Prediction of Flue Gas Composition and Comparative Overall Process Evaluation for Air and Oxyfuel Combustion of Estonian Oil Shale, Using Aspen Plus Process Simulation

2016 ◽  
Vol 30 (7) ◽  
pp. 5893-5900 ◽  
Author(s):  
Can R. Yörük ◽  
Andres Trikkel ◽  
Rein Kuusik
Oil Shale ◽  
2013 ◽  
Vol 30 (1) ◽  
pp. 6 ◽  
Author(s):  
A KONIST ◽  
T PIHU ◽  
D NESHUMAYEV ◽  
A SIIRDE

2021 ◽  
Vol 9 (1) ◽  
pp. 26-38
Author(s):  
Odeh A.O ◽  
Okpaire L.A ◽  
Oyedoh E.A

Oxy-fuel Combustion is a technology with the potential of drastically reducing the amount of CO2 emission, it relies on the use of oxygen and recycled CO2 instead of air as the oxidant. This helps to reduce the amount of the CO2 and NOx emissions. This study focuses on the components of flue gas produced and their amounts for oxy-fuel combustion in a coal-fired power plant (CFPP) and also the boiler efficiency using the direct (input-output) method. The combustion process of pulverized coal in a 120MW power plant is studied using Aspen Plus 11. The amount of each component in flue gas in coal-fired processes with air or O2/ CO2 (using recycle of 20%, 40%, 60% and 80% of CO2) as oxidizer was obtained. From the process simulation, as the recycle % of CO2 was increased, the flame temperature, CO and NOx emissions were reduced. The simulation results of air combustion were compared with that of oxy-fuel combustion with 80% recycle and it was seen that the flame temperature dropped from 1894oC when air was used as oxidizer to 1679oC for oxy-fuel combustion with 80% recycle. Also, there was a reduction in the amount of NOx produced, but the SOx levels were constant for both combustion processes. The Gross Calorific Value (GCV) of the coal was calculated from its Proximate Analysis using Dulong’s formula and it was used to estimate the Boiler Efficiency using the Direct (Input-Output) method and a value of 83.6% was obtained.


2012 ◽  
Vol 33 (2) ◽  
pp. 255-262 ◽  
Author(s):  
Angelika Kochel ◽  
Aleksandra Cieplińska ◽  
Arkadiusz Szymanek

Limestone in flue gas desulphurization in oxygen-enriched atmospheres - Part I: The effect of CO2 on limestone calcination The article describes the testing of four selected samples of limestone originating from four commercially exploited deposits. The tests of sorbents included a physicochemical analysis and calcination in different atmospheres. The main aim of the tests was to determine the possibilities for using limestone during combustion in oxygen-enriched atmospheres. Tests in a synthetic flue gas composition make it possible to assess the possibility of CaCO3 decomposition in atmospheres with an increased CO2 concentration.


2020 ◽  
Vol 6 ◽  
pp. 36-45 ◽  
Author(s):  
Lizica Simona Paraschiv ◽  
Alexandru Serban ◽  
Spiru Paraschiv

Energy ◽  
2015 ◽  
Vol 90 ◽  
pp. 1869-1877 ◽  
Author(s):  
William X. Meng ◽  
Subhodeep Banerjee ◽  
Xiao Zhang ◽  
Ramesh K. Agarwal

2019 ◽  
Vol 142 (6) ◽  
Author(s):  
Md. Moheiminul I. Khan ◽  
Mehrin Chowdhury ◽  
A. S. M. Arifur Rahman Chowdhury ◽  
Jad Aboud ◽  
Norman Love

Abstract This paper presents the results of thermal efficiency of two coal based oxy-combustion thermodynamic cycles that are modeled using aspen plus. The objective of the present study is to perform a parametric analysis, investigating the effect of different recirculation ratios at different pressures on the efficiencies of the cycle named for the company, ENEL, and the thermo energy power system, TIPS, cycles using aspen plus® software. Variables include the flue gas recycle flow rate, the combustor temperature, and the operational pressure. Five recirculation ratios were investigated, ranging from 20% to 75%. It was determined that as the amount of recycled gas into the combustor increased, the thermal efficiency increased for both the TIPS and ENEL cycles. The highest thermal efficiency for TIPS is 37% and for ENEL is 38%, both occurring at a 75% recirculation ratio. After investigation, since combustion temperature and specific heat capacity decreases at higher recirculation ratios, the mass flow rate was the dominant factor that contributes to the increase in thermal efficiency of the cycle. At each recirculation ratio, the effect of pressure is also determined. For ENEL, the increase in cycle efficiency is 10% over the pressure range of 1–12 bar at a recirculation ratio of 20%, while the increase in cycle efficiency is only 1.5% at a higher recirculation ratio of 75%. For TIPS, the cycle efficiency increases by 4% at the recirculation ratio of 20% and increases by 3% at the recirculation ratio of 75% for a pressure range of 50–80 bar.


Energies ◽  
2018 ◽  
Vol 11 (11) ◽  
pp. 3195 ◽  
Author(s):  
Kathleen Dupre ◽  
Emily Ryan ◽  
Azat Suleimenov ◽  
Jillian Goldfarb

The volatility of crude oil prices incentivizes the use of domestic alternative fossil fuel sources such as oil shale. For ex situ oil shale retorting to be economically and environmentally viable, we must convert the copious amounts of semi-coke waste to an environmentally benign, useable by-product. Using acid and acid + base treatments, we increased the surface area of the semi-coke samples from 15 m2/g (pyrolyzed semi-coke) to upwards of 150 m2/g for hydrochloric acid washed semi-coke. This enhancement in porosity and surface area is accomplished without high temperature treatment, which lowers the overall energy required for such a conversion. XRD analysis confirms that chemical treatments removed the majority of dolomite while retaining other carbonate minerals and maintaining carbon contents of approximately 10%, which is greater than many fly ashes that are commonly used as sorbent materials. SO2 gas adsorption isotherm analysis determined that a double HCl treatment of semi-coke produces sorbents for flue gas treatment with higher SO2 capacities than commonly used fly ash adsorbents. Computational fluid dynamics modeling indicates that the sorbent material could be used in a fixed bed reactor to efficiently remove SO2 from the gas stream.


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