Alkali-feldspar and Fe-Ti oxide exsolution textures as indicators of the distribution and subsolidus effects of magmatic ‘water’ in the Klokken layered syenite intrusion, South Greenland

1980 ◽  
Vol 71 (1) ◽  
pp. 1-12 ◽  
Author(s):  
Ian Parsons
Keyword(s):  
Gas Phase ◽  
Water Distribution ◽  
Alkali Feldspar ◽  
Sharp Change ◽  
Magmatic Evolution ◽  
Fine Grained ◽  
Rock Types ◽  
Ti Oxides ◽  
Normal Zoning ◽  
Granular Layers

ABSTRACTThe layered syenites in the Klokken intrusion consist of horizons of fine-grained, granular-textured ferroaugite syenite showing inverted cryptic layering, interleaved with coarser, laminated, more fractionated hedenbergite syenite. Distribution of hydrous mafic phases indicates build-up of water in parallel with magmatic evolution, and druses and pegmatitic segregations in the laminated syenites are evidence for late development of a gas phase. Feldspar bulk compositions are close to the minimum on the Ab-Or binary, with An decreasing from An7 to An1 with fractionation, and normal zoning in cryptoperthite crystals. Feldspars in granular syenites are transparent coherent cryptoperthites or braid microperthites; An-content is probably the main control of fine-perthite coarseness. Laminated syenite feldspars are turbid, coarse patch microperthites with rare relics of braid textures. This non-coherent coarsening was caused by interactions between feldspars and water entrapped at magmatic temperatures which was retained within the original lithologies to low subsolidus temperatures. Fe-Ti oxides reflect this water distribution, with regular trellis ilmenite-titanomagnetite intergrowths in less fractionated rocks and ragged granule exsolution in more advanced syenites. The sharp change in exsolution textures at granular-laminated syenite boundaries implies steep water-gradients within these interleaved rock types. Water was unable to penetrate the granular layers and did not circulate freely in the cooling intrusion.

scholarly journals Age and origin of the Cannon Point syenite, Essex County, New York: southernmost expression of Monteregian Hills magmatism?

2017 ◽  
Vol 54 (4) ◽  
pp. 379-392
Author(s):  
David G. Bailey ◽  
Marian Lupulescu ◽  
Jeffrey Chiarenzelli ◽  
Jonathan P. Traylor
Keyword(s):  
New York ◽  
New York State ◽  
Alkali Feldspar ◽  
Crustal Material ◽  
Lake Champlain ◽  
Essex County ◽  
York State ◽  
Fine Grained ◽  
The North ◽  
Basement Faults

Two syenite sills intrude the local Paleozoic strata of eastern New York State and are exposed along the western shore of Lake Champlain. The sills are fine-grained, alkali feldspar syenites and quartz syenites, with phenocrysts of sanidine and albite. The two sills are compositionally distinct, with crossing rare earth element profiles and different incompatible element ratios, which eliminates the possibility of a simple petrogenetic relationship. Zircon extracted from the upper sill yields a U–Pb age of 131.1 ± 1.7 Ma, making the sills the youngest known igneous rocks in New York State. This age is similar to that of the earliest intrusions in the Monteregian Hills of Quebec, >100 km to the north. Sr and Nd radiogenic isotope ratios are also similar to those observed in some of the syenitic rocks of the eastern Monteregian Hills. The Cannon Point syenites have compositions typical of A-type, within-plate granitoids. They exhibit unusually high Ta and Nb concentrations, resulting in distinct trace element signatures that are similar to those of the silicic rocks of the Valles Caldera, a large, rift-related magmatic system. We suggest that the Cannon Point syenites were melts derived primarily by anatexis of old, primitive, lower crustal material in response to Mesozoic rifting and to the intrusion of mantle-derived magmas. The sills indicate that the effects of continental rifting were spatially and temporally extensive, resulting in the reactivation of basement faults in the Lake Champlain Valley hundreds of kilometers west of the active rift boundary, and crustal melting >50 Ma after the initiation of rifting.

