Effect of Transition Metal Polymers with Varying Side Alkyl Chain on Viscosity Reduction of Crude Oil and Aggregation Behavior of Asphaltene

2015 ◽  
Vol 29 (12) ◽  
pp. 7771-7780 ◽  
Author(s):  
Jing-jing Li ◽  
Xuan Wang ◽  
Xiao-dong Tang ◽  
Fang Wang ◽  
Da-yong Qing
Energies ◽  
2021 ◽  
Vol 14 (15) ◽  
pp. 4703
Author(s):  
Qiang Deng ◽  
Michal Slaný ◽  
Huani Zhang ◽  
Xuefan Gu ◽  
Yong-Fei Li ◽  
...  

In this paper, alkyl aliphatic hydrazine, which is different from traditional polymer fluidity improver, was synthesized from aliphatic hydrazine and cetane bromide, and evaluated as a pour point and viscosity-reducer depressant for crude oil. The evaluation results showed that alkyl aliphatic hydrazone fully reduced the pour point and viscosity of crude oil with the increase of crude oil fluidity. The viscosity reduction rate of crude oil in Jinghe oilfield was 79.6%, and the pour point was reduced by about 11.3 °C. The viscosity reduction rate of crude oil in Xinjiang Oilfield was 74.7%, and the pour point was reduced by 8.0 °C. The long alkyl chain is beneficial to the eutectic of wax in crude oil, and the polar group inhibits the crystal growth, resulting in the decrease of pour point and viscosity. The waste oil is fully recycled into oilfield chemicals.


Fuel ◽  
2010 ◽  
Vol 89 (5) ◽  
pp. 1095-1100 ◽  
Author(s):  
Shadi W. Hasan ◽  
Mamdouh T. Ghannam ◽  
Nabil Esmail

2021 ◽  
Author(s):  
Ademola Balogun ◽  
Toyin Odutola ◽  
Yakubu Balogun

Abstract This research examines the use of 75nm Zinc Oxide nanoparticles (Nano ZnO) and Polyethylene Butene (PEB) in reducing the viscosity of Nigerian waxy crude oil. The rheology of the crude oil was studied by measuring the viscosity and shear stress of crude samples contaminated with varying concentration of PEB (500ppm, 1000ppm, 2000ppm, 3000ppm, 4000ppm and 5000ppm), varying concentrations of Nano ZnO (1wt%, 2wt%, 3wt% and 4wt%) and different blends of PEB and Nano ZnO at temperatures of between 10°C to 35°C and shear rates from 1.7 to 1020s-1. From Rheological Modelling analysis conducted, the Power law pseudoplastic model was the best fit for the experimental data with a regression coefficient of 0.99. Analysis of crude sample before addition of inhibitor showed evidence of non-Newtonian fluid behaviour as the shear stress-shear rate relationship curves were nonlinear due to wax precipitation at low temperatures (10°C to 15°C). The waxy crude demonstrated shear thinning behaviour with increasing shear rates (increasing turbulence) and the viscosity reduced with increasing temperature. The addition of inhibitors (PEB, Nano ZnO and their blends) effected Newtonian fluid behaviour in the crude samples as the shear stress-shear rate relationship curves were linear at all temperatures under study. The optimum concentration of the inhibitors in this study is 2000ppm PEB (causing 33% viscosity reduction) and 1wt% Nano ZnO (effecting 26% viscosity reduction). The best concentration of the blend was 2000ppm PEB blended with 1wt% Nano ZnO which effected a viscosity reduction of 41%. The research demonstrates the novel application of the blend of Nano ZnO and PEB in improving flowability of Nigerian waxy crude oil especially in offshore conditions with prevailing cold temperatures.


2017 ◽  
Vol 89 (3) ◽  
pp. 379-392 ◽  
Author(s):  
Maxim N. Sokolov ◽  
Alexander V. Anyushin ◽  
Rita Hernandez-Molina ◽  
Rosa Llusar ◽  
Manuel G. Basallote

AbstractThis contribution is a documentation of recent advances in the chemistry of chalcogenide polynuclear transition metal complexes coordinated with mono- and di-phosphines functionalized with hydroxo groups. A survey of complexes containing tris(hydroxymethyl)phosphine (THP) is presented. The influence of the alkyl chain in bidentate phosphines, bearing the P–(CH2)x–OH arms, is also analyzed. Finally, isolation and structure elucidation of the complexes with HP(OH)2, P(OH)3, As(OH)3, PhP(OH)2, stabilized by coordination to Ni(0) and Pd(0) centers embedded into chalcogenide clusters, is discussed.


2011 ◽  
Vol 239-242 ◽  
pp. 2650-2654
Author(s):  
Fu Chen ◽  
Jie He ◽  
Ping Guo ◽  
Yuan Xu ◽  
Cheng Zhong

According to the mechanisms of carbon dioxide miscible flooding and previous researchers’ work on synthesis of CO2-soluble surfactant, Citric acid isoamyl ester was synthesized, and it’s oil solubility and the rate of viscosity reduction both in oil-water system and oil were evaluated. And then we found that this compound can solve in oil effectively; the optimum mass of Citric acid isoamyl ester introduced in oil-water system is 0.12g when the mass ratio of oil and water is 7:3 (crude oil 23.4g, formation water 10g) and the experimental temperature is 50°C , the rate of viscosity reduction is 47.2%; during the evaluation of the ability of Citric acid isoamyl ester to decrease oil viscosity, we found that the optimum dosage of this compound in 20g crude oil is 0.2g when the temperature is 40°C, and the rate of viscosity reduction is 7.37% at this point.


Author(s):  
Hao Wang ◽  
Junhua Chen ◽  
Yang Zheng ◽  
Daniel A. Obenchain ◽  
Xuefang Xu ◽  
...  

RSC Advances ◽  
2019 ◽  
Vol 9 (65) ◽  
pp. 38257-38264 ◽  
Author(s):  
Shuai Li ◽  
Tengfei Miao ◽  
Xiaoxiao Cheng ◽  
Yin Zhao ◽  
Wei Zhang ◽  
...  

The chiral solvation induced chirality in achiral polyfluorenes showed the axial chirality for PF2/6 with branched side alkyl chain, but supramolecular chirality for PF8 with linear side alkyl chain.


Fuel ◽  
2020 ◽  
Vol 263 ◽  
pp. 116638 ◽  
Author(s):  
Jingjing Cui ◽  
Zhihong Zhang ◽  
Xuedong Liu ◽  
Lin Liu ◽  
Jian Peng

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