Electronic structure and magnetic properties of a HoPdAl single crystal

We study the field and temperature dependences of the magnetization (B≤7.5 T, T=2.0-75 K) of samples from a single crystal Pb1-x-ySnxVyTe (x=0.08, y=0.01) ingot synthesized by the Bridgman method. It is established that the magnetization of the samples contains two main contributions: the Brillouin-type paramagnetism of vanadium ions and the diamagnetism of the crystal lattice. Experimental field and temperature dependences of the magnetization are discussed in the framework of a theoretical model of electronic structure rearrangement in Pb1-x-ySnxVyTe with doping and approximated as the sums of two terms based on the modified Brillouin functions for vanadium ions in the V3+ and V2+ states. The concentrations of magnetically active vanadium ions in two different charge states with increasing impurity concentration along the ingot are determined.

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Electronic Structure Analysis of the Difference between Cs2AgF4and Rb2MnF4in Their Magnetic Properties and Single-Crystal Structure Determination of Rb2MnF4

Chemistry of Materials ◽

10.1021/cm060465+ ◽

2006 ◽

Vol 18 (14) ◽

pp. 3281-3286 ◽

Cited By ~ 19

Author(s):

D. Dai ◽

M.-H. Whangbo ◽

J. Köhler ◽

C. Hoch ◽

A. Villesuzanne

Keyword(s):

Crystal Structure ◽

Magnetic Properties ◽

Electronic Structure ◽

Single Crystal ◽

Structure Analysis ◽

Structure Determination ◽

Single Crystal Structure ◽

Crystal Structure Determination ◽

The Difference

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Electronic structure of paramagnetic clusters of transition metal ions. 2. Crystal and molecular structure, single crystal EPR spectra, and magnetic properties of [Co6(.mu.3-S)8(PEt3)6](PF6)

Journal of the American Chemical Society ◽

10.1021/ja00051a023 ◽

1992 ◽

Vol 114 (25) ◽

pp. 9898-9908 ◽

Cited By ~ 22

Author(s):

Alessandro Bencini ◽

Carlo A. Ghilardi ◽

Annabella Orlandini ◽

Stefano Midollini ◽

Claudia Zanchini

Keyword(s):

Molecular Structure ◽

Magnetic Properties ◽

Electronic Structure ◽

Transition Metal ◽

Metal Ions ◽

Single Crystal ◽

Crystal And Molecular Structure ◽

Transition Metal Ions ◽

Epr Spectra

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Single crystal to single crystal transformation of spin-crossover coordination polymers from 3D frameworks to 2D layers

Journal of Materials Chemistry C ◽

10.1039/d1tc00470k ◽

2021 ◽

Vol 9 (15) ◽

pp. 5082-5087

Author(s):

Yu Gong ◽

Wang-Kang Han ◽

Hui-Shu Lu ◽

Qing-Tao Hu ◽

Huan Tu ◽

...

Keyword(s):

Magnetic Properties ◽

Single Crystal ◽

Coordination Polymers ◽

Ligand Exchange ◽

Spin Crossover ◽

Metal Organic Frameworks ◽

Crystal Transformation ◽

Metal Organic

New Hofmann-type metal–organic frameworks display rare and complete ligand exchange induced single crystal to single crystal transformations from 3D frameworks to 2D layers, accompanied by magnetic properties transition from two-step SCO behavior to hysteretic SCO behavior.

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Biaxial strain, electric field and interlayer distance-tailored electronic structure and magnetic properties of two-dimensional g-C3N4/Li-adsorbed Cr2Ge2Te6 van der Waals heterostructures

Physical Chemistry Chemical Physics ◽

10.1039/d1cp00003a ◽

2021 ◽

Vol 23 (10) ◽

pp. 6171-6181

Author(s):

Yaoqi Gao ◽

Baozeng Zhou ◽

Xiaocha Wang

Keyword(s):

Magnetic Properties ◽

Electronic Structure ◽

Electric Field ◽

Van Der Waals ◽

Interlayer Distance ◽

Two Dimensional ◽

Biaxial Strain ◽

Van Der Waals Heterostructures

It is found that the biaxial strain, electric field and interlayer distance can effectively modulate the electronic structure and magnetic properties of two-dimensional van der Waals heterostructures.

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Single Crystal Growth and Physical Properties of Pyroxene CoGeO3

Crystals ◽

10.3390/cryst11040378 ◽

2021 ◽

Vol 11 (4) ◽

pp. 378

Author(s):

Li Zhao ◽

Zhiwei Hu ◽

Hanjie Guo ◽

Christoph Geibel ◽

Hong-Ji Lin ◽

...

Keyword(s):

High Pressure ◽

Magnetic Properties ◽

Magnetic Susceptibility ◽

Crystal Growth ◽

Physical Properties ◽

Single Crystal ◽

Single Crystals ◽

Magnetic Moments ◽

Single Crystal Growth ◽

The Impact

We report on the synthesis and physical properties of cm-sized CoGeO3 single crystals grown in a high pressure mirror furnace at pressures of 80 bar. Direction dependent magnetic susceptibility measurements on our single crystals reveal highly anisotropic magnetic properties that we attribute to the impact of strong single ion anisotropy appearing in this system with TN∼33.5 K. Furthermore, we observe effective magnetic moments that are exceeding the spin only values of the Co ions, which reveals the presence of sizable orbital moments in CoGeO3.

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