Zirconium oxide film formation on zircaloy by water corrosion

2000 ◽  
Vol 48 (18-19) ◽  
pp. 4749-4754 ◽  
Author(s):  
J.S Moya ◽  
M Diaz ◽  
J.F Bartolomé ◽  
E Roman ◽  
J.L Sacedon ◽  
...  
Keyword(s):  
Oxide Film ◽  
Zirconium Oxide ◽  
Film Formation ◽  
Zirconium Oxide Film

A zirconium oxide film self-assembled at the air–water interface

2005 ◽  
Vol 357 (1-2) ◽  
pp. 27-33 ◽  
Author(s):  
M.J. Henderson ◽  
A. Gibaud ◽  
J.-F. Bardeau ◽  
A.R. Rennie ◽  
J.W. White
Keyword(s):  
Oxide Film ◽  
Zirconium Oxide ◽  
Water Interface ◽  
Air Water Interface ◽  
Self Assembled ◽  
Zirconium Oxide Film

XPS STUDIES OF THE STABILITY OF A ZIRCONIUM CARBIDE FILM IN THE PRESENCE OF ZIRCONIUM OXIDE AND HYDROGEN

1995 ◽  
Vol 02 (03) ◽  
pp. 297-303 ◽  
Author(s):  
P.C. WONG ◽  
Y.S. LI ◽  
K.A.R. MITCHELL
Keyword(s):  
Oxide Film ◽  
Photoelectron Spectroscopy ◽  
Zirconium Oxide ◽  
Room Temperature ◽  
Hydrogen Plasma ◽  
Zirconium Carbide ◽  
X Ray ◽  
The Stability ◽  
Zirconium Oxide Film ◽  
Carbide Component

X-ray photoelectron spectroscopy (XPS) has been used to study the interfacial chemistries of a 65-Å film prepared by depositing zirconium in an oxidizing environment onto a methane-pretreated 11-Å thick zirconium oxide film, which initially was deposited onto a gold substrate. The second metal deposition results in an outermost region composed of a mixed zirconium oxide, while below there is metallic zirconium followed by zirconium carbide and carbon on top of the first zirconium oxide film, which is itself in contact with the gold. The carbide component showed no changes on heating to 425°C, on treating with a hydrogen plasma at room temperature, or on heating the resulting film to 425°C. The oxide layers do show characteristic changes, and this also contrasts with earlier observations for a zirconium sulphide film. The zirconium carbide Zr3d 5/2 component has a binding energy of 180.6 eV.

Investigation of nano-structured Zirconium oxide film on Ti6Al4V substrate to improve tribological properties prepared by PIII&D

2017 ◽  
Vol 394 ◽  
pp. 586-597 ◽  
Author(s):  
Sehrish Saleem ◽  
R. Ahmad ◽  
R. Ayub ◽  
Uzma Ikhlaq ◽  
Weihong Jin ◽  
...  
Keyword(s):  
Oxide Film ◽  
Tribological Properties ◽  
Zirconium Oxide ◽  
Ti6al4v Substrate ◽  
Zirconium Oxide Film

Protective Behavior of Anodic Zirconium Oxide Film

2009 ◽  
pp. 643-643-7 ◽  
Author(s):  
N El-Massry ◽  
SM Bedair ◽  
FH Hammad
Keyword(s):  
Oxide Film ◽  
Zirconium Oxide ◽  
Protective Behavior ◽  
Zirconium Oxide Film

Passivity of Zirconium In Sulfuric Acid Solutions–Effect of Cathodic Pretreatment

CORROSION ◽  
1973 ◽  
Vol 29 (2) ◽  
pp. 59-63 ◽  
Author(s):  
K. ELAYAPERUMAL ◽  
S. S. CHOUTHAI ◽  
J. BALACHANDRA
Keyword(s):  
Zirconium Oxide ◽  
Room Temperature ◽  
Cathodic Polarization ◽  
Film Formation ◽  
Saturated Calomel Electrode ◽  
Protective Film ◽  
Cathodic Pretreatment ◽  
Polarization Studies ◽  
Zirconium Oxide Film ◽  
Sulfuric Acid Solutions

Abstract The effect of cathodic pretreatment at −1.3 V vs a saturated calomel electrode (SCE) on the passivity of Kroll zirconium in 5, 10, and 20 vol % H2SO4 solution at room temperature was determined through potentiostatic anodic polarization studies. The cathodic treatment made the attainment of passivity easier and reduced the passive currents considerably. Studies on potential vs time and active and passive currents vs time indicated a protective film formation during the cathodic treatment. The possibility of a zirconium oxide film formation due to cathodic polarization induced alkalinity at −1.3 V (SCE) is discussed.

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