scholarly journals Composition and origin of nodules from the ≈20 ka Pomici di Base (PB)-Sarno eruption of Mt. Somma — Vesuvius, Italy

2012 ◽  
Vol 4 (2) ◽  
Author(s):  
Rita Klébesz ◽  
Robert Bodnar ◽  
Benedetto Vivo ◽  
Kálmán Török ◽  
Annamaria Lima ◽  
...  
Keyword(s):  
Melt Inclusions ◽  
Alkali Feldspar ◽  
Sem Analysis ◽  
Chemical Compositions ◽  
Type I ◽  
Type Ii ◽  
Vapor Bubbles ◽  
Ti Oxides ◽  
Basaltic Composition ◽  
Dark Green

AbstractNodules (coarse-grain “plutonic” rocks) were collected from the ca. 20 ka Pomici di Base (PB)-Sarno eruption of Mt. Somma-Vesuvius, Italy. The nodules are classified as monzonite-monzogabbro based on their modal composition. The nodules have porphyrogranular texture, and consist of An-rich plagioclase, K-feldspar, clinopyroxene (ferroan-diopside), mica (phlogopite-biotite) ± olivine and amphibole. Aggregates of irregular intergrowths of mostly alkali feldspar and plagioclase, along with mica, Fe-Ti-oxides and clinopyroxene, in the nodules are interpreted as crystallized melt pockets.Crystallized silicate melt inclusions (MI) are common in the nodules, especially in clinopyroxenes. Two types of MI have been identified. Type I consists of mica, Fe-Ti-oxides and/or dark green spinel, clinopyroxene, feldspar and a vapor bubble. Volatiles (CO2, H2O) could not be detected in the vapor bubbles by Raman spectroscopy. Type II inclusions are generally lighter in color and contain subhedral feldspar and/or glass and several opaque phases, most of which are confirmed to be oxide minerals by SEM analysis. Some of the opaque-appearing phases that are below the surface may be tiny vapor bubbles. The two types of MI have different chemical compositions. Type I MI are classified as phono-tephrite — tephri-phonolite — basaltic trachy-andesite, while Type II MI have basaltic composition. The petrography and MI geochemistry led us to conclude that the nodules represent samples of the crystal mush zone in the active plumbing system of Mt. Somma-Vesuvius that were entrained into the upwelling magma during the PB-Sarno eruption.

Formation of the hour-glass structure in augite

1969 ◽  
Vol 37 (288) ◽  
pp. 472-479 ◽  
Author(s):  
D. F. Strong
Keyword(s):  
Glass Structure ◽  
Coarse Grained ◽  
Crystal Face ◽  
Thin Sections ◽  
Rapid Crystallization ◽  
Fine Grained ◽  
Rock Types ◽  
The Common

SummaryA study of augite in over three hundred thin sections of mainly alkalic rocks permits the distinction of two main types of hour-glass structure. The common ‘swallow-tailed’, sometimes skeletal augite crystals are found in the fine-grained groundmass of many rock types, and it is suggested that rapid crystallization alone accounts for their formation. Hence, this type of hour-glass structure has been called ‘quench hour-glass’. The hour-glass structures of larger augite crystals of porphyritic and coarse-grained rocks are commonly described as hour-glass ‘zoning’, as they result primarily from compositional differences between the different sectors. These were formed under conditions of relatively slower cooling than the ‘quench hour-glass’, and thus cannot be explained in the same way. They are thought to have formed by a process involving adsorption of impurities on a particular crystal face so as to impede growth of these faces, producing an initial skeleton of hour-glass form, which is completed by later crystallization of augite richer in FeO, Na2O, TiO2, and Al2O3. This hypothesis also explains the patchy zoning of other augite crystals, casting doubt on some petrogenetic interpretations of such zones as core zones.

