Surviving Under Pressure: The Role of Solvent, Crystal Size, and Morphology During Pelletization of Metal–Organic Frameworks

2021 ◽  
Author(s):  
Timothy C. Wang ◽  
Ashley M. Wright ◽  
William J. Hoover ◽  
Kevin J. Stoffel ◽  
Rachelle K. Richardson ◽  
...  
Keyword(s):  
Crystal Size ◽  
Metal Organic Frameworks ◽  
Metal Organic ◽  
Size And Morphology ◽  
Role Of Solvent

scholarly journals Electrochemical Aptasensors Based on Hybrid Metal-Organic Frameworks

Sensors ◽  
2020 ◽  
Vol 20 (23) ◽  
pp. 6963
Author(s):  
Gennady Evtugyn ◽  
Svetlana Belyakova ◽  
Anna Porfireva ◽  
Tibor Hianik
Keyword(s):  
Electrochemical Sensors ◽  
Metal Organic Frameworks ◽  
High Porosity ◽  
Future Trends ◽  
Literature Information ◽  
Variable Size ◽  
Metal Organic ◽  
Signal Mode ◽  
Size And Morphology

Metal-organic frameworks (MOFs) offer a unique variety of properties and morphology of the structure that make it possible to extend the performance of existing and design new electrochemical biosensors. High porosity, variable size and morphology, compatibility with common components of electrochemical sensors, and easy combination with bioreceptors make MOFs very attractive for application in the assembly of electrochemical aptasensors. In this review, the progress in the synthesis and application of the MOFs in electrochemical aptasensors are considered with an emphasis on the role of the MOF materials in aptamer immobilization and signal generation. The literature information of the use of MOFs in electrochemical aptasensors is classified in accordance with the nature and role of MOFs and a signal mode. In conclusion, future trends in the application of MOFs in electrochemical aptasensors are briefly discussed.

From Micro to Nano: A Toolbox for Tuning Crystal Size and Morphology of Benzotriazolate-Based Metal–Organic Frameworks

2016 ◽  
Vol 16 (6) ◽  
pp. 3190-3197 ◽  
Author(s):  
Hana Bunzen ◽  
Maciej Grzywa ◽  
Manuel Hambach ◽  
Sebastian Spirkl ◽  
Dirk Volkmer
Keyword(s):  
Crystal Size ◽  
Metal Organic Frameworks ◽  
Metal Organic ◽  
Size And Morphology

scholarly journals Modelling drug adsorption in metal–organic frameworks: the role of solvent

RSC Advances ◽  
2021 ◽  
Vol 11 (28) ◽  
pp. 17064-17071
Author(s):  
Abhishek T. Sose ◽  
Hannah D. Cornell ◽  
Bradley J. Gibbons ◽  
Ashley A. Burris ◽  
Amanda J. Morris ◽  
...  
Keyword(s):  
Drug Loading ◽  
Metal Organic Frameworks ◽  
Drug Adsorption ◽  
Metal Organic ◽  
Role Of Solvent

Solvent plays a key role in drug loading in metal–organic frameworks.

scholarly journals Using Supercritical CO2 in the Preparation of Metal-Organic Frameworks: Investigating Effects on Crystallisation

Crystals ◽  
2019 ◽  
Vol 10 (1) ◽  
pp. 17 ◽  
Author(s):  
Huan Doan ◽  
Fei Cheng ◽  
Thandeka Dyirakumunda ◽  
Mark Elsegood ◽  
Jiamin Chin ◽  
...  
Keyword(s):  
Low Temperatures ◽  
Supercritical Co2 ◽  
Crystal Size ◽  
Solvothermal Method ◽  
Metal Organic Frameworks ◽  
Product Yields ◽  
Metal Organic ◽  
Size And Morphology

