines will contain ammonia. Ammonia will be converted to nitric oxides in the combustion process in gas turbines. Therefore, low fuel–NOx combustion technology is one of the most important research subjects. This paper describes low fuel–NOx combustion technology for 1300 °C class gas turbine combustor using low BTU coal gas fuel. Authors have showed that the rich–lean combustion method is effective to decrease fuel–NOx (1). In general in rich–lean combustion method, the fuel–NOx decreases, as the primary zone becomes richer. But flameholding becomes very difficult in even rich primary zone. For this reason this combustor was designed to have a flameholder with pilot flame. Combustion tests were conducted by using a full scale combustor used in 150 MW gas turbine at the atmospheric pressure condition.


Author(s):  
M. Sato ◽  
T. Abe ◽  
T. Ninomiya ◽  
T. Nakata ◽  
T. Yoshine ◽  
...  

From the view point of future coal utilization technology for the thermal power generation systems, the coal gasification combined cycle system has drawn special interest recently. In the coal gasification combined cycle power generation system, it is necessary to develop a high temperature gas turbine combustor using a low-BTU gas (LBG) which has high thermal efficiency and low emissions. In Japan a development program of the coal gasification combined cycle power generation system has started in 1985 by the national government and Japanese electric companies. In this program, 1300°C class gas turbines will be developed. If the fuel gas cleaning system is a hot type, the coal gaseous fuel to be supplied to gas turbines will contain ammonia. Ammonia will be converted to nitric oxides in the combustion process in gas turbines. Therefore, low fuel-NOx combustion technology will be one of the most important research subjects. This paper describes low fuel-NOx combustion technology for 1300°C class gas turbine combustors using coal gaseous low-BTU fuel as well as combustion characteristics and carbon monoxide emission characteristics. Combustion tests were conducted using a full-scale combustor used for the 150 MW gas turbine at the atmospheric pressure. Furthermore, high pressure combustion tests were conducted using a half-scale combustor used for the 1 50 MW gas turbine.


1995 ◽  
Vol 117 (4) ◽  
pp. 673-677 ◽  
Author(s):  
C. S. Cook ◽  
J. C. Corman ◽  
D. M. Todd

The integration of gas turbines and combined cycle systems with advances in coal gasification and gas stream cleanup systems will result in economically viable IGCC systems. Optimization of IGCC systems for both emission levels and cost of electricity is critical to achieving this goal. A technical issue is the ability to use a wide range of coal and petroleum-based fuel gases in conventional gas turbine combustor hardware. In order to characterize the acceptability of these syngases for gas turbines, combustion studies were conducted with simulated coal gases using full-scale advanced gas turbine (7F) combustor components. It was found that NOx emissions could be correlated as a simple function of stoichiometric flame temperature for a wide range of heating values while CO emissions were shown to depend primarily on the H2 content of the fuel below heating values of 130 Btu/scf (5125 kJ/NM3) and for H2/CO ratios less than unity. The test program further demonstrated the capability of advanced can-annular combustion systems to burn fuels from air-blown gasifiers with fuel lower heating values as low as 90 Btu/scf (3548 kJ/NM3) at 2300°F (1260°C) firing temperature. In support of ongoing economic studies, numerous IGCC system evaluations have been conducted incorporating a majority of the commercial or near-commercial coal gasification systems coupled with “F” series gas turbine combined cycles. Both oxygen and air-blown configurations have been studied, in some cases with high and low-temperature gas cleaning systems. It has been shown that system studies must start with the characteristics and limitations of the gas turbine if output and operating economics are to be optimized throughout the range of ambient operating temperature and load variation.


Author(s):  
Yan Xiong ◽  
Lucheng Ji ◽  
Zhedian Zhang ◽  
Yue Wang ◽  
Yunhan Xiao

Gas turbine is one of the key components for integrated gasification combined cycle (IGCC) system. Combustor of the gas turbine needs to burn medium/low heating value syngas produced by coal gasification. In order to save time and cost during the design and development of a gas turbine combustor for medium/low heating value syngas, computational fluid dynamics (CFD) offers a good mean. In this paper, 3D numerical simulations were carried out on a full scale multi-nozzle gas turbine combustor using commercial CFD software FLUENT. A 72 degrees sector was modeled to minimize the number of cells of the grid. For the fluid flow part, viscous Navier-Stokes equations were solved. The realizable k-ε turbulence model was adopted. Steady laminar flamelet model was used for the reacting system. The interaction between fluid turbulence and combustion chemistry was taken into account by the PDF (probability density function) model. The simulation was performed with two design schemes which are head cooling using film-cooling and impingement cooling. The details of the flow field and temperature distribution inside the two gas turbine combustors obtained could be cited as references for design and retrofit. Similarities were found between the predicted and experimental data of the transition duct exit temperature profile. There is much work yet to be done on modeling validation in the future.


