scholarly journals Laboratory Study and Field Matching of Matrix Acidizing of Petroleum Reservoir Rocks

2002 ◽  
Vol 14 (1) ◽  
pp. 119-135
Author(s):  
Mohammed M. Amro
2012 ◽  
Vol 43 ◽  
pp. 20-25 ◽  
Author(s):  
Zhirong Zhang ◽  
Paul Greenwood ◽  
Qu Zhang ◽  
Dan Rao ◽  
Weijun Shi

2020 ◽  
Vol 11 (4) ◽  
pp. 817-828
Author(s):  
V. Plotkin ◽  
V. V. Potapov

Many minerals have semiconductor properties. It is known that petroleum reservoir rocks permeated with hydrocarbon fluids can sometimes behave as semiconductors. In the Earth’s magnetic field, the electrical conductivity of such materials becomes anisotropic, and the Hall effect is quite possible in rocks in natural conditions and detectable by magnetotelluric sounding. In the anisotropic medium, the field is subject to normal mode splitting, and its components show different attenuation coefficients and phase velocities. The modes differ due to polarization and rotation of the field vectors (clockwise in one mode, and counterclockwise in another). With account of the Hall effect, responses of the medium can be different when the medium is excited by a single normal wave. To detect the Hall effect in MTS surveys, we use the polarization analysis method and select the spectra of modes with right and left circular polarization. Special experiments were carried out to detect the contribution of the Hall effect during the MTS surveys. This article presents the first estimates of the Hall conductivity for the studied rocks.


Author(s):  
C. J. Stuart ◽  
L.-C. Liang ◽  
J. B. Toney

A new analytical technique has been developed to allow direct imaging of native-state petroleum reservoir rocks by the use of the scanning electron microscope (SEM) in a low voltage mode combined with a solid-state cryo-system device. The SEM investigation of native-state reservoir rock samples is important since it enables direct visualization of: (1) the spatial distributions of the fluids in the pore system; (2) clay minerals in their natural hydrated states; (3) the native mineralogy; (4) combined effects on the reservoir's wettability and permeability. The technique uses low voltage SEM to image the uncoated surface of the wet sample at a high vacuum and applies the cryostage to control the vapor pressure of the fluid phase while imaging. A differentially pumped environmental chamber is not required with this approach.This technique utilizes a solid-state thermoelectric cooler device (TED) to achieve the required sample cooling. The TED operates on the Peltier principle permitting the surface of the TED to reach a temperature as low as 110 degrees centigrade below its reference temperature. A sample stage is refitted with a TED substage which is water-cooled. The water-cooling of the substage coupled with the TED allows a precise control of the sample temperature. The sample is fixed to the substage so that it is in direct thermal contact with the TED. The TED is then biased (by the use of DC currents) to provide the effective cooling necessary to minimize vaporization of the interstitial fluids in the sample. The sample and stage temperatures are constantly monitored by means of two microtype-K thermocouple devices. With this approach, no liquid nitrogen is needed for this technique.


1950 ◽  
Vol 2 (07) ◽  
pp. 195-204 ◽  
Author(s):  
N.T. Burdine ◽  
L.S. Gournay ◽  
P.P. Reichertz

1976 ◽  
Vol 16 (05) ◽  
pp. 261-268 ◽  
Author(s):  
M.K. Dabbous ◽  
A.A. Reznik ◽  
B.G. Mody ◽  
P.F. Fulton ◽  
J.J. Taber