In this report, we explore the use of supercritical CO2 (scCO2) in the synthesis of well-known metal-organic frameworks (MOFs) including Zn-MOF-74 and UiO-66, as well as on the preparation of [Cu24(OH-mBDC)24]n metal-organic polyhedra (MOPs) and two new MOF structures {[Zn2(L1)(DPE)]∙4H2O}n and {[Zn3(L1)3(4,4′-azopy)]∙7.5H2O}n, where BTC = benzene-1,3,5-tricarboxylate, BDC = benzene-1,4-dicarboxylate, L1 = 4-carboxy-phenylene-methyleneamino-4-benzoate, DPE = 1,2-di(4-pyridyl)ethylene, 4.4′-azopy = 4,4′- azopyridine, and compare the results versus traditional solvothermal preparations at low temperatures (i.e., 40 °C). The objective of the work was to see if the same or different products would result from the scCO2 route versus the solvothermal method. We were interested to see which method produced the highest yield, the cleanest product and what types of morphology resulted. While there was no evidence of additional meso- or macroporosity in these MOFs/MOPs nor any significant improvements in product yields through the addition of scCO2 to these systems, it was shown that the use of scCO2 can have an effect on crystallinity, crystal size and morphology.

Classification and role of modulators on crystal engineering of metal organic frameworks (MOFs)

2021 ◽  
Vol 444 ◽  
pp. 214064
Author(s):  
Danni Jiang ◽  
Chao Huang ◽  
Jian Zhu ◽  
Ping Wang ◽  
Zhiming Liu ◽  
...  
Keyword(s):  
Crystal Engineering ◽  
Metal Organic Frameworks ◽  
Metal Organic

scholarly journals Porphyrin and phthalocyanine-based Metal Organic Frameworks beyond metal-carboxylates

2020 ◽  
Author(s):  
Siddhartha De ◽  
Thomas Devic ◽  
Alexandra Fateeva
Keyword(s):  
Porous Materials ◽  
Metal Organic Frameworks ◽  
Metal Carboxylates ◽  
Natural Systems ◽  
Metal Organic

Given the ubiquitous role of porphyrins in natural systems, these molecules and related derivatives such as phthalocyanines are fascinating building units to achieve functional porous materials. Porphyrin-based MOFs have been...

Metal-organic frameworks for electrochemical reduction of carbon dioxide: The role of metal centers

2020 ◽  
Vol 40 ◽  
pp. 156-170 ◽  
Author(s):  
Ping Shao ◽  
Luocai Yi ◽  
Shumei Chen ◽  
Tianhua Zhou ◽  
Jian Zhang
Keyword(s):  
Carbon Dioxide ◽  
Electrochemical Reduction ◽  
Metal Organic Frameworks ◽  
Metal Centers ◽  
Metal Organic

Role of a 3D Structure in Energy Transfer in Mixed-Ligand Metal–Organic Frameworks

2021 ◽  
Author(s):  
Shaunak M. Shaikh ◽  
Stefan Ilic ◽  
Bradley J. Gibbons ◽  
Xiaozhou Yang ◽  
Elena Jakubikova ◽  
...  
Keyword(s):  
Energy Transfer ◽  
Metal Organic Frameworks ◽  
3D Structure ◽  
Mixed Ligand ◽  
Metal Organic

Critical role of water stability in metal–organic frameworks and advanced modification strategies for the extension of their applicability

2020 ◽  
Vol 7 (5) ◽  
pp. 1319-1347 ◽  
Author(s):  
Botao Liu ◽  
Kumar Vikrant ◽  
Ki-Hyun Kim ◽  
Vanish Kumar ◽  
Suresh Kumar Kailasa
Keyword(s):  
Drug Delivery ◽  
Water Purification ◽  
Gas Adsorption ◽  
Critical Role ◽  
Metal Organic Frameworks ◽  
Water Stability ◽  
Metal Organic

Metal–organic frameworks (MOFs) are well known for their versatile applications in diverse fields (e.g., gas adsorption, water purification, sensing, drug delivery, and catalysis).

scholarly journals The role of molecular modelling and simulation in the discovery and deployment of metal-organic frameworks for gas storage and separation

2019 ◽  
Vol 45 (14-15) ◽  
pp. 1082-1121 ◽  
Author(s):  
Arni Sturluson ◽  
Melanie T. Huynh ◽  
Alec R. Kaija ◽  
Caleb Laird ◽  
Sunghyun Yoon ◽  
...  
Keyword(s):  
Molecular Modelling ◽  
Metal Organic Frameworks ◽  
Gas Storage ◽  
Modelling And Simulation ◽  
Metal Organic
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