Effects of Proximity-Dependent Metal Migration on Bifunctional Composites Catalyzed Syngas to Olefins

ACS Catalysis ◽  
2021 ◽  
pp. 9729-9737
Author(s):  
Yi Ding ◽  
Feng Jiao ◽  
Xiulian Pan ◽  
Yi Ji ◽  
Mingrun Li ◽  
...  
Keyword(s):  

2020 ◽  
Vol 13 (4) ◽  
pp. 1269-1278 ◽  
Author(s):  
Kyojin Ku ◽  
Byunghoon Kim ◽  
Sung-Kyun Jung ◽  
Yue Gong ◽  
Donggun Eum ◽  
...  

We propose a new lithium diffusion model involving coupled lithium and transition metal migration, peculiarly occurring in a lithium-rich layered oxide.



Materials ◽  
2018 ◽  
Vol 11 (8) ◽  
pp. 1370 ◽  
Author(s):  
Chien-Ya Kao ◽  
Yen-Chieh Huang ◽  
Sheng-Yi Chiu ◽  
Ko-Liang Kuo ◽  
Pai-An Hwang

The addition of calcined waste clamshells (CCS) into polyethylene (PE) plastic bags imparts antibacterial properties due to the presence of CaO. In this study, different proportions of calcined waste clamshells were added to PE to explore its bacteriostatic effects. The PE plastic bags with 9% and 11% of CCS exhibited antibacterial efficacy. Further, total aerobic viable count (TVC) values for raw fish fillet packaging in 9% and 11% CCS-PE plastic bags for five days were similar to the 0% CCS-PE plastic bag group after three days of incubation. In addition, the CCS-PE plastic bag demonstrated stability against solvents when examined using the metal migration test under heptane, ethanol, and acetic acid treatments. The results revealed that the CCS-PE bag retains its CaO bacteriostatic efficacy and that the addition of CCS powder to PE prolongs the shelf life of raw fish fillets, as well as mitigating safety concerns from metal leakage.



2020 ◽  
pp. 2003256
Author(s):  
Rui Liu ◽  
Shiyao Zheng ◽  
Yifei Yuan ◽  
Pengfei Yu ◽  
Ziteng Liang ◽  
...  


Author(s):  
C. Song ◽  
D.V. Kerns ◽  
J.L. Davidson ◽  
D.L. Kinser
Keyword(s):  


2021 ◽  
Author(s):  
Dianwei Hou ◽  
Christopher Heard

Unbiased density functional global optimisation calculations, followed by kinetic Monte Carlo simulations are used to enumerate the potential energy surfaces for migration of noble metals Pt and Au inside the pore system of siliceous zeolite LTA. The effects of reducing adsorbates CO and H2 are determined. It is found that the two metals differ significantly in the strength and type of interaction with the framework, with strong, framework breaking interactions between Pt and and the zeolite, but only weak dispersive interactions between Au and the zeolite. Adsorbates are found to dramatically interfere with Pt-framework binding, leading to poorer atom-trapping, enhanced metal migration and faster equilibration.



2015 ◽  
Vol 51 (24) ◽  
pp. 4981-4984 ◽  
Author(s):  
Koichi Takano ◽  
Yousuke Ikeda ◽  
Shintaro Kodama ◽  
Youichi Ishii

Reaction of [(η6-C6Me6)Ru(Ph)(PMe3)]+ with internal alkynes gave rise to the 1,4-Ru migration to form the o-vinylaryl complex, providing the first example of 1,4-metal migration of a group 8 metal center; in one case further isomerization to an η3-allyl complex was observed.



1988 ◽  
Vol 3 (5) ◽  
pp. 996-1001 ◽  
Author(s):  
J. D. Rancourt ◽  
G. M. Porta ◽  
E. S. Moyer ◽  
D. G. Madeleine ◽  
L. T. Taylor

Polyimide-metal oxide (Co3O4 or CuO) composite films have been prepared via in situ thermal decomposition of cobalt (II) chloride or bis (trifluoroacetylacetonato) copper (II). A soluble polyimide (XU-218) and its corresponding prepolymer (polyamideacid) were individually employed as the reaction matrix. The resulting composites exhibited a greater metal oxide concentration at the air interface with polyamideacid as the reaction matrix. The water of imidization that is released during the concurrent polyamide acid cure and additive decomposition is believed to promote metal migration and oxide formation. In contrast, XU-218 doped with either HAuCl4 · 3H2O or AgNO3 yields surface gold or silver when themolyzed (300 °C).



2021 ◽  
pp. 251-261
Author(s):  
Junjie Fan ◽  
Jiaxiao Deng ◽  
Zhiyuan Ren ◽  
Jianli Wang
Keyword(s):  


2013 ◽  
Vol 2013 (1) ◽  
pp. 000050-000054
Author(s):  
Jon Abrokwah ◽  
John Stanback ◽  
Jerry Wang ◽  
Molly Johnson ◽  
Chi L. Jiaa

Moisture reliability of a 0.15-um gate PHEMT technology for mm-wave applications was investigated. The PHEMT technology is fabricated with a deep UV optical lithography, and typically exhibits transconductance of ~550 mS/mm and fT of ~90 GHz. Moisture reliability, THBL or BHAST performed at 85% relative humidity, and 95 °C, or 130 °C and 85% RH, respectively, initially showed failures up to 70%, under various process splits. Extensive failure analysis pointed to a number of mechanisms contributing to failure, the key culprit being moisture ingress, enabled by poor quality of SiN, stresses, seams, and voids in the passivation dielectric around the gate topology. Moisture penetrated the SiN to GaAs surface through seams in the dielectric around the gate or regions of high local stress such as gate feeds and ends. A corrosion process ensued with the applied voltage bias on the device drain and gate during the THBL or BHAST environmental stress, leading to GaAs oxidation, metal migration and shorts. By designing the gate topology appropriately, failures were reduced to the range of 0–3.4 %. Further, using a BCB overcoat, failures were completely eliminated.



ChemInform ◽  
2006 ◽  
Vol 37 (23) ◽  
Author(s):  
Karl H. Doetz ◽  
Benjamin Wenzel ◽  
Holger C. Jahr
Keyword(s):  


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