scholarly journals Enhancement of Proton Conductivity in Nonporous Metal–Organic Frameworks: The Role of Framework Proton Density and Humidity

2018 ◽  
Vol 30 (21) ◽  
pp. 7593-7602 ◽  
Author(s):  
Simona Pili ◽  
Peter Rought ◽  
Daniil I. Kolokolov ◽  
Longfei Lin ◽  
Ivan da Silva ◽  
...  
Keyword(s):  
Proton Conductivity ◽  
Metal Organic Frameworks ◽  
Proton Density ◽  
Metal Organic

scholarly journals The role of lattice vibration in the terahertz region for proton conduction in 2D metal–organic frameworks

2020 ◽  
Vol 11 (6) ◽  
pp. 1538-1541
Author(s):  
Tomoya Itakura ◽  
Hiroshi Matsui ◽  
Tomofumi Tada ◽  
Susumu Kitagawa ◽  
Aude Demessence ◽  
...  
Keyword(s):  
Proton Conductivity ◽  
Electronic Structures ◽  
Lattice Vibration ◽  
Metal Organic Frameworks ◽  
Proton Conduction ◽  
Terahertz Region ◽  
Metal Organic

Terahertz-regime vibrations of 2D MOFs dominate the intrinsic proton conductivity, and the motions depend on the valence electronic structures.

scholarly journals High proton conductivity in cyanide-bridged metal–organic frameworks: understanding the role of water

2015 ◽  
Vol 3 (44) ◽  
pp. 22347-22352 ◽  
Author(s):  
Yuan Gao ◽  
Richard Broersen ◽  
Wouter Hageman ◽  
Ning Yan ◽  
Marjo C. Mittelmeijer-Hazeleger ◽  
...  
Keyword(s):  
Proton Conductivity ◽  
Metal Organic Frameworks ◽  
Water Molecules ◽  
High Proton Conductivity ◽  
Lattice Water ◽  
High Proton ◽  
Metal Organic

Hop hop hop: the proton conductivity of the [Nd(mpca)2Nd(H2O)6Mo(CN)8]·nH2O is enabled by lattice water molecules in its channels.

Classification and role of modulators on crystal engineering of metal organic frameworks (MOFs)

2021 ◽  
Vol 444 ◽  
pp. 214064
Author(s):  
Danni Jiang ◽  
Chao Huang ◽  
Jian Zhu ◽  
Ping Wang ◽  
Zhiming Liu ◽  
...  
Keyword(s):  
Crystal Engineering ◽  
Metal Organic Frameworks ◽  
Metal Organic

scholarly journals Porphyrin and phthalocyanine-based Metal Organic Frameworks beyond metal-carboxylates

2020 ◽  
Author(s):  
Siddhartha De ◽  
Thomas Devic ◽  
Alexandra Fateeva
Keyword(s):  
Porous Materials ◽  
Metal Organic Frameworks ◽  
Metal Carboxylates ◽  
Natural Systems ◽  
Metal Organic

Given the ubiquitous role of porphyrins in natural systems, these molecules and related derivatives such as phthalocyanines are fascinating building units to achieve functional porous materials. Porphyrin-based MOFs have been...

Metal-organic frameworks for electrochemical reduction of carbon dioxide: The role of metal centers

2020 ◽  
Vol 40 ◽  
pp. 156-170 ◽  
Author(s):  
Ping Shao ◽  
Luocai Yi ◽  
Shumei Chen ◽  
Tianhua Zhou ◽  
Jian Zhang
Keyword(s):  
Carbon Dioxide ◽  
Electrochemical Reduction ◽  
Metal Organic Frameworks ◽  
Metal Centers ◽  
Metal Organic

Role of a 3D Structure in Energy Transfer in Mixed-Ligand Metal–Organic Frameworks

2021 ◽  
Author(s):  
Shaunak M. Shaikh ◽  
Stefan Ilic ◽  
Bradley J. Gibbons ◽  
Xiaozhou Yang ◽  
Elena Jakubikova ◽  
...  
Keyword(s):  
Energy Transfer ◽  
Metal Organic Frameworks ◽  
3D Structure ◽  
Mixed Ligand ◽  
Metal Organic

Surviving Under Pressure: The Role of Solvent, Crystal Size, and Morphology During Pelletization of Metal–Organic Frameworks

2021 ◽  
Author(s):  
Timothy C. Wang ◽  
Ashley M. Wright ◽  
William J. Hoover ◽  
Kevin J. Stoffel ◽  
Rachelle K. Richardson ◽  
...  
Keyword(s):  
Crystal Size ◽  
Metal Organic Frameworks ◽  
Metal Organic ◽  
Size And Morphology ◽  
Role Of Solvent

Metal–organic frameworks derived from a semi-rigid anthracene-based ligand and sulfonates: proton conductivity and dye degradation studies

CrystEngComm ◽  
2021 ◽  
Author(s):  
Aurobinda Mohanty ◽  
Udai P. Singh ◽  
Arijit Ghorai ◽  
Susanta Banerjee ◽  
R. J. Butcher
Keyword(s):  
Methylene Blue ◽  
Relative Humidity ◽  
Proton Conductivity ◽  
Dye Degradation ◽  
Metal Organic Frameworks ◽  
High Proton Conductivity ◽  
Methylene Blue Degradation ◽  
High Proton ◽  
Metal Organic ◽  
Degradation Studies

The MOFs were constructed by ligand AHP and sulfonate analogues. MOF4 exhibits a high proton conductivity of 1.95 × 10−3 S cm−1 at 95 °C and 98% relative humidity. MOFs 1–5 also serve as photocatalysts for methylene blue degradation.

Critical role of water stability in metal–organic frameworks and advanced modification strategies for the extension of their applicability

2020 ◽  
Vol 7 (5) ◽  
pp. 1319-1347 ◽  
Author(s):  
Botao Liu ◽  
Kumar Vikrant ◽  
Ki-Hyun Kim ◽  
Vanish Kumar ◽  
Suresh Kumar Kailasa
Keyword(s):  
Drug Delivery ◽  
Water Purification ◽  
Gas Adsorption ◽  
Critical Role ◽  
Metal Organic Frameworks ◽  
Water Stability ◽  
Metal Organic

Metal–organic frameworks (MOFs) are well known for their versatile applications in diverse fields (e.g., gas adsorption, water purification, sensing, drug delivery, and catalysis).

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