1998 ◽  
Vol 120 (3) ◽  
pp. 502-508 ◽  
Author(s):  
A. S. Feitelberg ◽  
M. A. Lacey

The General Electric Company has developed and successfully tested a full-scale, F-class (2550°F combustor exit temperature), rich-quench-lean (RQL) gas turbine combustor, designated RQL2, for low heating value (LHV) fuel and integrated gasification combined cycle applications. Although the primary objective of this effort was to develop an RQL combustor with lower conversion of fuel bound nitrogen to NOx than a conventional gas turbine combustor, the RQL2 design can be readily adapted to natural gas and liquid fuel combustion. RQL2 is the culmination of a 5 year research and development effort that began with natural gas tests of a 2” diameter perforated plate combustor and included LHV fuel tests of RQL1, a reduced scale (6” diameter) gas turbine combustor. The RQL2 combustor includes a 14” diameter converging rich stage liner, an impingement cooled 7” diameter radially-stratified-quench stage, and a backward facing step at the entrance to a 10” diameter film cooled lean stage. The rich stage combustor liner has a novel double-walled structure with narrow circumferential cooling channels to maintain metal wall temperatures within design limits. Provisions were made to allow independent control of the air supplied to the rich and quench/lean stages. RQL2 has been fired for almost 100 hours with LHV fuel supplied by a pilot scale coal gasification and high temperature desulfurization system. At the optimum rich stage equivalence ration NOx emissions were about 50 ppmv (on a dry, 15 percent O2 basis), more than a factor of 3 lower than expected from a conventional diffusion flame combustor burning the same fuel. With 4600 ppmv NH3 in the LHV fuel, this corresponds to a conversion of NH3 to NOx of about 5 percent. As conditions were shifted away from the optimum, RQL2 NOx emissions gradually increased until they were comparable to a standard combustor. A chemical kinetic model of RQL2, constructed from a series of ideal chemical reactors, matched the measured NOx emissions fairly well. The CO emissions were between 5 and 30 ppmv (on a dry, 15 percent O2 basis) under all conditions.


Author(s):  
Leo D. Eskin ◽  
Michael S. Klassen ◽  
Richard J. Roby ◽  
Richard G. Joklik ◽  
Maclain M. Holton

A Lean, Premixed, Prevaporized (LPP) combustion technology has been developed that converts liquid biofuels, such as biodiesel or ethanol, into a substitute for natural gas. This fuel can then be burned with low emissions in virtually any combustion device in place of natural gas, providing users substantial fuel flexibility. A gas turbine utilizing the LPP combustion technology to burn biofuels creates a “dispatchable” (on-demand) renewable power generator with low criteria pollutant emissions and no net carbon emissions. Natural gas, petroleum based fuel oil #1 and #2, biodiesel and ethanol were tested in an atmospheric pressure test rig using actual gas turbine combustor hardware (designed for natural gas) and achieved natural gas level emissions. Both biodiesel and ethanol achieved natural gas level emissions for NOx, CO, SOx and particulate matter (PM). Extended lean operation was observed for all liquid fuels tested due to the wider lean flammability range for these fuels compared to natural gas. Autoignition of the fuels was controlled by the level of diluent (inerting) gas used in the vaporization process. This technology has successfully demonstrated the clean generation of green, dispatchable, renewable power on a 30kW Capstone C30 microturbine. Emissions on the vaporized derived from bio-ethanol are 3 ppm NO(x) and 18 ppm CO, improving on the baseline natural gas emissions of 3 ppm NO(x), 30 ppm CO. Performance calculations have shown that for a typical combined cycle power plant, one can expect to achieve a two percent (2%) improvement in the overall net plant heat rate when burning liquid fuel as LPP Gas™ as compared to burning the same liquid fuel in traditional spray-flame diffusion combustors. This level of heat rate improvement is quite substantial, and represents an annual fuel savings of over five million dollars for base load operation of a GE Frame 7EA combined cycle plant (126 MW). This technology provides a clean and reliable form of renewable energy using liquid biofuels that can be a primary source for power generation or be a back-up source for non-dispatchable renewable energy sources such as wind and solar. The LPP technology allows for the clean use of biofuels in combustion devices without water injection or the use of post-combustion pollution control equipment and can easily be incorporated into both new and existing gas turbine power plants. No changes are required to the DLE gas turbine combustor hardware.


Author(s):  
Takeharu Hasegawa ◽  
Tohru Hisamatsu ◽  
Yasunari Katsuki ◽  
Mikio Sato ◽  
Masahiko Yamada ◽  
...  

