Field-Dependent Band Structure Measurements in Two-Dimensional Heterostructures

Nano Letters ◽  
2021 ◽  
Author(s):  
Paul V. Nguyen ◽  
Natalie C. Teutsch ◽  
Nathan P. Wilson ◽  
Joshua Kahn ◽  
Xue Xia ◽  
...  
1998 ◽  
Vol 58 (16) ◽  
pp. 10709-10720 ◽  
Author(s):  
D. Merbach ◽  
E. Schöll ◽  
W. Ebeling ◽  
P. Michler ◽  
J. Gutowski

2020 ◽  
Author(s):  
Thaksen Jadhav ◽  
Yuan Fang ◽  
Cheng-Hao Liu ◽  
Afshin Dadvand ◽  
Ehsan Hamzehpoor ◽  
...  

We report the first transformation between crystalline vinylene-linked two-dimensional (2D) polymers and crystalline cyclobutane-linked three-dimensional (3D) polymers. Specifically, absorption-edge irradiation of the 2D poly(arylenevinylene) covalent organic frameworks (COFs) results in topological [2+2] cycloaddition cross-linking the π-stacked layers in 3D COFs. The reaction is reversible and heating to 200°C leads to a cycloreversion while retaining the COF crystallinity. The resulting difference in connectivity is manifested in the change of mechanical and electronic properties, including exfoliation, blue-shifted UV-Vis absorption, altered luminescence, modified band structure and different acid-doping behavior. The Li-impregnated 2D and 3D COFs show a significant ion conductivity of 1.8×10<sup>−4</sup> S/cm and 3.5×10<sup>−5</sup> S/cm, respectively. Even higher room temperature proton conductivity of 1.7×10<sup>-2</sup> S/cm and 2.2×10<sup>-3</sup> S/cm was found for H<sub>2</sub>SO<sub>4</sub>-treated 2D and 3D COFs, respectively.


1992 ◽  
Vol 82 (4) ◽  
pp. 235-238 ◽  
Author(s):  
P. Wetzel ◽  
C. Pirri ◽  
P. Paki ◽  
J.C. Peruchetti ◽  
D. Bolmont ◽  
...  

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