Effect of Fabrication and Operation Conditions on CO2 Separation Performance of PEO–PA Block Copolymer Membranes

2015 ◽  
Vol 54 (29) ◽  
pp. 7273-7283 ◽  
Author(s):  
Yuanyuan Wang ◽  
Hongyu Li ◽  
Guangxi Dong ◽  
Colin Scholes ◽  
Vicki Chen
Keyword(s):  
Block Copolymer ◽  
Co2 Separation ◽  
Separation Performance ◽  
Operation Conditions

Block copolymer membranes based on polyetheramine and methyl-containing polyisophthalamides designed for efficient CO2 separation

2017 ◽  
Vol 30 (9) ◽  
pp. 1064-1074 ◽  
Author(s):  
Xin Fu ◽  
Xueqin Li ◽  
Ruili Guo ◽  
Jianshu Zhang ◽  
Xingzhong Cao
Keyword(s):  
Carbon Dioxide ◽  
Block Copolymer ◽  
Ethylene Oxide ◽  
Free Volume ◽  
Gas Mixtures ◽  
Co2 Separation ◽  
Separation Performance ◽  
Mass Ratio ◽  
Fractional Free Volume ◽  
Diphenyl Sulfone

A series of block copolymer membranes was designed using polyetheramine (PEA) and methyl-containing polyisophthalamides (MPA) for the separation of carbon dioxide (CO2)/methane (CH4) gas mixtures. PEA consists of abundant ethylene oxide units, which show good affinity with CO2, and MPA consists of methyl (Me) substituents, which can increase the fractional free volume of block copolymer membranes. The Me substituents were introduced into MPA via polymerization from isophthaloyl dichloride (IPC), 2,5-dimethyl-1,4-phenylenediamine (DPD), and 4,4′-bis(3-aminophenoxy)diphenyl sulfone (BADS). Therefore, the CO2 solubility and diffusivity in the membranes could be improved by tailoring the PEA/MPA mass ratio and BADS/DPD mole ratio, respectively. The membrane with a PEA/MPA mass ratio of 6/4 and a BADS/DPD mole ratio of 1/10 exhibited optimum CO2 separation performance with a CO2 permeability of 629 Barrer and CO2/CH4 selectivity of 23 at 2 × 105 Pa and 25°C.

scholarly journals Protein separation performance of self-assembled block copolymer membranes

RSC Advances ◽  
2014 ◽  
Vol 4 (20) ◽  
pp. 10252 ◽  
Author(s):  
J. Hahn ◽  
J. I. Clodt ◽  
V. Filiz ◽  
V. Abetz
Keyword(s):  
Block Copolymer ◽  
Protein Separation ◽  
Separation Performance ◽  
Self Assembled

In situ synthesis of polymer grafted ZIFs and application in mixed matrix membrane for CO2 separation

2018 ◽  
Vol 6 (7) ◽  
pp. 3151-3161 ◽  
Author(s):  
Yongqiang Gao ◽  
Zhihua Qiao ◽  
Song Zhao ◽  
Zhi Wang ◽  
Jixiao Wang
Keyword(s):  
Polymer Matrix ◽  
In Situ Synthesis ◽  
Mixed Matrix Membrane ◽  
Co2 Separation ◽  
Separation Performance ◽  
Mixed Matrix ◽  
Interfacial Compatibility ◽  
Gas Separation Performance ◽  
Functionalized Surface

PEI-g-ZIF-8 presents appropriate porous structure, amino functionalized surface and improved interfacial compatibility with the polymer matrix to endow the MMMs with excellent gas separation performance.

Effect of branched and cycloalkyl functionalities on CO2 separation performance of poly(IL) membranes

2015 ◽  
Vol 155 ◽  
pp. 89-95 ◽  
Author(s):  
W. Jeffrey Horne ◽  
Mary A. Andrews ◽  
Matthew S. Shannon ◽  
Kelsey L. Terrill ◽  
Joshua D. Moon ◽  
...  
Keyword(s):  
Co2 Separation ◽  
Separation Performance

scholarly journals The effect of Poly(Ethylene oxide) cross-linking structure on the mechanical properties and CO2 separation performance of an ion gel membrane

Polymer ◽  
2019 ◽  
Vol 180 ◽  
pp. 121666 ◽  
Author(s):  
Victor A. Kusuma ◽  
Christina Chen ◽  
James S. Baker ◽  
Megan K. Macala ◽  
David Hopkinson
Keyword(s):  
Mechanical Properties ◽  
Ethylene Oxide ◽  
Cross Linking ◽  
Co2 Separation ◽  
Separation Performance ◽  
Poly Ethylene Oxide ◽  
Ion Gel ◽  
Poly Ethylene
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