Oxygen Surface Exchange and Tracer Diffusion in Differently Oriented Thin Films of Gd-Doped CeO2

2020 ◽  
Vol 12 (32) ◽  
pp. 36768-36777
Author(s):  
Stephan P. Waldow ◽  
Benjamin J. Statham ◽  
Hans F. Wardenga ◽  
Thomas E. Weirich ◽  
Andreas Klein ◽  
...  
Keyword(s):  
Thin Films ◽  
Tracer Diffusion ◽  
Surface Exchange ◽  
Doped Ceo2 ◽  
Oxygen Surface Exchange ◽  
Oxygen Surface

Surface potentials and oxygen surface exchange coefficients of acceptor and donor-doped CeO2 thin films

2021 ◽  
Author(s):  
Hans F. Wardenga ◽  
Katharina N.S. Schuldt ◽  
Stephan Peter Waldow ◽  
Roger A De Souza ◽  
Andreas Klein
Keyword(s):  
Thin Films ◽  
Work Function ◽  
Surface Electron ◽  
Surface Exchange ◽  
Surface Potentials ◽  
Doped Ceo2 ◽  
Oxygen Surface Exchange ◽  
Oxygen Surface

In order to evaluate the influence of work function and surface electron concentrations on oxygen surface exchange coefficients, the surface potentials of acceptor-, donor-, and nominally un-doped CeO2 films are...

scholarly journals Influence of Heterointerfaces on the Kinetics of Oxygen Surface Exchange on Epitaxial La1.85Sr0.15CuO4 Thin Films

2021 ◽  
Vol 11 (9) ◽  
pp. 3778
Author(s):  
Gene Yang ◽  
So-Yeun Kim ◽  
Changhee Sohn ◽  
Jong K. Keum ◽  
Dongkyu Lee
Keyword(s):  
Thin Films ◽  
Oxygen Vacancies ◽  
Elevated Temperatures ◽  
Surface Exchange ◽  
Electrical Conductivity Relaxation ◽  
Exchange Kinetics ◽  
Relaxation Curves ◽  
Kinetics Of ◽  
Oxygen Surface Exchange ◽  
Oxygen Surface

Considerable attention has been directed to understanding the influence of heterointerfaces between Ruddlesden–Popper (RP) phases and ABO3 perovskites on the kinetics of oxygen electrocatalysis at elevated temperatures. Here, we report the effect of heterointerfaces on the oxygen surface exchange kinetics by employing heteroepitaxial oxide thin films formed by decorating LaNiO3 (LNO) on La1.85Sr0.15CuO4 (LSCO) thin films. Regardless of LNO decoration, tensile in-plane strain on LSCO films does not change. The oxygen surface exchange coefficients (kchem) of LSCO films extracted from electrical conductivity relaxation curves significantly increase with partial decorations of LNO, whereas full LNO coverage leads to the reduction in the kchem of LSCO films. The activation energy for oxygen exchange in LSCO films significantly decreases with partial LNO decorations in contrast with the full coverage of LNO. Optical spectroscopy reveals the increased oxygen vacancies in the partially covered LSCO films relative to the undecorated LSCO film. We attribute the enhanced oxygen surface exchange kinetics of LSCO to the increased oxygen vacancies by creating the heterointerface between LSCO and LNO.

Limits to the rate of oxygen transport in mixed-conducting oxides

2017 ◽  
Vol 5 (38) ◽  
pp. 20334-20350 ◽  
Author(s):  
Roger A. De Souza
Keyword(s):  
Oxygen Transport ◽  
Tracer Diffusion ◽  
Surface Exchange ◽  
Conducting Oxides ◽  
Oxygen Surface Exchange ◽  
Oxygen Tracer ◽  
Oxygen Surface

Chemically reasonable limits to the rates of oxygen tracer diffusion and oxygen surface exchange in acceptor-doped oxides are examined.

Oxygen surface exchange properties and surface segregation behavior of nanostructured La0.6Sr0.4Co0.2Fe0.8O3−δ thin film cathodes

2019 ◽  
Vol 21 (13) ◽  
pp. 7183-7195 ◽  
Author(s):  
K. Develos-Bagarinao ◽  
J. De Vero ◽  
H. Kishimoto ◽  
T. Ishiyama ◽  
K. Yamaji ◽  
...  
Keyword(s):  
Thin Film ◽  
Thin Films ◽  
Surface Segregation ◽  
Oxygen Exchange ◽  
Surface Exchange ◽  
Segregation Behavior ◽  
Oxygen Surface Exchange ◽  
Exchange Properties ◽  
Oxygen Surface

Nanostructured LSCF thin films with more enhanced oxygen exchange properties also show a higher tendency to surface segregation.

scholarly journals Strontium influence on the oxygen electrocatalysis of La2−xSrxNiO4±δ (0.0 ≤ xSr ≤ 1.0) thin films

2014 ◽  
Vol 2 (18) ◽  
pp. 6480-6487 ◽  
Author(s):  
Dongkyu Lee ◽  
Yueh-Lin Lee ◽  
Alexis Grimaud ◽  
Wesley T. Hong ◽  
Michael D. Biegalski ◽  
...  
Keyword(s):  
Thin Films ◽  
Surface Exchange ◽  
Exchange Kinetics ◽  
Oxygen Surface Exchange ◽  
Oxygen Surface

Strong Sr dependence of the oxygen surface exchange kinetics for the La2−xSrxNiO4±δ (LSNO) thin films.

scholarly journals Tensile Lattice Strain Accelerates Oxygen Surface Exchange and Diffusion in La1–xSrxCoO3−δ Thin Films

ACS Nano ◽  
2013 ◽  
Vol 7 (4) ◽  
pp. 3276-3286 ◽  
Author(s):  
Markus Kubicek ◽  
Zhuhua Cai ◽  
Wen Ma ◽  
Bilge Yildiz ◽  
Herbert Hutter ◽  
...  
Keyword(s):  
Thin Films ◽  
Lattice Strain ◽  
Surface Exchange ◽  
And Diffusion ◽  
Oxygen Surface Exchange ◽  
Oxygen Surface

scholarly journals Surface chemistry of La0.6Sr0.4CoO3−δ thin films and its impact on the oxygen surface exchange resistance

2015 ◽  
Vol 3 (45) ◽  
pp. 22759-22769 ◽  
Author(s):  
Ghislain M. Rupp ◽  
Helena Téllez ◽  
John Druce ◽  
Andreas Limbeck ◽  
Tatsumi Ishihara ◽  
...  
Keyword(s):  
Thin Films ◽  
Surface Chemistry ◽  
Oxygen Exchange ◽  
Surface Exchange ◽  
Icp Ms ◽  
Exchange Kinetics ◽  
Oxygen Surface Exchange ◽  
Oxygen Surface

Correlation between the surface chemistry of LSC thin films analyzed by LEIS and ICP-MS and the oxygen exchange kinetics.

Enhanced Oxygen Surface Exchange Kinetics and Stability on Epitaxial La0.8Sr0.2CoO3−δ Thin Films by La0.8Sr0.2MnO3−δ Decoration

2014 ◽  
Vol 118 (26) ◽  
pp. 14326-14334 ◽  
Author(s):  
Dongkyu Lee ◽  
Yueh-Lin Lee ◽  
Alexis Grimaud ◽  
Wesley T. Hong ◽  
Michael D. Biegalski ◽  
...  
Keyword(s):  
Thin Films ◽  
Surface Exchange ◽  
Exchange Kinetics ◽  
Oxygen Surface Exchange ◽  
Oxygen Surface
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