scholarly journals The distribution of Pre-Westphalian source rocks in the North German Basin – Evidence from magnetotelluric and geochemical data

2001 ◽  
Vol 80 (1) ◽  
pp. 71-84 ◽  
Author(s):  
N. Hoffmann ◽  
H. Jödicke ◽  
P. Gerling

AbstractFor the first time this project attempts to directly correlate magnetotelluric and geochemical data with the aim of creating a model on the regional distribution of potential pre-Westphalian source rocks deposited in marine environments in the North German basin.Analysis of the magnetotelluric data shows, that there is a deep good conductor at the north-eastern fringe of the North German basin around the islands of Rügen and Usedom and on the mainland north east of the Anklam Fault. Through integration with seismic data and the offshore well G14 the conductor can be correlated with the Cambro-Ordovician Scandinavian Alum shales. To the south an adjoining area approximately corresponding to the depo-centre of the Rotliegend basin lacks a deep good conductor. Therefore it can be assumed that a regional distribution of comparable source rocks is unlikely. Another excellent and important conductor starts to the south west of the Lower Elbe Line extending along the Dutch-German border into the North Sea, and into the Münsterland. Its place in the local stratigraphy has not been adequately established. It is most likely that this good conductor corresponds to the black shales of the Early Namurian and the Dinantian, which is the case in the boreholes Münsterland 1 and Pröttlin 1 for example. In this paper they are collectively called Rhenohercynian Alum shales. On the Dutch-German border a transition into the “Bowland Shale” facies or equivalents is to be expected. It cannot be ruled out that even stratigraphically older black shales, possibly from the Cambro-Ordovician could contribute to the high integrated conductivity of the deep good conductor.The evidence of highly conductive layers in the deep subsurface poses the question whether these layers could be potential source rocks for the gases in the north German gas fields. This question can be answered with a clear yes. Gas and isotope geochemical studies on gases from producing Rotliegend deposits have shown that Rhenohercynian Alum shales have been a significant source for these fields. This will be illustrated in detail using the gas fields from the production province “Ems Estuary” as an example.

Geosciences ◽  
2018 ◽  
Vol 8 (8) ◽  
pp. 283 ◽  
Author(s):  
Patrick Nadoll ◽  
Meike Rehm ◽  
Florian Duschl ◽  
Reiner Klemd ◽  
Dennis Kraemer ◽  
...  

Hydrothermal fluorites from Paleozoic sedimentary rocks and volcanic units in the North German Basin (NGB) have been investigated to create a petrographic and geochemical inventory—with particular focus on strategic elements such as rare earth elements (REE)—and to uncover possible links between the post-Variscan hydrothermal mineralization in the NGB and bordering areas such as the Harz Mountains and Flechtingen Calvörde Block (FCB). Fluorites from ten localities underwent a detailed petrographic examination, including SEM-BSE/CL imagery, and were compositionally analysed using LA-ICP-MS. Overall, REY concentrations are comparatively low in fluorite from all investigated areas—the median sum of REY ranges from 0.3 to 176 ppm. EuropiumCN anomalies are slightly negative or absent, indicating that either the formation fluid experienced temperatures above 250 °C or that fluid-rock interactions and REE enrichment was likely controlled by the source rock (i.e., volcanic) composition and complexation processes. Fluorites from the Altmark-Brandenburg Basin (ABB) and the Lower Saxony Basin (LSB) display distinctly different REYCN signatures, suggesting that fluid compositions and genetic processes such as fluid-rock interaction differed significantly between the two areas. Complex growth zones and REYCN signatures in fluorite from the ABB and the FCB reflect geochemical variability due to adsorption processes and intrinsic crystallographic controls and imply that they are genetically related. Two petrographically and geochemically distinct generations are observed: Fluorite I—light SEM shades, relatively enriched in LREE; Fluorite II—darker SEM shades, comparatively depleted LREE, slightly higher HREE concentrations. These fluorite generations represent zoned (or cyclical) growth within a single progressive hydrothermal event and do not reflect a secondary remobilization process. We demonstrate that increasing Tb/La ratios and decreasing La/Ho ratios can be the result of continuous zoned growth during a single mineralizing event, with significant compositional variations on a micron-scale. This has implications for the interpretation of such trends and hence the inferred genetic evolution of fluorite that displays such geochemical patterns. The complex micro-scale intergrowth of these generations stresses the need for detailed petrographic investigations when geochemical data are collected and interpreted for mineral exploration.


Geophysics ◽  
2005 ◽  
Vol 70 (4) ◽  
pp. R45-R56 ◽  
Author(s):  
Lars Nielsen ◽  
Hans Thybo ◽  
Martin Glendrup

Seismic wide-angle data were recorded to more than 300-km offset from powerful airgun sources during the MONA LISA experiments in 1993 and 1995 to determine the seismic-velocity structure of the crust and uppermost mantle along three lines in the southeastern North Sea with a total length of 850 km. We use the first arrivals observed out to an offset of 90 km to obtain high-resolution models of the velocity structure of the sedimentary layers and the upper part of the crystalline crust. Seismic tomographic traveltime inversion reveals 2–8-km-thick Paleozoic sedimentary sequences with P-wave velocities of 4.5–5.2 km/s. These sedimentary rocks are situated below a Mesozoic-Cenozoic sequence with variable thickness: ∼2–3 km on the basement highs, ∼2–4 km in the Horn Graben and the North German Basin, and ∼6–7 km in the Central Graben. The thicknesses of the Paleozoic sedimentary sequences are ∼3–5 km in the Central Graben, more than 4 km in the Horn Graben, up to ∼4 km on the basement highs, and up to 8 km in the North German Basin. The Paleozoic strata are clearly separated from the shallower and younger sequences with velocities of ∼1.8–3.8 km/s and the deeper crystalline crust with velocities of more than 5.8–6.0 km/s in the tomographic P-wave velocity model. Resolution tests show that the existence of the Paleozoic sediments is well constrained by the data. Hence, our wide-angle seismic models document the presence of Paleozoic sediments throughout the southeastern North Sea, both in the graben structures and in deep basins on the basement highs.


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