The development of integrated coal gasification combined cycle (IGCC) systems ensures cost-effective and environmentally sound options for supplying future coal utilizing power generation needs. The Japanese government and the electric power industries in Japan promoted research and development of an IGCC system using an air-blown entrained-flow coal gasifier. We worked on developing a low-Btu fueled gas turbine combustor to improve the thermal efficiency of the IGCC by raising the inlet-gas temperature of gas turbine. On the other hand, Europe and the United States are now developing the oxygen-blown IGCC demonstration plants. Coal gasified fuel produced in an oxygen-blown entrained-flow coal gasifier, has a calorific value of 8.6MJ/m 3 which is one fifth that of natural gas. However, the adiabatic flame temperature of oxygen-blown medium-Btu coal gaseous fuel is higher than that of natural gas and so NOx production from nitrogen fixation is expected to increase significantly. In the oxygen-blown IGCC system, a surplus nitrogen in quantity is produced in the oxygen-production unit. When nitrogen premixed with coal gasified fuel is injected into the combustor, the power to compress nitrogen increases. A low NOx combustion technology which is capable of decreasing the power to compress nitrogen is a significant advance in gas turbine development with an oxygen-blown IGCC system. We have started to develop a low NOx combustion technology using medium-Btu coal gasified fuel produced in the oxygen-blown IGCC process. In this paper, the effect of nitrogen injected directly into the combustor on the thermal efficiency of the plant is discussed. A 1300 °C-class gas turbine combustor with a swirling nitrogen injection function designed with a stable and low NOx combustion technology was constructed and the performance of this combustor was evaluated under atmospheric pressure conditions. Analyses confirmed that the thermal efficiency of the plant improved by 0.2 percent (absolute), compared with a case where nitrogen is premixed with coal gasified fuel before injection into the combustor. Moreover, this new technique which injects nitrogen directly into the high temperature region in the combustor results in a significant reduction in NOx production from nitrogen fixation. We estimate that CO emission concentration decreases to a significant level under high pressure conditions, while CO emission concentration in contrast to NOx emission rises sharply with increases in quantity of nitrogen injected into the combustor.


Author(s):  
Alan S. Feitelberg ◽  
Michael A. Lacey

The General Electric Company has developed and successfully tested a full-scale, ‘F’ class (2550°F combustor exit temperature), rich-quench-lean (RQL) gas turbine combustor, designated RQL2, for low heating value (LHV) fuel and integrated gasification combined cycle applications. Although the primary objective of this effort was to develop an RQL combustor with lower conversion of fuel bound nitrogen to NOx than a conventional gas turbine combustor, the RQL2 design can be readily adapted to natural gas and liquid fuel combustion. RQL2 is the culmination of a 5 year research and development effort that began with natural gas tests of a 2″ diameter perforated plate combustor and included LHV fuel tests of RQL1, a reduced scale (6″ diameter) gas turbine combustor. The RQL2 combustor includes a 14″ diameter converging rich stage liner, an impingement cooled 7″ diameter radially-stratified-quench stage, and a backward facing step at the entrance to a 10″ diameter film cooled lean stage. The rich stage combustor liner has a novel double-walled structure with narrow circumferential cooling channels to maintain metal wall temperatures within design limits. Provisions were made to allow independent control of the air supplied to the rich and quench/lean stages. RQL2 has been fired for almost 100 hours with LHV fuel supplied by a pilot scale coal gasification and high temperature desulfurization system. At the optimum rich stage equivalence ratio NOx emissions were about 50 ppmv (on a dry, 15% O2 basis), more than a factor of 3 lower than expected from a conventional diffusion flame combustor burning the same fuel. With 4600 ppmv NH3 in the LHV fuel, this corresponds to a conversion of NH3 to NOx of about 5%. As conditions were shifted away from the optimum, RQL2 NOx emissions gradually increased until they were comparable to a standard combustor. A chemical kinetic model of RQL2, constructed from a series of ideal chemical reactors, matched the measured NOx emissions fairly well. The CO emissions were between 5 and 30 ppmv (on a dry, 15% O2 basis) under all conditions.


Author(s):  
C. S. Cook ◽  
J. C. Corman ◽  
D. M. Todd

The integration of gas turbines and combined cycle systems with advances in coal gasification and gas stream cleanup systems will result in economically viable IGCC systems. Optimization of IGCC systems for both emission levels and cost of electricity is critical to achieving this goal. A technical issue is the ability to use a wide range of coal and petroleum-based fuel gases in conventional gas turbine combustor hardware. In order to characterize the acceptability of these syngases for gas turbines, combustion studies were conducted with simulated coal gases using full scale advanced gas turbine (7F) combustor components. It was found that NOx emissions could be correlated as a simple function of stoichiometric flame temperature for a wide range of heating values while CO emissions were shown to depend primarily on the H2 content of the fuel below heating values of 130 Btu/scf (5125 kJ/NM3) and for H2/CO ratios less than unity. The test program further demonstrated the capability of advanced can-annular combustion systems to burn fuels from air-blown gasifiers with fuel lower heating values as low as 90 Btu/scf (3548 kJ/NM3) at 2300 F (1260 C) firing temperature. In support of ongoing economic studies, numerous IGCC system evaluations have been conducted incorporating a majority of the commercial or near commercial coal gasification systems coupled with “F” series gas turbine combined cycles. Both oxygen and air-blown configurations have been studied, in some cases with high and low temperature gas cleaning systems. It has been shown that system studies must start with the characteristics and limitations of the gas turbine if output and operating economics are to be optimized throughout the range of ambient operating temperature and load variation.


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