scholarly journals Synthesis of a Biodegradable PLA: NMR Signal Deconvolution and End-Group Analysis

Author(s):  
Juana M. Pérez ◽  
Cristina Ruiz ◽  
Ignacio Fernández
1951 ◽  
Vol 190 (2) ◽  
pp. 733-740 ◽  
Author(s):  
Sidney. Udenfriend ◽  
Sidney F. Velick

1965 ◽  
Vol 48 (7) ◽  
pp. 884-887 ◽  
Author(s):  
E.B. Kalan ◽  
M.P. Thompson ◽  
Rae Greenberg ◽  
L. Pepper

2016 ◽  
Vol 13 (2) ◽  
pp. 221-234
Author(s):  
Baghdad Science Journal

Different polymers were prepared by condensation polymerization of sebacic anhydride and adipic anhydride with ethylene glycol and poly(ethylene glycol). Their number average molecular weights were determined by end group analysis. Then, they were grafted on the prepared phthalocyaninatocopper(II) compounds with the general formula (NH2)4PcCu(II) having amino groups of 3,3',3'',3'''- or 4,4',4'',4'''- positions. All prepared polymers, compounds, and phthalocyaninatocopper(II)-grafted polymers were characterized by FTIR. The sizing measurements were carried out in 3,3',3'',3'''- (NH2)4PcCu(II) and 4,4',4'',4'''- (NH2)4PcCu(II) compounds with and without grafting polymers. The results showed that the grafting process led to decreasing in particle size and increasing in surface area. The grafting process was reflected positively on the thermal degradation of 3,3',3'',3'''- (NH2)4PcCu(II) and 4,4',4'',4'''- (NH2)4PcCu(II) grafted polymers. They had higher thermal stability accompanied with higher char residue and T50% weight loss with 3,3',3'',3'''-(NH2)4PcCu(II) and their grafted polymers being the best.


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