Restite-melt and mafic-felsic magma mixing and mingling in an S-type dacite, Cerro del Hoyazo, southeastern Spain

Author(s):  
H. P. Zeck

ABSTRACTApproximately 10-15 vol% of the Neogene Hoyazo dacite consists of Al-rich restite rock inclusions (A12O3 = 20–45%) and monocrystal inclusions derived therefrom. Restite material and dacitic melt were formed syngenetically from a (semi-)pelitic rock sequence by means of anatexis. Restite rock fragments and dacite show similar high δ18O values (13–16‰) corresponding to those found for sedimentary material. Striking monocrystal restite inclusions in the dacite rock are graphite crystals measuring a few hundred μm, 0.5–10 mm blue cordierite crystals and 2–10 mm ruby red crystals of almandine-rich garnet (1.1 ± 0.2 vol%). Although the almandine crystals are perfectly euhedral, they are identical in every respect to the crystals found in the Al-rich restite rock inclusions and cannot be crystallisation products of the magmatic melt. The dacite also contains many inclusions of quartz gabbroic and basaltoid material which contains inclusions identical to the restite material found in the dacitic glass base. Many basaltoid inclusions show well-developed chilled borders. These inclusions may represent a more mafic magma of deeper origin which mixed with some dacite magma before mingling into it.

2021 ◽  
Author(s):  
Barbara Cserép ◽  
Zoltán Kovács ◽  
Kristóf Fehér ◽  
Szabolcs Harangi

<p>Identification of trans-crustal magma reservoir processes beneath volcanoes is a crucial task to better understand the behaviour and possible future activities of volcanic systems. Detailed petrological investigations have a fundamental role in such studies. Dacitic magmas are usually formed in an upper crustal magma reservoir by complex open-system processes including crystal fractionation and magma mixing following recharge events. Conditions of such processes are usually constrained by crystal-scale studies, whereas there is much less information about the petrogenetic processes occurring in the lower crustal hot zone. Here we provide insight into such processes by new results on amphibole crystal clots found in dacitic pumices from an explosive volcanic suite of the Ciomadul volcano, the youngest one in eastern-central Europe.</p><p>Amphibole is a common mineral phase of the Ciomadul dacites, occuring as phenocrysts and antecrysts, but occasionally they also form crystal clots with an inner core of either pyroxene or olivine with high Mg-numbers. Olivine is observed mostly in the 160-130 ka lava dome rocks, whereas the younger explosive eruption products are characterised by orthopyroxene and clinopyroxene. Such mafic crystal clots are most common in the pumices of the earliest explosive eruptions, which occurred after long quiescence at 56-45 ka. The most common appearance has high-Mg pyroxene core (mg#: 0.76-0.92) rimmed by amphibole. Two types of amphibole are found in such clots: irregular zone of actinolite to magnesio-hornblende directly around orthopyroxene and high Mg-Al pargasitic amphibole as the outer zone. Several crystal clots contain smaller amphibole crystals with diffuse transition to clinopyroxene at the inner part and complexly zoned amphibole with biotite inclusions in the outer part. These amphibole and pyroxene have lower Mg-number (< 0.80), and higher MnO content (up to 0.52 wt%) than the most common type. In both cases, amphibole could be a peritectic product of earlier-formed pyroxenes, which reacted with water-rich melt at higher and lower temperatures, respectively. Actinolite to magnesio-hornblende at the contact represents a transitional phase between pyroxene and the newly formed amphibole. In a few cases, crystal clots contain amphibole inclusions in pyroxene macrocrysts. These amphiboles have a particular composition not yet reproduced by experiments: they have high mg# (>0.86), but low tetrahedral Al (0.9-1.0 apfu) and usually high Cr content (Cr<sub>2</sub>O<sub>3</sub> is up to 0.9 wt%), similar to the orthopyroxene and clinopyroxene hosts (0.26-0.71 and 0.78-0.89 wt%, respectively). We interpret these amphiboles as an early formed liquidus phase crystallized along with pyroxene from an ultra-hydrous mafic magma. Occasionally, crystal clots are complexly zoned amphibole macrocrysts with dispersed clinopyroxene inclusions. The amphibole has a wide compositional range, usually with high Mg-Al pargasitic core. These amphiboles could have formed by peritectic reaction between clinopyroxene and a water-rich melt.</p><p>The observed mafic crystal clots in the dacites indicate the presence of strongly hydrous mafic magmas accumulated probably at the crust-mantle boundary. During mafic recharge, volatile transfer may contribute to the crystal mush rejuvenation at shallow depth and triggering explosive eruptions.</p><p>This research was financed by the Hungarian National Research, Development and Innovation Fund (NKFIH) within K135179 project.</p>