Subsolidus crystallization behaviour in the system KAlSi3O8–NaAlSi3O8–H2O

1969 ◽  
Vol 37 (286) ◽  
pp. 173-180 ◽  
Author(s):  
Ian Parsons
Keyword(s):  
Water Vapour ◽  
Alkali Feldspar ◽  
Starting Material ◽  
Crystallization Behaviour ◽  
Temperature Range ◽  
Feldspar Composition ◽  
Normal Zoning

SummaryWhen gels and glasses of alkali feldspar composition are crystallized hydrothermally below their solidus the crystals present when crystallization is incomplete do not have the same Na:K ratio as the starting material but bear a relation to the starting material analogous to that between crystals and liquids coexisting at the liquidus. This effect has been investigated in the temperature range 700–850 °C at water-vapour pressures between 5000 lb/in.2 and 30000 lb/in.2 Fractionation and normal zoning of crystals may, in principle, occur within fixed bulk compositions held under isothermal, isobaric conditions.

scholarly journals Crack-enhanced weathering in inscribed marble: a possible application in epigraphy

2021 ◽  
Vol 33 (2) ◽  
pp. 189-202
Author(s):  
Stylianos Aspiotis ◽  
Jochen Schlüter ◽  
Kaja Harter-Uibopuu ◽  
Boriana Mihailova
Keyword(s):  
Raman Spectroscopy ◽  
Penetration Depth ◽  
Environmental Conditions ◽  
Coarse Grained ◽  
Asia Minor ◽  
X Ray Diffraction ◽  
Western Turkey ◽  
Fine Grained ◽  
Rock Types ◽  
Micro Cracks

Abstract. Raman spectroscopy has been applied to check if there are detectible material differences beneath the inscribed and non-inscribed areas of marble-based written artefacts, which could be further used to visualize lost or hardly readable text via suitable mapping. As a case study, marble segments with ∼ 2000-year-old inscribed letters from Asia Minor (western Turkey) and marble gravestones with 66 ± 14-year-old inscriptions from the cemetery of Ohlsdorf (Hamburg, Germany) have been subjected to Raman spectroscopy, as well as to complementary X-ray diffraction, wavelength-dispersive electron probe microanalysis, and Fourier-transform infrared spectroscopy, to thoroughly study the effect of different environmental conditions, grain size, and inscription age on the nature and penetration depth of marble alteration. The results demonstrate that environmental conditions rule over the type of dominant weathering changes, which are carotenoid molecular inclusions produced by lichen and amorphous carbon for marbles from Hamburg and Asia Minor, respectively. The alteration is much stronger in medium- and coarse-grained than in fine-grained marble, but it is suppressed by letter colouring. In the absence of letter colouring, the weathering-related products in both ancient and modern engraved marbles are more abundant beneath than away from the engraved areas, and the penetration depth is larger due to the enhancement of fissures and micro-cracks around the inscribed areas. We show that the Raman intensity ratio between the strongest peak of the weathering-related product (ν(C=C) ∼ 1520 cm−1 for carotenoids or the G peak ∼ 1595 cm−1 for soot-like carbon) and the strongest peak of marble (CO3 stretching near 1087 cm−1) can serve as a quantitative marker to indirectly map the lateral distribution of cracks induced during the inscribing process and hence can potentially be used to trace lost text on vanished marble inscriptions. This approach can be applied to other rock types, but further studies are required to identify the corresponding autochthonous weathering-related products.

scholarly journals An Overview on the Classification and Tectonic Setting of Neoproterozoic Granites of the Nubian Shield, Eastern Desert, Egypt

Geochemistry ◽  
2021 ◽  
Author(s):  
Gaafar A. El Bahariya
Keyword(s):  
Continental Crust ◽  
Tectonic Setting ◽  
Alkali Feldspar ◽  
Eastern Desert ◽  
Granitic Rocks ◽  
Rock Types ◽  
Nubian Shield ◽  
Magma Sources ◽  
Tectonic Settings ◽  
Ocean Ridge

