Surface Treatment in Solar Cell Technology
In the fabrication of solar cells of both the crystalline and thin film types, surface treatment has been found to play a decisive role. The electron microscope has been used in an attempt to isolate and to optimize those surface features which contribute beneficially towards increased cell performance. From our work thus far it is suspected that surface roughness plays a significant role in the efficiency of light-trapping so basic to this form of energy conversion device. We have observed that etchants used to prepare the semiconductor surfaces often attack these surfaces quite selectively, producing identifiable surfaces determined by the etchant used and the semiconductor so treated. For example, an etch of a cadmium sulfide vacuum evaporated film with hydrochloric acid, one part in three parts of distilled water produced an etch less harsh or rough as a similar dilution of phosphoric acid in the same time period.