2020 ◽  
Vol 57 (9) ◽  
pp. 1011-1029
Author(s):  
Gabriel Sombini dos Santos ◽  
Sandra M. Barr ◽  
Chris E. White ◽  
Deanne van Rooyen

The Margaree pluton extends for >40 km along the axis of the Ganderian Aspy terrane of northern Cape Breton Island, Nova Scotia. The pluton consists mainly of coarse-grained megacrystic syenogranite, intruded by small bodies of medium-grained equigranular syenogranite and microgranite porphyry, all locally displaying rapakivi texture. The three rock types have similar U–Pb (zircon) ages of 363 ± 1.6, 364.8 ± 1.6, and 365.5 ± 3.3 Ma, respectively, consistent with field and petrological evidence that they are coeval and comagmatic. The rare earth elements display parallel trends characterized by enrichment in the light rare earth elements, flat heavy rare earth elements, moderate negative Eu anomalies, and, in some cases, positive Ce anomalies. The megacrystic and rapakivi textures are attributed to thermal perturbation in the magma chamber caused by the mixing of mafic and felsic magma, even though direct evidence of the mafic magma is mainly lacking at the current level of exposure. Magma evolution was controlled by fractionation of quartz, K-feldspar, and Na-rich plagioclase in molar proportions of 0.75:0.12:0.13. The chemical and isotopic (Sm–Nd) signature of the Margaree pluton is consistent with the melting of preexisting continental crust that was enriched in heat-producing elements, likely assisted by intrusion of mantle-derived mafic magma during Late Devonian regional extension. The proposed model involving magma mixing at shallow crustal levels in a cryptic silicic-mafic magma chamber during post-Acadian extension is consistent with models for other, better exposed occurrences of rapakivi granite in the northern Appalachian orogen.


2015 ◽  
Vol 104 (8) ◽  
pp. 2033-2055 ◽  
Author(s):  
Michael Abratis ◽  
Lothar Viereck ◽  
Jörg A. Pfänder ◽  
Roland Hentschel

Minerals ◽  
2020 ◽  
Vol 10 (2) ◽  
pp. 171 ◽  
Author(s):  
Huasheng Qi ◽  
Sanming Lu ◽  
Xiaoyong Yang ◽  
Jianghong Deng ◽  
Yuzhang Zhou ◽  
...  

The newly exploited Qiaomaishan Cu−W deposit, located in the Xuancheng ore district in the MLYRB, is a middle-sized Cu–W skarn-type polymetallic deposit. As Cu–W mineralization is a rare and uncommon type in the Middle-Lower Yangtze River Belt (MLYRB), few studies have been carried out, and the geochemical characteristics and petrogenesis of Qiaomaishan intrusive rocks related to Cu–W mineralization are not well documented. We studied two types of ore-bearing intrusive rocks in the Qiaomaishan region, i.e., pure granodiorite porphyry and granodiorite porphyry with mafic microgranular enclaves (MMEs). Age characterization using zircon LA–ICP–MS showed that they were formed almost simultaneously, around 134.9 to 135.1 Ma. Granodiorite porphyries are high Mg# adakites, characterized by high-K calc-alkaline and metaluminous features that are enriched in LILEs (e.g., Sr and Ba) and LREEs, but depleted in HFSEs (e.g., Nb, Ta, and Ti) and HREEs. Moreover, they have enriched Sr–Nd–Hf isotopic compositions (with whole-rock (87Sr/86Sr)i ratios (0.706666−0.706714), negative εNd(t) values of −9.1 to −8.6, negative zircon εHf(t) values of −12.2 to −6.7, and two-stage Hf model ages (TDM2) between 1.5 and 2.0 Ga). However, compared to host rocks, the granodiorite porphyry with MMEs shows variable geochemical compositions, e.g., high Mg#, Cr, Ni, and V contents and enriched with LILEs. In addition, they have more depleted ISr, εNd(t), and εHf(t) values (0.706025 to 0.706269, −6.4 to −7.4, and −10.6 to −5.7, respectively), overlapping with regions of Early Cretaceous mafic rocks derived from enriched lithospheric mantle in the MLYRB. Coupled with significant disequilibrium textures and geochemical features of host rocks and MMEs, we propose that those rocks have resulted from mixing the felsic lower crust-derived magma and the mafic magma generated from the enriched mantle. The mixed magmas subsequently rose to shallow crust to form the ore-bearing rocks and facilitate Cu–W mineralization.


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