Granites constitute the main rock components of the Earth’s continental crust, which suggested to be formed in variable geodynamics environments. The different types of granitic rocks, their compositional characteristics, tectonic settings and magma sources are outlined. Mineralogical classification of granites includes four rock types: tonalites, granodiorites, granite (monzogranite and syenogranites) and alkali-feldspar granites. Alphabetical classification subdivided granites into: I-type, S-type, A-type and M-type granites. Moreover, formation of granitic magmas requires distinctive geodynamic settings such as: volcanic arc granite (Cordilleran); collision-related granites (leucogranites); intra-plate and ocean ridge granites. The Eastern Desert of Egypt (ED) forms the northern part of Nubian Shield. Both older and younger granites are widely exposed in the ED. Old granites (OG) comprise tonalites and granodiorites of syn- to late-orogenic granitoid assemblages. They are calcalkaline, I-type, metaluminous and display island arc tectonic setting. Younger granites (YG) on the other hand, include granites, alkali-feldspar granites and minor granodiorites. They are of I- and A-type granites and of post-orogenic to anorogenic tectonic settings. The majority of the YG are alkaline, A-type granite and of within-plate tectonic setting (WPG). The A-type granites are subdivided into: A2-type postorogenic granites and A1-type anorogenic granites. Granite magma genesis involves: (a) fractional crystallization of mafic mantle-derived magmas; (b) anatexis or assimilation of old, upper crustal rocks (c) re - melting of juvenile mafic mantle – derived rocks underplating the continental crust. Generally, older I-type granitoids were interpreted to result from melting of mafic crust and dated at approximately 760–650 Ma, whereas younger granites suggested to be formed as a result of partial melting of a juvenile Neoproterozoic mantle source. Moreover, they formed from anatectic melts of various crustal sources that emplaced between 600 and 475 Ma.

Composition and structural state of coexisting feldspars, Salton Sea geothermal field

1986 ◽  
Vol 50 (355) ◽  
pp. 75-84 ◽  
Author(s):  
S. Douglas McDowell
Keyword(s):  
Excellent Agreement ◽  
Structural State ◽  
Alkali Feldspar ◽  
Geothermal Field ◽  
Salton Sea ◽  
Geothermal System ◽  
Temperature Range ◽  
Fine Grained ◽  
Alkali Feldspars

AbstractActive metamorphism of fine grained sandstone in the c.16000 year old Salton Sea geothermal system has produced a suite of chemically equilibrated coexisting authigenic alkali feldspars and re-equilibrated detrital feldspars in the 250–360°C temperature range. At c.335°C the average compositions, 2 Vs, and (t1o+t1m) and Z ordering parameters of coexisting authigenic feldspars are [Or0.52Ab97.40An2.08, 2Vx = 91.3±4.8, (t1o + t1m) = 0.89±0.05, Z = 0.79±0.09], and [Or94.42 Ab5.10An0.48, 2Vx = 70, (t1o + t1m) = 0.90, Z = 0.81]. At c.360°C authigenic albite becomes more An-rich and less ordered [Or1.21Ab92.83An5.97, 2Vx = 87.5±3.4, (t1o + t1m) = 0.85±0.03, Z = 0.70±0.07] and K-feldspar is no longer stable. Detrital plagioclase (An up to 40%) is preserved metastably to temperatures up to c.190°C in strongly carbonate-cemented sandstone which forms part of a geothermally produced permeability cap. It undergoes rapid alkali exchange at temperatures near 200°C, and by 250°C no plagioclase with An-content over 12% is observed. At > 250°C authigenic and most detrital alkali feldspar compositions are in excellent agreement with the Bachinski and Muller (1971) microcline-low-albite solvus.

Delineation of sandstone reservoirs of Pletmos Basin offshore South Africa into Flow Units using Core Data

2020 ◽  
Vol 123 (4) ◽  
pp. 479-492
Author(s):  
M. Opuwari ◽  
M. Amponsah-Dacosta ◽  
S. Mohammed ◽  
N. Egesi
Keyword(s):  
South Africa ◽  
Gamma Ray ◽  
Rock Type ◽  
Low Flow ◽  
Flow Zone ◽  
Fine Grained ◽  
Rock Types ◽  
Porosity And Permeability ◽  
Sandstone Reservoirs ◽  
Permeability Data

