Application of Cathodoluminescence Imaging to the Study of Sedimentary Rocks

Sediments commonly contain organic material which appears as refractory carbonaceous material in metamorphosed sedimentary rocks. Grew and others have shown that relative carbon content, crystallite size, X-ray crystallinity and development of well-ordered graphite crystal structure of the carbonaceous material increases with increasing metamorphic grade. The graphitization process is irreversible and appears to be continous from the amorphous to the completely graphitized stage. The most dramatic chemical and crystallographic changes take place within the chlorite metamorphic zone.The detailed X-ray investigation of crystallite size and crystalline ordering is complex and can best be investigated by other means such as high resolution transmission electron microscopy (HRTEM). The natural graphitization series is similar to that for heat-treated commercial carbon blacks, which have been successfully studied by HRTEM (Ban and others).

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Charging microscopy and cathodoluminescence imaging of semi-insulating gallium arsenide

Proceedings, annual meeting, Electron Microscopy Society of America ◽

10.1017/s042482010014542x ◽

1986 ◽

Vol 44 ◽

pp. 816-817

Author(s):

T.C. Sheu ◽

S. Myhajlenko ◽

D. Davito ◽

J.L. Edwards ◽

R. Roedel ◽

...

Keyword(s):

Integrated Circuits ◽

Secondary Electron ◽

Crystal Defects ◽

Device Performance ◽

Gaas Wafer ◽

Surface Charging ◽

Gaas Substrates ◽

Voltage Contrast ◽

Cathodoluminescence Imaging ◽

Scanning Electron

Liquid encapsulated Czochralski (LEC) semi-insulating (SI) GaAs has applications in integrated optics and integrated circuits. Yield and device performance is dependent on the homogeniety of the wafers. Therefore, it is important to characterise the uniformity of the GaAs substrates. In this respect, cathodoluminescence (CL) has been used to detect the presence of crystal defects and growth striations. However, when SI GaAs is examined in a scanning electron microscope (SEM), there will be a tendency for the surface to charge up. The surface charging affects the backscattered and secondary electron (SE) yield. Local variations in the surface charge will give rise to contrast (effectively voltage contrast) in the SE image. This may be associated with non-uniformities in the spatial distribution of resistivity. Wakefield et al have made use of “charging microscopy” to reveal resistivity variations across a SI GaAs wafer. In this work we report on CL imaging, the conditions used to obtain “charged” SE images and some aspects of the contrast behaviour.

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Stabilizing pyritic material

The Paleontological Society Special Publications ◽

10.1017/s2475262200005207 ◽

1989 ◽

Vol 4 ◽

pp. 244-248 ◽

Cited By ~ 2

Author(s):

Donald L. Wolberg

Keyword(s):

Significant Contribution ◽

Organic Materials ◽

Sedimentary Rocks ◽

Iron Sulfides ◽

Decomposition Products ◽

Iron Minerals ◽

Pyrite Formation ◽

Organic Sediments ◽

Freshwater Environments

The minerals pyrite and marcasite (broadly termed pyritic minerals) are iron sulfides that are common if not ubiquitous in sedimentary rocks, especially in association with organic materials (Berner, 1970). In most marine sedimentary associations, pyrite and marcasite are associated with organic sediments rich in dissolved sulfate and iron minerals. Because of the rapid consumption of sulfate in freshwater environments, however, pyrite formation is more restricted in nonmarine sediments (Berner, 1983). The origin of the sulfur in nonmarine environments must lie within pre-existing rocks or volcanic detritus; a relatively small, but significant contribution may derive from plant and animal decomposition products.

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