Solution Chemistry to Control Boron-Containing Monolayers on Silicon: Reactions of Boric Acid and 4-Fluorophenylboronic Acid with H- and Cl-terminated Si(100)

Langmuir ◽  
2021 ◽  
Author(s):  
Dhamelyz Silva-Quinones ◽  
Robert E. Butera ◽  
George T. Wang ◽  
Andrew V. Teplyakov
Keyword(s):  
Boric Acid ◽  
Solution Chemistry

Thermodynamic modeling of boric acid and selected metal borate systems

2013 ◽  
Vol 85 (11) ◽  
pp. 2117-2144 ◽  
Author(s):  
Peiming Wang ◽  
Jerzy J. Kosinski ◽  
Malgorzata M. Lencka ◽  
Andrzej Anderko ◽  
Ronald D. Springer
Keyword(s):  
Boric Acid ◽  
Natural Waters ◽  
Chemical Speciation ◽  
Mixed Solvent ◽  
Water System ◽  
Solution Chemistry ◽  
Chloride Salt ◽  
Liquid Equilibrium ◽  
Metal Borate ◽  
Borate Systems

A comprehensive thermodynamic model, referred to as the mixed-solvent electrolyte (MSE) model, has been applied to calculate phase equilibria, speciation, and other thermodynamic properties of selected systems that are of interest for understanding the chemistry of salt lakes and natural waters. In particular, solubilities and chemical speciation have been analyzed for various boron-containing systems, which represent an important subset of solution chemistry for such applications. The model has been shown to reproduce the speciation, solubility, and vapor–liquid equilibrium (VLE) data in the boric acid + water system over wide ranges of temperature and concentration. Specifically, solubilities have been accurately represented in the full concentration range of the B2O3 + H2O system (xB2O3 = 0~1), which includes H3BO3. The accuracy of the model has also been demonstrated by calculating solubilities in various aqueous borate systems, i.e., MnO + B2O3 + H2O (where M = Li, Na, Ca, Mg), and their mixtures with a chloride salt or an acid (i.e., LiCl, NaCl, HCl). The model predicts the effects of chemical speciation, temperature, and concentrations of various acid, base, and salt components on the formation of competing solid phases.

Boric Acid

1889 ◽  
Vol 27 (690supp) ◽  
pp. 11021-11021
Keyword(s):  
Boric Acid

PENGAWETAN ROTAN KURANG DIKENAL SEBAGAI BAHAN BAKU MEBEL MENGGUNAKAN RENDAMAN DINGIN

2012 ◽  
Vol 4 (2) ◽  
pp. 11
Author(s):  
Saibatul Hamdi
Keyword(s):  
Boric Acid ◽  
Central Kalimantan

This research used the lesser known species as much 5 types rattan, consisted of i.e marau (Calamus Mettanensis Becc), toho (Calamus Spp), galang (Daemonorops Verticilaris Griff Mart), hijau (Calamus Spp) and simpurut (Calamus Panajuga Becc) from Central Kalimantan. Preservative used the mixture of boric acid with the borax and copper-8 by  the concentration of 1,0 %, 2,0 % and 3,0 %. Soaked time during 2 day, 4 day and 6 day by immersion chilled. Result of research indicated that the retention value varied, the greater of concentration condensation and soaking period, the greater average the value of retention while penetration result at all of treatment showed the value 100 %.Keywords:  rattan, preservation, retention, penetration, cold soaking.

Solution chemistry effects on the solvation shell of metal ions

2020 ◽  
Author(s):  
Xiangwen Wang ◽  
Dimitrios Toroz ◽  
Seonmyeong Kim ◽  
Simon Clegg ◽  
Gun-Sik Park ◽  
...  
Keyword(s):  
Metal Ions ◽  
Pure Water ◽  
Solvation Shell ◽  
Solution Chemistry ◽  
Chemical Characteristics ◽  
Velocity Autocorrelation Function ◽  
Ionic Solvation ◽  
General Terms ◽  
Alkaline Earth Metal Ions ◽  
Wide Range

<div> <p>As natural aqueous solutions are far from being pure water, being rich in ions, the properties of solvated ions are of relevance for a wide range of systems, including biological and geochemical environments. We conducted ab initio and classical MD simulations of the alkaline earth metal ions Mg<sup>2+</sup> and Ca<sup>2+</sup> and of the alkali metal ions Li<sup>+</sup>, Na<sup>+</sup>, K<sup>+</sup> and Cs<sup>+</sup> in pure water and electrolyte solutions containing the counterions Cl<sup>–</sup> and SO<sub>4</sub><sup>2–</sup>. Through a detailed analysis of these simulations, this study reports on the effect of solution chemistry (composition and concentration of the solution) to the ion–water structural properties and interaction strength, and to the dynamics, hydrogen bond network, and low-frequency dynamics of the ionic solvation shell. Except for the ion–water radial distribution function, which is weakly dependent on the counter-ions and concentrations, we found that all other properties can be significantly influenced by the chemical characteristics of the solution. Calculation of the velocity autocorrelation function of magnesium ions, for example, shows that chlorine ions located in the second coordination shell of Mg<sup>2+</sup> weaken the Mg(H<sub>2</sub>O)<sub>6</sub><sup>2+</sup> hydration ‘cage’ of the cation. The result reported in this study suggest that ionic solvation shell can be significantly influenced by the interactions between other ions present in solution ions, especially those of opposite charge. In more general terms, the chemical characteristics of the solution, including the balance between ion-solvent and ion-ion interactions, could result in significant differences in behavior and function of the ionic solvation shell.</p> </div>

Arylboronic Acids in Self-condensation of Glucosamines Forming Deoxyfructosazine, Catalysts or Reagents?

2019 ◽  
Author(s):  
Meifeng Wang ◽  
Gan Zhu ◽  
Yiqun Li ◽  
Liuqun Gu
Keyword(s):  
Molecular Recognition ◽  
Boric Acid ◽  
Boronic Acid ◽  
Catalytic Mechanism ◽  
Organic Transformations ◽  
Food Industries ◽  
Arylboronic Acids ◽  
Excess Amount ◽  
Phenyl Boronic Acid ◽  
Boron Acid

Arylboronic acids were widely used as efficient catalysts in direct amide formation and other organic transformations. Surprisingly, reports on their use as catalysts in carbohydrates synthesis are very rare even though boron acid-diol complexation was extensively investigated in molecular recognition for saccharides and so on. Here we developed an efficient arylboronic acids catalyzed dimerization of glucosamines forming deoxyfructosazine which is important compound in pharmaceutical and food industries, against a commonly held belief that excess amount of phenyl boronic acid (or boric acid) is a must. A catalytic mechanism was also proposed and arylboronic acids instead of their boronates was identified as catalysts.

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