Abstract The present study is focused on the comparison of petrophysical rock typing and zonation methods of the Valanginian age sandstone in the Pletmos Basin offshore South Africa, to produce a zonation scheme for the low-permeability shaly sandstone reservoirs from core porosity and permeability data. The Valanginian age sediments of the Lower Cretaceous consist predominantly of a shallow marine sequence with interbeds of siltstone, claystone, generally fine-grained sandstone, and glauconitic, with varying amounts of an argillaceous matrix. A core description report was used in conjunction with a gamma-ray log to group rock types into different facies based on texture and grain size. Three different facies were identified as facies 1, a moderately sorted fine to medium-grained glauconitic sandstone; facies 2, a fine to very fine-grained glauconitic sandstone, moderately sorted; facies 3, a very fine sandstone to siltstone, laminated, argillaceous and bioturbated. Three independent reservoir zonation methods (Winland r35 pore throat, Hydraulic Flow Unit, and Stratigraphic Modified Lorenz Plot) were applied to three wells (SW1, SW2, and SW3) for which wireline logs, core porosity, and permeability data are available. Results were analyzed and compared with facies used as a context for the identification of rock types and zones. The results revealed eleven zones, grouped as moderate, very-low, and tight zones. The moderate flow zone is the best reservoir quality rock composed of macroporous rock type, ranked, as good rock type associated with facies 1. Three very-low flow zones were identified, which are of a microporous rock type, ranked as poor quality rock, associated with facies 2. Eight tight zones were revealed, which are of nanoporous rock type ranked as an impervious rock. The tight flow zone is the most reduced rock quality associated with facies 3. This study has developed a zonation scheme that will be used to locate other flow zones as well as to investigate whether the units/zones identified extend to other parts of the field.

scholarly journals Interpretation of zircon coronae textures from metapelitic granulites of the Ivrea–Verbano Zone, northern Italy: two-stage decomposition of Fe–Ti oxides

Solid Earth ◽  
2017 ◽  
Vol 8 (4) ◽  
pp. 789-804 ◽  
Author(s):  
Elizaveta Kovaleva ◽  
Håkon O. Austrheim ◽  
Urs S. Klötzli
Keyword(s):  
Host Rock ◽  
Granulite Facies ◽  
Northern Italy ◽  
Retrograde Metamorphism ◽  
Brittle Deformation ◽  
Granulite Facies Metamorphism ◽  
Fine Grained ◽  
Ti Oxides ◽  
Facies Metamorphism ◽  
Metapelitic Granulites

Abstract. In this study, we report the occurrence of zircon coronae textures in metapelitic granulites of the Ivrea–Verbano Zone. Unusual zircon textures are spatially associated with Fe–Ti oxides and occur as (1) vermicular-shaped aggregates 50–200 µm long and 5–20 µm thick and as (2) zircon coronae and fine-grained chains, hundreds of micrometers long and ≤ 1 µm thick, spatially associated with the larger zircon grains. Formation of such textures is a result of zircon precipitation during cooling after peak metamorphic conditions, which involved: (1) decomposition of Zr-rich ilmenite to Zr-bearing rutile, and formation of the vermicular-shaped zircon during retrograde metamorphism and hydration; and (2) recrystallization of Zr-bearing rutile to Zr-depleted rutile intergrown with quartz, and precipitation of the submicron-thick zircon coronae during further exhumation and cooling. We also observed hat-shaped grains that are composed of preexisting zircon overgrown by zircon coronae during stage (2). Formation of vermicular zircon (1) preceded ductile and brittle deformation of the host rock, as vermicular zircon is found both plastically and cataclastically deformed. Formation of thin zircon coronae (2) was coeval with, or immediately after, brittle deformation as coronae are found to fill fractures in the host rock. The latter is evidence of local, fluid-aided mobility of Zr. This study demonstrates that metamorphic zircon can nucleate and grow as a result of hydration reactions and mineral breakdown during cooling after granulite-facies metamorphism. Zircon coronae textures indicate metamorphic reactions in the host rock and establish the direction of the reaction front.

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