Abstract Drainage air-water capillary-pressure curves were obtained for Pittsburgh and Pocahontas coals at various overburden pressures. Capillary-pressure data were used to investigate pore-size characteristics. Results were indicative of the complex pore structure of coal, consisting primarily of a network of macro- and microfractures. In most cases, however, displacement pressure and residual water saturation increased at higher overburden pressure. Reasonable agreement between measured relative permeabilities and those calculated from capillary-pressure data with Purcell's model was obtained for only a few samples. Fracture permeabilities computed from pore-size distribution were lower than permeabilities pore-size distribution were lower than permeabilities actually measured at the same overburden pressure. Helium porosity was considerably higher than porosity determined by water saturation, indicating porosity determined by water saturation, indicating inaccessible pore volume to water. Pore compressibility was determined under triaxial stress-loading conditions. Changes in porosity with overburden pressure were more significant at pressures below 1,500 psig. Above this pressure, pore compressibility appeared to approach a pressure, pore compressibility appeared to approach a constant value averaging about 0.5 × 10(−4) psi(−1) for the coal samples studied. Introduction Increased interest in underground coal gasification and coal-seam degasification for the purpose of producing clean energy stimulated fundamental producing clean energy stimulated fundamental research into the phenomena of multiphase fluid flow through coal. Two previous papers presented results of investigation of the air- and water-permeability and relative-permeability characteristics at various overburden pressures for two different types of coal. However, to understand the mechanisms of two-phase flow (usually gas and water) through a complex porous system such as coal, one needs a clear insight into the internal pore structure of coal and the interaction between pore structure of coal and the interaction between this structure and the associated fluids. Such knowledge of the make-up of the pore structure helps in modeling fluid flow through the system and in interpreting permeability and relative-permeability data. Interaction between the pore structure and fluids results in the capillary-pressure phenomena. Capillary-pressure data have been used extensively to determine the pore characteristics of many petroleum reservoir rocks and to relate these petroleum reservoir rocks and to relate these characteristics to the single- and two-phase flow behavior in the rock. It is also known that natural fracture systems are the principal source of flow capacity of many petroleum reservoir rocks and contribute materially petroleum reservoir rocks and contribute materially to the storage capacity of some. Changes in fracture capacity resulting from changes in net overburden pressure have an important influence on the flow pressure have an important influence on the flow properties of the rock, as reported by Jones. In our properties of the rock, as reported by Jones. In our previous work with coal, which is a naturally previous work with coal, which is a naturally fractured system, absolute and effective permeabilities were found to be highly sensitive to overburden pressure (pov). Thus, it would be expected that the pressure (pov). Thus, it would be expected that the effect of Pov on the fracture flow capacity, capillary pressure, and pore compressibility is more dramatic pressure, and pore compressibility is more dramatic for coal. The internal structure of coal has been studied by microscopic methods, gas sorption measurements, and by mercury porosimetry. Data on helium porosity of different types of coal also can be porosity of different types of coal also can be found in Ref. 5. However, we are not aware of any determinations of capillary pressure in coal at different overburden pressures. In this paper gas-liquid capillary-pressure relationships for coal at different overburden pressures are presented. pressures are presented. SPEJ P. 261


1962 ◽  
Vol 2 (01) ◽  
pp. 18-20
Author(s):  
B.G. Hurd

HURD, B.G., SOCONY MOBIL OIL CO., INC., DALLAS, TEX. Abstract A liquid-Freon permeameter suitable for making routine permeability determinations on small plug samples is described. The instrument is characterized by simplicity of design and ease of operation, and can be assembled inexpensively from stock items of laboratory equipment. It combines the unique advantages of both liquid and gas permeameters while eliminating many undesirable features of both general classes of instruments. Precision and accuracy of the specific Freon permeability measurements compare favorably with results of conventional liquid and gas permeameters. Introduction The liquid-Freon permeameter described in this paper was designed and built for special investigations of the properties of petroleum reservoir rocks. However, its unique advantages over conventional gas and liquid permeameters make it eminently suitable for routine use in the core analysis of small plug samples. In general, gas permeameters are very popular because of their simplicity of design and ease of operation. However, apparent gas permeabilities are normally higher than true specific permeabilities unless special corrections for gas-slippage are applied. Since these corrections require two or more measurements at different internal gas pressures, much of the time advantage of the specific gas permeability measurements is lost. Liquid permeability measurements, on the other hand, require no slip correction, but liquid saturation of the sample is time-consuming and difficult to insure. Often, too, the saturating liquid must be extracted or dried from the plug before it can be used for another experiment. The liquid Freon permeameter described herein retains the inherent accuracy of the liquid permeameter, while affording the speed and ease of operation of the gas permeameter. Freon-12 (dichlorodifluoromethane) is a halogenated hydrocarbon, immiscible in the liquid phase with water. It may be considered as an oil phase in laboratory fluid-flow studies. Like butane and propane, it is a gas at normal room temperatures and atmospheric pressure but can be liquefied at moderate pressures. Complete liquid saturation of a plug sample with any of these fluids can be easily achieved by condensing vapors in the sample and operating the permeameter at a pressure above the vapor pressure of the liquid. Freon-12 is superior to butane or propane for permeability measurements only in that it is relatively non toxic and completely incombustible, and thus presents no fire or explosion hazard. Freon-12 is believed to be completely nonreactive with most petroleum-reservoir rock samples. It volatilizes immediately from a plug on depressurizing to leave a clean, dry sample suitable for subsequent experiments. Thus, the inherent risk of changing physical properties of rock samples by cleaning and drying operations between permeability measurement and subsequent experiments is eliminated. DESCRIPTION OF THE PERMEAMETER The design of the liquid Freon permeameter is shown schematically in Fig. 1. SPEJ P. 18^


2014 ◽  
Vol 122 ◽  
pp. 534-541 ◽  
Author(s):  
Maira A. Oliveira ◽  
Alexandre S.L. Vaz ◽  
Fernando D. Siqueira ◽  
Yulong Yang ◽  
Zhenjiang You ◽  
...  

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