Structural-Sensitivity in Propylene Mild Oxidation on New [100] Oriented MoO3 Catalysts

Author(s):  
M. Abon ◽  
B. Mingot ◽  
J. Massardier ◽  
J.C. Volta
2021 ◽  
Vol 50 (6) ◽  
pp. 2143-2148
Author(s):  
Yongxing Tang ◽  
Kejia Li ◽  
Ajay Kumar Chinnam ◽  
Richard J. Staples ◽  
Jean'ne M. Shreeve

Mild oxidation reactions of nitrogen-rich heterocyclic rings lead to the formation of energetic compounds with the mono-N-oxide moiety which show good thermal stabilities and detonation performances.


Author(s):  
Mohammadtaghi Vakili ◽  
Wen Qiu ◽  
Giovanni Cagnetta ◽  
Jun Huang ◽  
Gang Yu

Catalysts ◽  
2020 ◽  
Vol 10 (8) ◽  
pp. 934 ◽  
Author(s):  
Raoof Bardestani ◽  
Rouholamin Biriaei ◽  
Serge Kaliaguine

Catalytic hydrogenation of aldehydes is required as the stabilizing step in bio-oils conversion. Ruthenium supported on carbon was used in the present work for hydrogenation of furfural (FF) to furfuryl alcohol (FA). Converting a biochar with no surface area and low carboxyl groups surface density to an outstanding catalyst support using a very simple mild air/steam oxidation is the original contribution of this work. The mildly oxidized biochar is impregnated with a targeted loading of 2.5 wt.% Ru via ion-exchange, using Ru(NH3)6Cl2 precursor. ICP analysis shows that the mild oxidation increases Ru adsorption capacity of untreated biochar from 1.2 to 2.2 wt.%. H2 chemisorption and TEM analysis indicate that the preliminary mild oxidation leads to higher Ru dispersion. XPS analysis also shows that the treatment prevents Ru from surface segregation. The highest value of 93% FA selectivity at 53% FF conversion was obtained in a batch autoclave reactor under optimized conditions.


Author(s):  
T. M. Sankaranarayanan ◽  
K. Thirunavukkarasu ◽  
M. Banu ◽  
A. Pandurangan ◽  
S. Sivasanker
Keyword(s):  

1980 ◽  
Vol 60 (3) ◽  
pp. 541-548 ◽  
Author(s):  
M. SCHNITZER ◽  
D. A. HINDLE

Three humic and one fulvic acid were degraded by mild chemical oxidation with peracetic acid, with special emphasis on the effects of this type of oxidation on N-containing components. The different types of N that were considered were NH4+-N, amino acid-N, amino sugar-N, NO2−-N + NO3−-N, and by difference from total N, "unknown" N. The behaviour toward mild chemical oxidation of all four preparations was essentially similar: there were decreases in mino acid-N, amino sugar-N and "unknown" N, increases in NH4+-N, NO2−-N + NO3−-N with one material, and in N-gases. The "unknown" N was not inert. Between 16.6 and 59.1% of the latter appeared to be converted, as a result of mild chemical oxidation, to NH3 and N-gases which were expelled from the systems. The results presented provide an insight into what happens to N-containing humic components as a result of mild oxidation.


1973 ◽  
Vol 27 (2) ◽  
pp. 341-357 ◽  
Author(s):  
I. Ziderman ◽  
J. Bel-Ayche
Keyword(s):  

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